E.i. Dupont De Nemours and Company

Hoechst Aktiengesellschaft

Vianova Resins, Inc.

Herberts Ag

Klausjoerg Klein

Heinz-Peter Katzmann

Horst Lehmann

Gabriele Buettner

Markus A Schafheutle

Achim Voelker

Susanne Wehner

Helmut Hoenig

Manfred Valtrovic

Rudolf Schipfer

Georg Pampouchidis

Karl-Friedrich Doessel

Herbert Matzer

Hartmut Foedde

Norbert David

Klaus-Peter Doebler

Johann Hirtl

Walter Kuehhirt

Ludwig Siever

Erik Bambach

Klaus-Peter Lorenz

A process for producing a CED coating by cathodic electrodeposition of a coating on an electrically conductive substrate in a CED coating bath and thermal cross-linking of the CED coating film obtained, wherein before thermal cross-linking outside of the CED coating bath, the CED coating film is brought into contact with an aqueous preparation of at least one metal compound, wherein the at least one metal compound is a compound of a metal with an oxidation number of +2 or higher and is selected from the group consisting of compounds containing cations of the metal, compounds forming cations of the metal in aqueous medium, compounds containing cations containing the metal, compounds forming cations containing the metal in aqueous medium, compounds comprising outwardly neutral complexes of the metal, colloidal oxide of the metal and colloidal hydroxide of the metal, wherein the metal itself is selected from the group consisting of metals having atomic numbers of 20 to 83 with the express exclusion of chromium, arsenic, cadmium, antimony, mercury, thallium and lead.

Process for producing coatings on electrically conductive substrates by cathodic electrodeposition coating

A process for the production of coated substrates comprising the successive steps of:

Process for the production of coated substrates

Waterborne cathodic electrodeposition (CED) coating agents comprising resin solids and optionally pigments, fillers, organic solvents and conventional coating additives, wherein said CED coating agents comprise at least one bismuth salt selected from the group consisting of bismuth hydroxycarboxylic acid salts and bismuth sulfonic acid salts in a quantity of 0.1 to 2.5 wt-%, calculated as bismuth and relative to resin solids content, together with at least one compound selected from the group consisting of yttrium and neodymium compounds in a quantity of 0.1 to 1 wt-%, calculated as metal and relative to resin solids content.

Cathodic electrodeposition coating agents containing bismuth salts together with yttrium and/or neodymium compounds, production and use thereof

Waterborne cathodic electrodeposition (CED) coating compositions comprising resin solids and optionally pigments, fillers and conventional coating additives, wherein said CED coating compositions comprise at least one bismuth compound in a quantity of 0.1 to 2.5 wt. %, calculated as bismuth and relative to resin solids content, together with at least one dicarboxylic acid selected from among acyclic dicarboxylic acids with 3 to 7 carbon atoms and dicarboxylic acids with 8 to 10 carbon atoms comprising a cyclic structural unit in a quantity of 3 to 15 equivalent-%, relative to the acid equivalents present in the CED coating composition.

Cathodic electrodeposition coating compositions containing bismuth compounds and dicarboxylic acids, production and use thereof

A process for the production of a CED (cathodic electrodeposition) coating with improved adhesion towards subsequent layers by cathodic electrodeposition of a coating layer of a CED coating composition onto an electrically conductive substrate and thermal curing by baking in an indirectly heated circulating air oven operated with a proportion of fresh air in the circulating air of the oven of 0 to 20 vol. %, wherein the CED coating composition used contains at least one water-soluble metal nitrate corresponding to a quantity of 1 to 10 mmol of nitrate per 100 g of resin solids content, wherein the metal is selected from the group consisting of metals of atomic numbers 20 to 83, with the exception of chromium, arsenic, rubidium, ruthenium, rhodium, palladium, cadmium, antimony, caesium, osmium, iridium, platinum, mercury, thallium and lead, and wherein at most 50 area-% of the CED-coated substrate surface are rinsed with water prior to thermal curing.

Cathodic electrodeposition coating agent containing 0.1 wt-% to 5 wt-%, based on the resin solids, of at least one polymer having an acid value of 20 to 100 mg KOH/g and a content of lateral and/or terminal aliphatic C5-C14-hydrocarbon radicals of 40 wt-% to 80 wt-%.

Cathodic electrodeposition coating agents

Process for electrocoating bulk articles

A two-component concentrate which includes an aqueous dispersion of a cathodically depositable binder having groups comprising active hydrogen that are cross-linkable using blocked polyisocyanate, as the binder component, and an anhydrous, organic solution of an oxime-blocked isocyanate-functional adduct of aromatic polyisocyanate and at least one compound comprising at least one group capable of addition towards isocyanate and at least one tertiary amino group, as the cross-linking component is used for the preparation of cathodic electrodeposition coating compositions.

Concentrate suitable for the preparation of cathodic electrodeposition coating compositions

A process for preparing a multi-layer coating on an electrically conductive automotive body or an electrically conductive automotive body part by applying a cathodic electrodeposition coating layer, optionally a further coating layer and an outer clear coating, in which the cathodic electrodeposition coating layer of a cathodic electrodeposition coating composition is applied which, as the cathodic electrodeposition binder, contains a seed polymer with an amine value of 30 to 100 mg KOH/g and a hydroxyl value of 50 to 200 mg KOH/g, which can be prepared by radical polymerisation of 70 to 97 wt-% of a monomer mixture comprising hydroxy-functional olefinically unsaturated monomer and amino-functional olefinically unsaturated monomer in the presence of 3 to 30 wt-% of an aminoepoxy resin.

Process for preparing multi-layer coatings on automotive bodies or automotive body parts

A process for coating three-dimensional, electrically conductive substrates by applying a coating layer of a stoving coating composition substantially only to the exterior surfaces of the substrates at a layer thickness sufficient to electrically insulate such surfaces, stoving the coating layer and then coating the interior surfaces with an electrodeposition coating composition, wherein the stoving coating composition is characterised by a volume resistivity from 10 to 10 Ohm&middot;cm of applied and stoved coating layers of said composition.

Process for coating three-dimensional electrically conductive substrates

Cathodic electrodeposition coating compositions containing, in addition to conventional self-cross-linking or external cross-linking film-forming binders as well as optionally cross-linking agents, pigments, extenders, additives conventionally used in coating agents and solvents, from 0.1 to 5 wt-%, based on the resin solids content of the coating compositions, of one or more sulphonamides, when coated on a galvanized surface, produce coatings that are substantially free of pinholes.

Cathodic electrodeposition coating compositions and process for using same

Cationic polyurethane-based polymer dispersions

Catalysts useful for the curing of, for example, cataphoretic deposition coating materials, including water-soluble bismuth compounds and an epoxy-amine adduct, the preparation of the bismuth compound involving acid being employed in a quantity such that there are less than 2 mol of dissociable protons per mole of bismuth.

Bismuth catalysts useful for curing of cataphoretic deposition coating

Aqueous baths for electrophoretic lacquering containing binding agents capable of cathodic deposition and containing as additives for enhancing surface appearance, in particular as anti-cratering agents,

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Wuppertal, Germany

Klausjoerg Klein