Degussa Aktiengesellschaft

Klaus Hentschel

Klaus Huthmacher

Herbert Tanner

Hans-Joachim Hasselbach

Friedhelm Geiger

Marcel Vingerhoets

Marc Samson

Martin Korfer

Jose Vanrobaeys

Klaus Willigerodt

Karl-Ludwig Weber

Ferdinand Theissen

Sven-Peter Mannsfeld

Baudouin Halsberghe

Manfred Schmidt

Ralf Goedecke

Knut Ehrhardt

Michael Kissner

Rolf-Dieter M&ouml;ller

Cyanuric chloride moldings, especially tablets and flakes, have advantages over powders in ease of handling. The moldings are produced by droplet or strip application of molten cyanuric chloride on to a surface and dissipation of the latent heat of fusion by cooling the surface or contacting the melt applied as droplets or strips with a cooling gas.

Process for the production of cyanuric chloride moldings

A process for the preparation of methionine or a salt of methionine by reaction of the components 3-methylmercaptopropionaldhyde, hydrogen cyanide, ammonia and carbon dioxide or components from which the above-mentioned components can be prepared, optionally in the presence of water, to 5-(2-methylmercaptoethyl)-hydantoin and further reaction thereof to methionine or the salt thereof, characterised in that the reaction of the components is initiated by means of at least one premixture in such a way that a first mixture is formed containing at least the predominant proportion (at least 5/10) of the 3-methylmercaptopropionaldeyde and at least 1/10 of the hydrogen cyanide component or corresponding quantities of components from which these components can be prepared, and less than 5/10 of one of the components ammonia, carbon dioxide or of the components from which ammonia or carbon dioxide can be prepared, and in that this first mixture is combined with the other component(s) for the reactive conversion to 5-(2-methylmercaptoethyl)-hydantoin, wherein this (these) latter component(s) may be premixed in one or more other mixtures.

Process for the preparation of D,L-methionine or the salt thereof

The invention relates to aqueous solutions of sodium salts of trimercapto-s-triazine whose molar saturation concentration at 0.degree. C. to 40.degree. C. is above the saturation concentration of trimercapto-s-triazine trisodium salt (TMT-Na.sub.3). More than two but less than three hydrogen atoms of the trimercapto-s-triazine are replaced by sodium ions. The solutions preferably contain trimercapto-s-triazine disodium salt (TMT-Na.sub.2) in addition to a little TMT-Na.sub.3. Surprisingly, the water solubility of TMT-Na.sub.2 is greater than that of TMT-Na.sub.3. The solutions represent a suitable supply form for the active substance trimercapto-s-triazine (TMT-H.sub.3) used in the separation of heavy metals The preparation takes place by means of reacting TMT-Na.sub.3 with TMT-H.sub.3 in a molar ratio of 1:greater than 0-less than 0.5, especially 1:0.1 to 1:&lt;0.5 in aqueous solution.

Aqueous solutions of sodium salts of trimercapto-s-triazine, their

The disodium salt of trimercapto-s-triazine hexahydrate (TMT-Na.sub.2.6H.sub.2 O) which has a considerably higher water solubility than previously known TMT sodium salts. It is used for separating heavy metals from aqueous phase, especially from waste water. TMT-Na.sub.2.6H.sub.2 O is prepared by reacting TMT-Na.sub.3 .9H.sub.2 O, available from cyanuric chloride, with trimercapto-s-triazine (TMT-Ha.sub.3) in a molar ratio of 2-2.1 to 1 in aqueous medium with subsequent crystallization of the TMT-Na.sub.2 .6H.sub.2 O.

Disodium salt of trimercapto-s-triazine hexahydrate, and method of its

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Rodenbach, Germany

Klaus Hentschel