Wd Media (Singapore) Pte. Ltd.

Hoya Corporation

Wd Media, LLC

Hoya Magnetics Singapore Pte. Ltd.

(Singapore) Pte. Ltd.

Wd Meida (Singapore) Pte. Ltd.

Koichi Shimokawa

Katsushi Hamakubo

Kae Itoh

Kota Suzuki

Kota Hara

Hiroshi Tomiyasu

Masafumi Ishiyama

A magnetic disk of is provided, the magnetic disk having at least a magnetic layer, a carbon protective layer, and a lubrication layer sequentially provided on a substrate. In an embodiment, the lubrication layer a film formed by a lubricant having a perfluoropolyether compound A having a perfluoropolyether main chain in the structure and also having a hydroxyl group at the end and a compound C obtained from a reaction between a compound B expressed by: [Chemical formula 1] CF(&#x2014;O&#x2014;CF)m-(O&#x2014;CF)n-OCF[m and n in the formula are natural numbers.] and aluminum oxide.

Magnetic disk and manufacturing method thereof

A lubricant compound is contained in a lubrication layer of a magnetic disk in which at least a magnetic layer, a protective layer, and a lubrication layer are sequentially provided on a substrate, and the lubricant compound contains a component A represented by Chemical formula 1 and a component B represented by Chemical formula 2: wherein X in Chemical formula 1 represents OH wherein X in Chemical formula 2 represents OCHCH(OH)CHOH,and the lubricant compound further contains a component C made of a specific compound having a phosphezene ring in the structure thereof.

Lubricant compound for magnetic disk and magnetic disk

A magnetic disk having at least a magnetic layer, a carbon protective layer, and a lubrication layer sequentially provided on a substrate. The lubrication layer is a film formed by a lubricant that contains two types of compounds having a perfluoropolyether main chain in the structure, a molecular weight distribution of the two types in total being within a range of 1 to 1.2. The two types of compounds include a compound a having a hydroxyl group at the end and a compound b having a number average molecular weight smaller than the number average molecular weight of the compound a and not more than 1500. A content of the compound b in the two types of compounds is not more than 10%.

A lubricant for a magnetic disk that is excellent in heat resistance and is suitably used in a magnetic disk to be mounted on a magnetic recording device of a thermally assisted magnetic recording system and a magnetic disk provided with a lubricant layer containing this lubricant. The lubricant for a magnetic disk contains a compound where perfluoropolyether groups each having a perfluoropolyether main chain in its structure and a phosphazene ring at an end are linked to each other through a linking group. The linking group is an aliphatic group or a phosphazene ring. In a magnetic disk having at least a magnetic recording layer, a protective layer, and a lubricant layer on a substrate, the lubricant layer contains the lubricant for a magnetic disk.

Lubricant for magnetic disk and magnetic disk

Provided is a magnetic disk comprising a lubricating layer formed of a lubricant. The lubricant constituting the lubricating layer has excellent properties, for example, excellent fluidity, surface energy, and CFT properties. By virtue of the excellent properties, the magnetic disk has a high level of reliability despite a low flying height of a magnetic head due to a recent rapid increase in recording density and a very severe environment resistance requirement due to diversification of applications. The magnetic disk comprises a substrate and at least a magnetic layer, a protective layer, and a lubricating layer provided in that order over the substrate. The lubricating layer is formed of a lubricant that is a mixture of a specific perfluoropolyether lubricant with a lubricant formed of a compound comprising perfluoropolyether groups having a perfluoropolyether main chain in the structure thereof and having a hydroxyl group at the end thereof, the perfluoropolyether groups being bonded to each other through a divalent linking group having at least two hydroxyl groups in the structure thereof.

Magnetic disk and method of manufacturing the same

A method of manufacturing a magnetic disk in which at least a magnetic layer, a carbon protective layer, and a lubrication layer are sequentially formed on a substrate is provided. The method comprises forming a film of a lubricant composition on the protective layer, the lubricant comprising a lubricant compound having a perfluoropolyether main chain in the molecular structure and an aromatic group or a phosphazene ring. The method further comprises forming the lubrication layer, and subjecting the magnetic disk to ultraviolet irradiation under a nitrogen gas or an inert gas atmosphere having an oxygen concentration of 5 volume % or less by adjusting an atmospheric temperature to a range of 50 to 180&#xb0; C.

Method of producing a magnetic recording disc

On manufacturing a magnetic disk having at least a magnetic layer (), a protective layer (), and a lubricating layer () formed in this order over a substrate (), the lubricating layer is formed by using a coating solution in which a perfluoropolyether compound having a perfluoropolyether main chain and a hydroxyl group in a structure thereof is dispersed and dissolved in a fluorine-based solvent having a boiling point of 90&#xb0; C. or more.

Method of manufacturing a magnetic disk

A magnetic disk in which at least a magnetic layer, a protective layer, and the lubrication layer are sequentially provided on a substrate, the lubrication layer contains a lubricant compound for a magnetic disk, having a perfluoropolyether main chain in the molecular structure and a structure indicated as follows at a position close to the center of the molecule:-0-CH&#x2014;CH(OH)&#x2014;CH&#x2014;CH&#x2014;CH(OH)&#x2014;CH-0-or-0-CH&#x2014;CH(OH)&#x2014;CH(OH)&#x2014;CH-0-.

Lubricant for magnetic disc, magnetic disc and method of producing the same

In a magnetic disk that has at least a magnetic layer, a carbon-based protective layer, and a lubricating layer formed in this order over a substrate, the lubricating layer contains a lubricant compound including a compound which has a perfluoropolyether main chain in a structure thereof, an aromatic group located at a position except each end of a molecule thereof, and a polar group at each end of the molecule.

Lubricant compound for a magnetic disk, magnetic disk, and method of manufacturing the same

A lubricant for magnetic disks which can form a lubricating layer having a reduced thickness while attaining a high coverage and is excellent in heat resistance and adhesion to a protective layer. The lubricant for magnetic disks comprises a perfluoropolyether compound in which the relationship between the number-average molecular weight and the standardized value of the number of hydroxy groups contained in the molecule satisfies the following: the number-average molecular weight is in the range of 1,000-6,000; the standardized value of the number of hydroxy groups contained in the molecule is 180 or higher; and the compound is in a region located below the line connecting the point where the number-average molecular weight is 1,000 and the standardized value of the number of hydroxy groups in the molecule is 400 to the point where the number-average molecular weight is 6,000 and the standardized value of the number of hydroxy groups in the molecule is 1,600. The compound has at least one hydroxy group around the center of the molecular chain.

Lubricant for magnetic disk, process for producing the same, and magnetic disk

In order to obtain a magnetic recording disk that exhibits high reliability even if the flying height of a magnetic head becomes very narrow, a lubricant is specified in terms of both molecular structure and quantitative data. That is, a lubricating layerof the magnetic recording diskis formed by a lubricant which contains perfluoropolyether compounds represented by the following chemical formula (Chemical Formula 1) and which has a first component content of 71.7%, a second component content of 15.7%, a third component content of 11.7%, a fourth component content of 0.3%, and a fifth component content of 0.6%:X&#x2014;OCHCF&#x2014;(CFO)(CFO)&#x2014;CFOCHO&#x2014;X&#x2003;&#x2003;(Chemical Formula 1)

Magnetic recording disk and method for manufacture thereof

The present invention provides a lubricant for forming a lubricating layer which is useful in preventing fly and stiction and/or corrosion at an extremely small flying height of 10 nm or less, which is prevented from migrating at a high rotational speed of 5400 rpm or more, which has high adhesion, and which is suitable for a load/unload method. A crude lubricant containing at least one perfluoropolyether is degassed and then purified. Alternatively, a liquid crude lubricant containing at least one perfluoropolyether is purified by vaporizing the crude lubricant and then liquefying the vapor of the perfluoropolyether within a distance less than the mean free path of molecules of the perfluoropolyether. A magnetic disk is prepared in such a manner that a carbonaceous protective layer is formed above a substrate and a lubricating layer is formed on the protective layer using of the lubricant. The lubricant contains the perfluoropolyether and has a molecular weight distribution of 1.3 or less.

Lubricant for magnetic disks, method for producing the lubricant used in the magnetic disks, and method for manufacturing the same

Disclosed is a magnetic disk which has a lubricant layer with excellent heat resistance and high adhesiveness and is free from fly-stiction failure or corrosion failure even at an extremely low flying height of 10 nm or lower. Also disclosed is a magnetic disk which has a lubricant layer with good thermal properties and can exert a stable action over a wide temperature range. The magnetic disk comprises a substrate (), and a magnetic layer (), a carbon-containing protective layer () and a lubricant layer () provided on the substrate (), wherein the lubricant layer () contains a magnetic disk lubricant comprising a compound having a phosphazene ring and two or more hydroxyl and/or carboxyl groups in the molecule.

Magnetic disk

On producing a lubricant which is used in making a lubrication layer included in a magnetic disk from the lubricant, a phosphorus-containing compound is removed from a raw-material lubricant including the phosphorus-containing compound to produce the lubricant. The magnetic disk includes a substrate on which at least a magnetic layer, a protection layer, and the lubrication layer formed by the use of the lubricant are successively formed.

Method of producing a lubricant for a magnetic disk, lubricant for a magnetic disk, magnetic disk, and method of producing a magnetic disk

A magnetic recording disk having a substrate, a magnetic layer formed on the substrate, a protective layer formed on the magnetic layer and a lubricant layer formed on the protective layer, the lubricant layer containing a perfluoropolyether compound having an end moiety containing a phosphazene ring and a perfluoropolyether compound having an end moiety containing a hydroxyl group, or the lubricant layer containing a perfluoropolyether compound having an end moiety containing a hydroxyl group on the protective layer side and a perfluoropolyether compound having an end moiety containing a phosphazene ring on the other surface side, and a process for manufacturing each of these magnetic recording disks.

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Tokyo, Japan

Koichi Shimokawa