Nissan Chemical Industries Limited

Nagaoka University of Technology

University of Hyogo

Nissan Chemical Corporation

Kohei Goto

Tadashi Hatanaka

Shojiro Yukawa

Masato Moriuchi

Kimiaki Tsutsui

Yuta Kanno

Nobuhiro Kawatsuki

Jun Ito

Kanako Suzuki

Hiroshi Ono

Tomoyuki Sasaki

Hiroyuki Omura

Ryoichi Ashizawa

Takahiro Sakai

Masaaki Katayama

Hirobumi Shida

Masahide Ishizuya

Yuta Kawano

The present invention provides a polarization-independent terahertz wave control element, and provides a method for manufacturing a polarization-independent terahertz wave control element. The present invention provides a terahertz wave control element comprising: (A) a first flat plate having (A1) a first substrate, (A2) a first electrode formed on the first substrate, and (A3) a first liquid crystal alignment film formed on the first electrode; (B) a second flat plate having (B1) a second substrate, (B2) a second electrode formed on the second substrate, and (B3) a second liquid crystal alignment film formed on the second electrode; and (C) a liquid crystal present in a space formed by disposing (A) the first flat plate and (B) the second flat plate parallel to each other with a predetermined distance therebetween so that the first and second liquid crystal alignment films face each other, wherein (D1) the terahertz wave control element has a first portion in which the liquid crystal is aligned in a first direction parallel to (A) the first flat plate and (B) the second flat plate, and a second portion in which the liquid crystal is aligned in a second direction orthogonal to the first direction and parallel to (A) the first flat plate and (B) the second flat plate when no voltage is applied, (D2) the first portion has a first width, the second portion has a second width, the first and second portions are disposed adjacent to each other and alternately disposed in a predetermined cycle, (D3) when voltage is applied, the liquid crystal in each of the first portion and the second portion is aligned in a direction orthogonal to (A) the first substrate and (B) the second substrate, and (E) a phase change in which a terahertz wave transmitted through the terahertz wave control element is independent of the state of polarization.

Terahertz wave control element

A photoreactive liquid crystal composition containing (A) a photoreactive polymer liquid crystal which includes a photoreactive side chain in which at least one type of reaction selected from (A-1) photocrosslinking and (A-2) photoisomerization occurs, and (B) a low molecular weight liquid crystal. An optical element or display element is formed having a liquid crystal cell including the photoreactive liquid crystal composition.

Photoreactive liquid crystal composition, display element, optical element, method for manufacturing display element, and method for manufacturing optical element

Provided is a liquid crystal display element that can be baked at a low temperature when forming a liquid crystal alignment film capable of imparting an alignment regulating property and a pretilt angle developing property via a photoalignment method. Further provided is a liquid crystal display element in which the liquid crystal pretilt angles are highly stable, and display burn-in hardly occurs even due to long usage. Further provided are a vertical liquid crystal alignment film to be used in the liquid crystal display element, and a liquid crystal aligning agent with which it is possible to provide the vertical liquid crystal alignment film. A liquid crystal aligning agent of the present invention contains: component (A), which is a polymer including (A-1) a site having an isocyanate group and/or a blocked isocyanate group and (A-2) a site having photoreactivity; component (B), which is a compound having, in a molecule, at least two functional groups of at least one type selected from the group consisting of an amino group and a hydroxyl group; and an organic solvent.

Liquid crystal aligning agent containing crosslinking agent and polymer that has site having isocyanate group and/or blocked isocyanate group and site having photoreactivity, liquid crystal alignment film, and liquid crystal display element

The present invention relates to a liquid crystal aligning agent which contains a polymer that has a site having an isocyanate group and/or a blocked isocyanate group, a site having a photoreactive group having photoalignment, and a site having at least one functional group selected from an amino group and a hydroxyl group in each molecule. The present invention provides a liquid crystal display element which enables baking at low temperatures during the formation of a liquid crystal alignment film by a photoalignment method, the liquid crystal alignment film being able to be imparted with alignment regulating property and pretilt angle developing property.

Liquid crystal aligning agent, liquid crystal alignment film and liquid crystal display element

The present invention provides the following: a photo alignment method-use liquid crystal aligning agent used to obtain a photo alignment method-use liquid crystal alignment film that does not cause bright spots even when negative liquid crystals are used, and that is capable of achieving good after-image characteristics; a liquid crystal alignment film obtained from the liquid crystal aligning agent; and a liquid crystal display element provided with the liquid crystal aligning agent. Provided is the liquid crystal aligning agent which contains a polyimide or polyimide precursor obtained from a reaction between: a tetracarboxylic acid dianhydride represented by formula (1) (in the formula, Xis as set forth in the present specification) or a derivative thereof; and a diamine component that contains a diamine represented by formula (2) (in the formula, R, Zand n are as set forth in the present specification).

A retardation material-forming resin composition for providing an orientation material that has high photoreaction efficiency and with which a polymerizable crystal can be aligned in a highly sensitive manner. A retardation material-forming resin composition being thermally curable wherein including a resin (component (A)) having a photo-aligning group to which a thermally reactive moiety is bonded directly or connected via a linking group; an orientation material obtained by use of the composition, and a retardation material formed by use of a cured film obtained from the composition.

Retardation material-forming resin composition, orientation material, and retardation material

A cured-film formation composition suitable to form a cured film having liquid-crystal alignment properties. A cured-film formation composition including a component (A) that is one or more monomers having a group having a photo-alignment moiety and thermally reactive moiety, and a polymerizable group; component (B) that is at least one polymer selected from the group of components (B-1) to (B-3) (the component (B-1) being a polymer having, in a quantity of at least two of at least one group selected from the group of hydroxy group, carboxyl group, amide group, amino group, an alkoxysilyl group and group of Formula (2), component (B-2) being a polymer capable of thermally reacting with thermally reactive moiety of component (A) and is self-cross-linkable, and component (B-3) being a melamine formaldehyde resin); and component (C) that is a cross-linking agent; and an orientation material and retardation material which are formed of the cured-film formation composition.

Cured film formation composition, orientation material and retardation material

A retardation material-forming resin composition for providing an orientation material that has high photoreaction efficiency and with which a polymerizable liquid crystal can be aligned in a highly sensitive manner. A retardation material-forming resin composition being thermally curable wherein including a resin (component (A)) having a photo-aligning group to which a thermally reactive moiety is bonded directly or connected via a linking group; an orientation material obtained by use of the composition, and a retardation material formed by use of a cured film obtained from the composition.

A cured-film formation composition that includes: (A) one or more compounds having a photo-aligning group and hydroxy group, etc.; (B) a polymer having at least one substituent from the group of a hydroxy group, carboxy group, amino group, and alkoxysilyl group, and the like; and (C) a cross-linking agent. Component (A) contains a compound having a group of Formula [1] below as the photo-aligning group: where Aand Aare independently a hydrogen atom or methyl group; and Ais a hydroxy group. A cured-film is formed from the cured-film formation composition, and orientation material is formed by use of photo-alignment technique. A retardation material is obtained by applying a polymerizable liquid crystal on the orientation material and curing it.

Cured film formation composition, orientation material, and retardation material

A cured-film formation composition to form a cured film having excellent liquid-crystal alignment properties, orientation material, and retardation material by use of the orientation material. A cured-film formation composition includes: (A) one or more compounds having a photo-aligning group and hydroxy group, etc.; (B) a polymer having at least one substituent from the group of a hydroxy group, carboxy group, amino group, and alkoxysilyl group, and the like; and (C) a cross-linking agent, the component (A) contains at least a compound having a group of Formula [1] below as the photo-aligning group: (in the Formula, Aand Aare independently a hydrogen atom or methyl group; and Ais a hydroxy group, etc.). A cured-film is formed from the cured-film formation composition, and orientation material is formed by use of photo-alignment technique. A retardation material is obtained by applying a polymerizable liquid crystal on the orientation material and curing it.

To provide a liquid crystal aligning agent useful to obtain a liquid crystal alignment film excellent in liquid crystal alignment properties, alignment controlling power and rubbing resistance, having high voltage retention characteristics and having reduced charge accumulation, and a liquid crystal display device which is less susceptible to display failure, to lowering of contrast or to image persistence. A liquid crystal aligning agent comprising a low resistance polyimide precursor having a volume resistivity of from 1&#xd7;10to 1&#xd7;10&#x3a9;cm when formed into a film, and a high alignment polyimide precursor or polyimide having a specific structure, and a liquid crystal display device employing this liquid crystal aligning agent.

Liquid crystal aligning agent and liquid crystal display device employing it

To provide a liquid crystal aligning agent useful to obtain a liquid crystal alignment film which exhibits a high voltage retention characteristic even under high temperature conditions and which has a low accumulation charge, and a liquid crystal display device which is less susceptible to lowering of contrast or to image persistence. A liquid crystal aligning agent comprising at least one selected from a polyamic acid obtained by reactive polymerization of a tetracarboxylic dianhydride component with a diamine component, and a polyimide obtained by cyclodehydration of the polyamic acid, characterized in that at least part of the tetracarboxylic dianhydride component is a tetracarboxylic dianhydride having an alicyclic structure or an aliphatic structure, and at least part of the diamine component is a diamine represented by the following formula (1): (wherein two among Rto Rare primary amino groups, and the rest are hydrogen atoms or monovalent organic groups other than primary amino groups, provided that they may be the same or different from one another), and a liquid crystal display device having a liquid crystal alignment film obtained from this liquid crystal aligning agent.

Material for liquid crystal aligning and liquid crystal displays made by using the same

A liquid crystal aligning agent capable of forming a liquid crystal alignment film having favorable electrical characteristics, and excellent in the storage stability and the productivity.

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Funabashi, Japan

Kohei Goto