Mitsui Toatsu Chemicals, Incorporated

Mitsui-Nisso Corporation

Kiyotsugu Asai

Masayuki Kamiyama

Toshihiko Kawabata

Tsukuru Izukawa

Ariko Nishikawa

Tamotsu Kunihiro

Masaaki Aoki

Akihiro Yamaguchi

Takashi Saito

Kazunori Takaguchi

Shigeru Yatsugi

Toshiyuki Ichikawa

Mayumi Tani

Kiyou Fukuda

High concentration-low viscosity polymer-polyols are prepared by polymerizing mixtures of acrylonitrile and styrene in polyols, which are free of any polymerizable carbon-carbon double bond, in the presence of alkyl-substituted tertiary amines. Without use, as a dispersion stabilizer, of organic compounds which have a polymerizable carbon-carbon double bond and terminal hydroxyl groups, there can be obtained polymer-polyols which have a concentration of the polymer of 33-60 wt % and a glass transition temperature of the polymer of 90.degree.-120.degree. C.

Polyurethane foam prepared from high concentration-low viscosity

High concentration-low viscosity polymer-polyols are prepared by polymerizing mixtures of acrylonitrile and styrene in polyols, which are free of any polymerizable carbon-carbon double bond, in the presence of alkyl-substituted tertiary mines. Without use, as a dispersion stabilizer, of organic compounds which have a polymerizable carbon-carbon double bond and terminal hydroxyl groups, there can be obtained polymer-polyols which have a concentration of the polymer of 33-60 wt % and a glass transition temperature of the polymer of 90.degree.-120.degree. C.

Polymer-polyol, process for preparation thereof and uses thereof

This invention relates to a novel polyaldimine, preparation process of the polyaldimine, moisture curable polyurethane composition containing the polyaldimine and use of the composition Polyaldimine of this invention is represented by the formula (I): ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are a halogen atom, hydrogen atom, alkoxy group having 4 or less carbon atoms or an alkyl group having 5 or less carbon atoms, and may be the same or different; R.sup.4 is a hydrogen atom or a methyl group; Y is --N.dbd.CH--C(R.sup.5).sub.3 or --N.dbd.CH--C(CH.sub.3).sub.2 --CH.sub.2 --O--CO--R.sup.6 wherein R.sup.5 is an alkyl having 4 or less carbon atoms, R.sup.6 is an alkyl group, anilino group, benzylamino group or an alkylamino group having 16 or less carbon atoms; and l is an integer of 1 or 2, m is an integer of 1 to 3, and n is an integer of 0 to 300. Polyaldimine is prepared by condensation of the corresponding aromatic polyamine and aldehyde. A moisture curable polyurethane composition is prepared from the above polyaldimine and organic polyisocyanates. Sealing materials, wall covering materials, water proof materials and flooring materials can be prepared by blending thixotropic agents or fillers with the polyurethane composition. These materials have very good storage stability and are rapidly cured by atmospheric moisture and cured polyurethane resin having excellent properties can be obtained.

Polyaldimine derivatives

.beta.-amino-.beta.-propiolactam derivative and moisture curable

A super-soft polyurethane elastomer is prepared by reacting an organic polyisocyanate in the presence of a specified organometallic catalyst, with a molar ratio specified mixture of (a) low molecular weight triol and high molecular weight polyol, or (b) low molecular weight triol, aromatic ring containing low molecular weight diol and high molecular weight polyol.

Process for preparing thermally stable super-soft polyurethane elastomer

A thermosetting polyurethane resin which when used as a one-pack surface-protective coating agent for glass bottles, inorganic vessels, and the like exhibits excellent mechanical strength, appearance, and water resistance at sterilization temperatures of about 90.degree. C. is obtained by interacting: (a) 10 to 40% by weight of at least two polyoxyalkylene polyols based on the weight of the nonvolatile matter of the thermosetting polyurethane resin, said at least two polyoxyalkylene polyols including 1 to 8% by weight relative to the nonvolatile matter of the thermosetting polyurethane resin of a nonionic surface active agent selected from the group consisting of a polyoxyethylene glycol or a polyoxyethylene-polyoxypropylene glycol, and mixtures thereof, (b) a monofunctional isocyanate-blocking agent, (c) a chain-elongating agent, (d) a cross-linking agent, and (e) a mixture of methylene-bis (4-cyclohexylisocyanate) and iso-phorone diisocyanate at a molar ratio in the range of from 1:0.3 to 1:1.5.

Thermosetting polyurethane resin and coating agent thereof prepared from

An aqueous dispersed urethane composition which is excellent in film-forming property and useful in protecting glass bottles when formed into a film can be obtained by producing a urethane oligomer by interacting a polyoxyalkylene glycol having a molecular weight equal to or above 1200, a low molecular weight chain-elongating agent selected from a glycol, an amino-alcohol and a diamine each having a molecular weight below 500, an isocyanate-blocking agent selected from an oxime, a lactam and an alcohol, and a diisocyanate, and dispersing the urethane oligomer and a hardener in water by the use of a surface active agent such that the sum by weight of the surface active agent contained in the aqueous dispersed urethane composition and the polyoxyalkylene glycol which is one of the starting materials for the production of the urethane oligomer is in the range of 15 to 35% of the sum by weight of the surface active agent, the urethane oligomer and the hardener.

Method of coating glass bottle with aqueous dispersed urethane

A thixotropic urethane-base sealing material comprising a base polymer selected from the group consisting of a urethane prepolymer and a mixture thereof with a polyol, prior to being hardened, colloidal silica or bentonite used as an anti-sag agent, and an additive used in synergistic combination with the anti-sag agent selected from the group consisting of a sulfoxide expressed by the formula

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Aichi, Japan

Kiyotsugu Asai