Osaka Gas Company Limited

National Institute of Advanced Industrial Science and Technology

Isuzu Glass Company, Ltd.

Isuzu Glass Ltd.

Koichiro Ikeda

Tetsuo Sakai

Takashi Mukai

Naoto Yamashita

Taichi Sakamoto

Hidaka Asonuma

Yuta Ikeuchi

Kunihiko Tani

Hinako Matsuo

Kiichiro Yamaguchi

Naoki Inoue

Satoshi Mori

Kota Yokoyama

Tsubasa Shimizu

Shota Kawashima

Fuyuki Noguchi

Yukio Hiranaka

When the product gas producing operation is stopped, a stand-by operation is executed in which a product gas filling up a reforming processing unit is circulated, in a state in which an adsorbent of adsorption towers is maintained in a state in which adsorption target components are desorbed, and the heating of a reformer by a heating burner is maintained, and when the stand-by operation is stopped and the product gas producing operation is started, initial operation processing is executed in which immediately after the start, a source gas and steam are supplied to the reformer to produce a reformed gas, and the reformed gas from the reforming processing unit supplied to the adsorption towers to produce the product gas, and then the product gas producing operation in which the product gas is collected in a product gas tank is executed.

Operation method for hydrogen production device, and hydrogen production device

At a center portion of a ceiling wall of a furnace body having a lateral wall between the ceiling wall and a bottom wall, there is a burner that combusts downwards. A reforming reaction tube is provided in a circumference of the burner to carry out a steam reforming treatment on a source gas. A discharging portion is an opening at an upper side portion of the lateral wall for discharging combustion gas of the burner. A cylindrical outer wall is disposed at an outer side portion of the lateral wall. In an outside space formed between the lateral wall and the outer wall, there is a steam generating heat exchanger generating steam or a mixture gas of a source gas and steam. At a lower side portion of the outer wall, there is outside discharging opening discharging the combustion gas which flows through the outside space.

Reforming furnace

When a product gas producing operation is stopped, a purge operation is executed in which steam purge processing and product gas purge processing are sequentially performed. The steam purge is supplying, instead of a source gas, a product gas from a product gas tank to a reformer using a compressor, and supplying a reformed gas from a reforming processing unit to a plurality of adsorption towers, which perform a pressure swing adsorption operation, while the reformer is heated by a heating burner and steam is supplied to the reformer. The product gas purge is supplying the product gas from the product gas tank to the reformer using the compressor, and supplying the product gas from the reforming processing unit to the plurality of adsorption towers, which perform the pressure swing adsorption operation, while the supply of the steam is stopped and the heating of the reformer is maintained.

The teachings herein are directed at a lithium secondary battery negative electrode active material consisting of a Sn Sb based sulfide that delivers a high electrode capacity density, excellent output characteristics, and excellent cycle life characteristics and also provide a method for manufacturing the lithium secondary battery negative electrode active material, said method being capable of easily manufacturing the high performance lithium secondary battery negative electrode active material at low cost without requiring a high-temperature processing step and special facilities as required in a glass melting method. The negative electrode active material preferably is prepared using a method that includes a step of obtaining a Sn Sb based sulfide precipitate by adding an alkali metal sulfide to a mixed solution of a tin halide and an antimony halide.

Lithium secondary battery negative electrode active material and method for manufacturing same

A method for hydrogen production by pressure swing adsorption that can increase the recovery efficiency of an adsorption target component while enabling an off-gas to be appropriately supplied to a combustion device is provided that can achieve a cost reduction and an increase in the efficiency of the combustion operation.

Method for hydrogen production by pressure swing adsorption

Problem. Provided is a negative electrode material for a sodium secondary battery and its manufacturing method, and a negative electrode for a sodium secondary battery, and a sodium secondary battery, wherein the negative electrode material can have excellent cycle characteristics while maintaining high discharge capacity. Solution. A negative electrode material for a sodium secondary battery according to the present invention includes sulfide or sulfide composite body containing sulfur and antimony, and as necessary further includes the following component(s) of (i): (i) at least one or more element(s) selected from a group consisting of Sn, As, Bi, Ge, Ga, Pb, and C, wherein when a component(s) of (i) is included, the ratio of each of the above described components is sulfur: 10 to 70 mol %, antimony: 10 to 70 mol %, and (i): 3 to 60 mol %.

Negative electrode material for sodium secondary battery and method for producing same, negative electrode for sodium secondary batter, and sodium secondary battery

[Object] The object is to provide a negative electrode material for a lithium secondary battery, wherein a sulfide-based negative electrode with water-resistant properties can exert excellent cycle characteristics and high output performance while maintaining a high discharge capacity and there is no precipitation of lithium dendrites during charge at low temperature. [Means for Solving Problems] A negative electrode material for a lithium secondary battery comprising sulfur and sulfide glass including the following components (i) and (ii): (i) at least one or more elements selected from a group consisting of Sb, As, Bi, Ge, Si, Cu, Zn, Pd, In and Zr; and (ii) at least one or more elements selected from a group consisting of Se, Te, Ga, Sn, Pb, Cd, Al, Fe, Mg, Ca, Co, Ag, Sr, P and Ba, 

Negative electrode material for lithium secondary battery and its manufacturing method, and negative electrode for lithium secondary battery, and lithium secondary battery

A catalytic reactor including: a reaction container filled with a catalyst having ruthenium; and an introduction part for introducing a material fluid to the reaction container. The reaction container is supplied with a mixed gas as material fluid to produce synthetic gas containing hydrogen and carbon monoxide in the presence of the catalyst. The introduction part is connected to the reaction container in a horizontal direction or a direction inclined downward from above a horizontal plane, and a height of the catalyst filled in the reaction container is adjusted above a height at which the material fluid is fed from the introduction part to the reaction container. Also, a method of using the catalytic reactor including monitoring a molar ratio of carbon and oxygen contained in the material fluid and stopping the supply of an oxygen-containing gas to the reaction container before the molar ratio becomes excessively low.

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Osaka, Japan

Koichiro Ikeda