Jx Metals Corporation

Jx Advanced Metals Corporation

Jx Nippon Mining Metals Corporation

Koichi Takemoto

Yuichiro Shindo

Toru Imori

Shiro Tsukamoto

Takahiro Uchida

Masahiro Takahata

Hideaki Fukuyo

Masatomi Murakami

Provided is a method for producing stannous oxide, comprising a step of subjecting stannous sulfate to neutralization in an aqueous solution using ammonium carbonate or ammonium bicarbonate, and thereby precipitating stannous oxide. This production method is a novel means for producing stannous oxide in which chlorine, sulfur, sodium, and potassium are sufficiently reduced, and which has excellent solubility.

Stannous oxide powder and method for producing same

A copper electrode material comprising Cu and unavoidable impurities, wherein the content of the unavoidable impurities is 1 ppm by mass or less and the average crystal grain diameter is 100 μm or less. A copper-containing electrode material having improved corrosion resistance is provided by the copper electrode material.

Copper electrode material

In the present invention, a high-purity metallic tin suitable for use in an EUV exposure device is provided through use of an oxidation-resistant metallic tin, the oxidation-resistant metallic tin containing 99.995 mass % or more of tin, and unavoidable impurities, and the thickness of an oxide film being 2.0 nm or less when the surface of a cut face of the oxidation-resistant metallic tin is measured by AES.

Oxidation-resistant metallic tin

The present invention provides a method for producing an aqueous tin methanesulfonate solution by dissolving tin (II) oxide in an aqueous methanesulfonic acid solution, wherein if A is the number of moles of the tin (II) oxide and B is the number of moles of the methanesulfonic acid, the value of B/2A is within the range of from 1.0 to 1.4. This method for dissolving tin (II) oxide into an aqueous methanesulfonic acid solution is able to achieve a high tin ion concentration.

Method for dissolving tin (II) oxide

The purpose of the present invention is to provide a stannous oxide, which has excellent solubility and resistance to oxidation, from a stannous oxide powder comprising a stannous oxide and inevitable impurities, the stannous oxide powder having a stannous oxide content of 99.99 mass % or more in dry mass, a specific surface area of less than 0.5 m/g, a D50 particle size of 20 to 60 μm, and a half width of the particle size distribution of 5 to 30 μm.

Stannous oxide powder

Provided is a stannous oxide powder that can be suitably used for supplying tin ions, and has improved solubility and at the same time has an improved handling property. A stannous oxide powder comprising stannous oxide and inevitable impurities, wherein a content of stannous oxide in a dry mass is 99.9% by mass or more; a specific surface area is from 0.1 to 1.0 m/g; a TAP density is from 2 to 4 g/cm; a 50% particle diameter is from 30 to 60 &#x3bc;m; and an angle of repose is from 10 to 33&#xb0;.

Provided is high purity tin having purity of 5N (99.999% by mass), which can suppress generation of particles. According to the high purity tin, the number of particles each having a particle diameter of 0.5 &#x3bc;m or more is 50,000 or less per a gram.

High purity tin and method for producing same

Provided is a high-purity tin product that does not contain undesirable carbonaceous impurities as a result of the following: a vacuum-packed high-purity metal article (vacuum-packed high-purity tin article) is obtained by vacuum packaging a high-purity metal (high-purity tin), at least a portion of a surface of a high-purity metal being covered with a fluorocarbon resin sheet; and the vacuum-packed high-purity metal article(vacuum-packed high-purity tin article) is obtained by vacuum packaging, with a vacuum packaging film, the high-purity metal in which at least a portion of a surface is covered with the fluorocarbon resin sheet.

Growing community of inventors

Ibaraki, Japan

Koichi Takemoto