Daihatsu Motor Company, Ltd.

University of Yamanashi

Takahata Precision Co., Ltd.

The University of New Mexico

Takahata Precision Japan Co., Ltd.

Japan Atomic Energy Agency

Otsuka Chemical Co., Ltd.

Koichiro Asazawa

Hirohisa Tanaka

Kenji Miyatake

Naoki Yokota

Junpei Miyake

Koji Yamada

Manai Shimada

Eriko Nishino

Hideaki Ono

Aoi Takano

Plamen B Atanassov

Natsumi Yoshimura

Alexey Serov

Katsuya Nagase

Kazuya Yamamoto

Masaharu Asano

Masatoshi Taniguchi

Masahiro Watanabe

Yui Kuwabara

Yasunari Maekawa

Tetsuya Yamaki

Akinori Oka

Takeshi Kato

Yousuke Konno

Tim S Olson

Takashi Kitajima

Svitlana Pylypenko

Ken Sonogi

Hiroshi Koshikawa

Susumu Yamaguchi

Haruyuki Nakanishi

Tomokazu Sakamoto

Masahiro Abe

Taro Kimura

Tomokazu Skamoto

Kimio Yoshimura

Hideyuki Shishitani

Fumihiro Sanpei

Provided are an anion exchange resin being capable of producing an electrolyte membrane, a binder for forming an electrode catalyst layer and a battery electrode catalyst layer, which have improved electrical properties and chemical properties. For example, used is an anion exchange resin which has a hydrophobic unit being composed of bisphenol AF residues repeated via carbon-carbon bond and a hydrophilic unit being composed of hydrophilic groups repeated via carbon-carbon bond, in which the hydrophilic group is formed by connecting an anion exchange group to a fluorene backbone via a divalent saturated hydrocarbon group, and in which the hydrophobic unit and the hydrophilic unit are connected via carbon-carbon bond.

Anion exchange resin, electrolyte membrane, binder for forming electrode catalyst layer, fuel cell electrode catalyst layer and fuel cell

Provided are an anion exchange resin being capable of producing an electrolyte membrane and the like, which have improved chemical properties (durability). For example, used is an anion exchange resin comprising a hydrophobic unit being composed of a plurality of divalent hydrophobic groups repeated via carbon-carbon bond, the divalent hydrophobic group having a plurality of aromatic rings which are connected to each other via a divalent fluorine-containing group; and a hydrophilic unit being composed of a plurality of hydrophilic groups repeated via carbon-carbon bond, the hydrophilic groups being composed of a plurality of aromatic rings which are connected to each other via a divalent hydrocarbon group and/or carbon-carbon bond, and the hydrophilic groups containing an anion exchange group-containing group including a quaternary ammonium salt having a piperidine ring, and wherein the hydrophobic unit and the hydrophilic unit are connected via carbon-carbon bond.

Provided are an anion exchange resin being capable of producing an electrolyte membrane for a fuel cell, a binder for forming an electrode catalyst layer and a fuel cell electrode catalyst layer, which have an improved physical property (anion conductivity); a method for producing thereof; an electrolyte membrane for a fuel cell, a binder for forming an electrode catalyst layer and a fuel cell electrode catalyst layer produced from the anion exchange resin; and a fuel cell having the electrolyte membrane or the electrode catalyst layer. For example, the anion exchange resin is obtained by reacting a hydrophobic monomer with an aminoalkyl group-containing monomer, in which the hydrophobic monomer is composed of one aromatic ring or a plurality of aromatic rings to which two halogen atoms are bonded, and the aminoalkyl group-containing monomer is composed of one aromatic ring or a plurality of aromatic rings to which two halogen atoms are bonded and an aminoalkyl group is introduced; and by quaternizing the amino group. In the anion exchange resin, a divalent hydrophobic group formed by the residue of the hydrophobic monomer, and a divalent hydrophilic group formed by the residue of the quaternized aminoalkyl group-containing monomer are bonded via direct bond.

Anion exchange resin, method for producing thereof, electrolyte membrane for fuel cell, binder for forming electrode catalyst layer, fuel cell electrode catalyst layer and fuel cell

An anion exchange resin capable of producing an electrolyte membrane, a binder for forming an electrode catalyst layer and a fuel cell electrode catalyst layer, which have improved chemical properties and mechanical properties; an electrolyte membrane and a binder for forming an electrode catalyst layer produced from the anion exchange resin; and a fuel cell having the electrolyte membrane or the electrode catalyst layer.

An anion exchange resin capable of producing an electrolyte membrane, a binder for forming an electrode catalyst layer and a fuel cell electrode catalyst layer, which have improved electrical properties; an electrolyte membrane and a binder for forming an electrode catalyst layer produced from the anion exchange resin; and a fuel cell having the electrolyte membrane or the electrode catalyst layer.

A supported bi-metallic non-platinum catalyst that is capable of oxidizing hydrazine to produce, as by-products of energy production, nitrogen, water, and zero or near-zero levels of ammonia is described. The catalyst is suitable for use in fuel cells, particularly those that utilizes an anion-exchange membrane and a liquid fuel such as hydrazine.

Supported Ni-M materials for electrooxidation of hydrazine

The present invention provides an anion exchange resin capable of producing an electrolyte membrane for a fuel cell, a binder for forming an electrode catalyst layer and a battery electrode catalyst layer. The anion exchange resin of the present invention has a hydrophobic unit, a hydrophilic unit and divalent fluorine-containing groups. The hydrophobic unit has divalent hydrophobic groups composed of one aromatic ring or a plurality of aromatic rings that are repeated via carbon-carbon bond. The hydrophilic unit has divalent hydrophilic groups composed of one aromatic ring or a plurality of aromatic rings, at least one of which has an anion exchange group, that are repeated via carbon-carbon bond. The divalent fluorine-containing groups have a specific structure and are bonded via carbon-carbon bond to the hydrophobic unit and/or the hydrophilic unit and/or a moiety other than these units.

Anion exchange resin, electrolyte membrane for fuel cell, binder for forming electrode catalyst layer, battery electrode catalyst layer and fuel cell

An anion exchange resin having a hydrophobic unit with divalent hydrophobic groups bonded to each other via an ether bond, the divalent hydrophobic groups being composed of one aromatic ring, or being composed of a plurality of aromatic rings which are bonded to each other via a divalent hydrocarbon group, carbon-carbon bond or the like; and a hydrophilic unit having divalent hydrophilic groups bonded to each other via carbon-carbon bond, the divalent hydrophilic groups being composed of one aromatic ring, or being composed of a plurality of aromatic rings which are bonded to each other via a divalent hydrocarbon group or carbon-carbon bond, the aromatic ring or at least one of the aromatic rings having an anion exchange group are bonded via carbon-carbon bond.

Supported Ni&#x2014;M materials for electrooxidation of hydrazine

An anion conducting electrolyte membrane with high performance where the electric conductivity and the water uptake are balanced, and a method of manufacturing the same are disclosed. The anion conducting electrolyte membrane comprises: a polymeric material which consists of fluorine polymer, olefinic polymer, or aromatic polymer; weak base quaternary salt obtained by the reaction of grafts introduced by graft polymerizing vinyl monomer which contains halogenated alkyl groups using radiation and strong organic bases.

Anion conducting electrolyte membrane and manufacturing method thereof

A fuel cell system of the present invention includes a fixing unit that fixes or releases hydrazine, a fuel cell to which hydrazine released in the fixing unit is supplied as fuel, a supply line for supplying an aqueous hydrazine solution from a hydrazine supply source to the fixing unit, a drain line for draining drained water from the fixing unit, a first sensing unit for detecting a hydrazine concentration in an aqueous hydrazine solution flowing in the supply line, a second sensing unit for detecting a hydrazine concentration in drained water flowing in the drain line, and a detection unit that detects the amount of hydrazine fixed in the fixing unit based on the concentration values detected by the first sensing unit and the second sensing unit.

Hydrazine fixing detection system

In a fuel cell including an electrolyte layer allowing an anion component to migrate, and a fuel-side electrode and an oxygen-side electrode arranged to face each other while sandwiching the electrolyte layer, the oxygen-side electrode contains a first catalyst containing a first transition metal and polypyrrole, and a second catalyst containing a second transition metal and a porphyrin ring-containing compound so that the mixing ratio of the first catalyst relative to 100 parts by mass of the total amount of the first catalyst and the second catalyst is more than 10 parts by mass, and below 90 parts by mass.

Oxygen side electrode for a fuel cell

A fuel cell system of the present invention includes a fixing unit that fixes or releases hydrazine; a releasing liquid supplying unit that supplies a water-based releasing liquid for releasing hydrazine fixed in the fixing unit to the fixing unit; a fuel cell to which hydrazine released in the fixing unit is supplied as fuel; a sensing unit for detecting an amount of hydrazine supplied to the fuel cell; and a detection unit that detects an amount of hydrazine fixed in the fixing unit based on a predetermined theoretical hydrazine supply amount to the fuel cell and a hydrazine supply amount detected by the sensing unit.

Fuel cell system

A dimethyl ether reforming catalyst that can reform dimethyl ether to produce a mixed gas of higher concentration of hydrogen and a fuel cell device using the dimethyl ether reforming catalyst. In the dimethyl ether reforming catalyst, copper, or copper and at least one transition metal except the copper is supported on a solid acid. A mixed gas obtained by a reforming device using the dimethyl ether reforming catalyst is fed to the fuel cell as a fuel gas.

Dimethyl ether reforming catalyst

A fuel cell system includes a reforming device for producing a hydrogen-rich gas mixture by reforming a hydrogen-containing compound, and a fuel cell stack for generating electromotive fore by a reaction between hydrogen and oxygen. The fuel cell system further includes a hydrogen separating device disposed between the reforming device and the fuel cell stack. The hydrogen separating device is provided with hydrogen permeating means for obtaining a fuel gas by separating hydrogen gas from the gas mixture.

Fuel cell system with hydrogen gas separation

Growing community of inventors

Shiga, Japan

Koichiro Asazawa