Nissan Chemical Industries Limited

Kiyomi Ozawa

Shigeru Ishii

Masayoshi Hirose

Masataka Hatanaka

Yasuyuki Nakajima

Makoto Tsugeno

Mamoru Hayashi

Kiminori Hirata

Masaki Kudo

Ryoichi Nonaka

Kenji Makino

Yasuo Kawamura

Yoshinori Ochiai

Yoshihiro Iwasawa

Gojyo Sakata

Jun Sato

Masayuki Ogawa

Shigekatu Okamoto

Hiroki Takahashi

Eizo Katakura

Pyrazoline derivatives useful as insecticides having the formula ##STR1## wherein X represents a hydrogen atom or a halogen atom; Y represents a halogen atom, a trifluoromethyl group or --A--R'; R represents a C.sub.1-10 alkyl group, a lower alkenyl group or a lower alkynyl group; and A represents an oxygen atom, a sulfur atom, a sulfinyl group or a sulfonyl group and R' represents a halogen-substituted lower alkyl group.

Insecticidal

Fluorine substituted pyridine methyl esters having the formula ##STR1## wherein R represents ##STR2## in which X is chlorine or difluoromethoxy; Y is chlorine or tert-butyl; and Z is a halogen atom, are novel compounds which are useful as insecticides and acaricides.

Fluorine substituted pyridine methyl esters and insecticidal and

Novel phenoxypicolinic aldehydes, namely, 6-(4'-difluoromethoxyphenoxy)picolinic aldehyde and 5-fluoro-6-phenoxypicolinic aldehyde.

Phenoxypicolinic aldehydes

Pyrazoline derivatives useful as insecticides having the formula ##STR1## wherein R.sup.1 represents hydrogen atom, a lower alkyl group, (CH.sub.2).sub.n CN group, (CH.sub.2).sub.n OR group, phenyl group or a halogen-substituted phenyl group; R.sup.2 represents hydrogen atom or methyl group; Y represents hydrogen atom or chlorine atom; X represents oxygen atom, sulfur atom, sulfinyl or sulfonyl group; R.sup.3 represents a halogen-substituted lower alkyl group; and n is integer 1 to 3 and R represents a lower alkyl group.

Insecticidal 3-difluoromethoxyphenyl-1-phenylcarbamoyl-2-pyrazolines

This invention relates to a heterocyclic ether or thioether linkage containing urea compounds of the following formula I: ##STR1## wherein B denotes an oxygen atom or a sulfur atom, A denotes CH or a nitrogen atom, X.sup.1 and X.sup.2 denote independently of each other hydrogen atom, halogen atom, trifluoromethyl group or nitro group, Y and Z denote independently of each other hydrogen atom or halogen atom, and P and Q denote independently of each other hydrogen atom, halogen atom, alkoxyl group or alkyl group, a process for producing the same and an insecticide containing the same.

Benzoazine ether or thioether linkage containing urea compounds, process

Ketone derivatives represented by the general formula (I) ##STR1## where R is --CH.sub.2 R.sup.1 (where R.sup.1 is a hydrogen atom or an alkyl group), a halogen-substituted alkyl group, a cyano-substituted alkyl group, a cyclopropyl group, ##STR2## (where R.sup.2 is a hydrogen atom or an alkyl group and Y is a hydrogen atom or a halogen atom) or ##STR3## (where R.sup.3 is a hydrogen atom, an alkyl group, a phenyl group or a halogen-substituted phenyl group, and Z is a hydrogen atom or a halogen atom), and X is an oxygen atom or a sulfur atom.

Phenyl ketone derivatives

Pyrazoline derivatives having the formula ##STR1## wherein R.sup.1 represents hydrogen atom, a lower alkyl group, phenyl group or a halogen-substituted phenyl group; R.sup.2 represents hydrogen atom or phenyl group which can have halogen substituents; X represents oxygen or sulfur atom; Y and Z respectively represent hydrogen atom, a halogen atom, a lower alkyl group, a lower alkoxy group, nitro-group, trifluoromethyl group, a lower alkylthio group, an acyl group, nitrile group or a lower alkyl sulfonyl group.

Insecticidal pyrazoline derivatives and composition

A process for producing 6-phenoxypicolinic aldehydes, which comprises reacting a 2-halogeno-6-phenoxypyridine represented by the general formula I: ##STR1## where X is a halogen atom, Y is independently an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms substituted by a halogen atom, an alkylthio group of 1 to 4 carbon atoms, a trifluoromethyl group, a fluorine atom or a chlorine atom, Z is a hydrogen atom or a fluorine atom, and n is an integer of 0 to 2, with magnesium metal, and then with a formylating reagent. These compounds are used as intermediates for the synthesis of insecticides.

Process for producing 6-phenoxypicolinic aldehydes

Phenylcyclopropane carboxylic acid derivatives having the formula ##STR1## wherein X represents hydrogen or a halogen atom, C.sub.1-5 alkyl group C.sub.1-5 alkoxy group, trifluoromethyl, cyclopropyl, tri-lower alkylsilyl, lower alkylthio or cyano group; Y represents hydrogen atom or cyano group; and R represents ##STR2## are novel compounds which are useful as insecticides and acaricides.

Insecticidal and acaricidal phenylcyclo-propane carboxylic acid

Phenylcyclopropane carboxylic acid derivatives having the formula (I) ##STR1## wherein X represents a C.sub.2 -C.sub.10 straight or branched alkyl group, are novel compounds having excellent acaricidal effect.

Acaricidal compounds of cyclopropane carboxylic acid derivatives

A phenoxypyridine derivative having the formula

Phenoxypyridine derivatives

Insecticidal compounds having the formula ##STR1## wherein X and Y are the same or different and represent a hydrogen or a halogen atom, methyl group, a lower alkoxy group, trifluoromethyl group, phenoxy group or X and Y form ##STR2## group except both of X and Y are hydrogen atoms.

Insecticidal compounds of phenylcyclopropane carboxylic acid esters

Soil fungi-inhibiting agent containing as the active ingredient one or more of the compounds represented by the following general formula ##STR1## wherein I. WHEN BOTH X and Y are oxygen atoms, Z is hydrogen atom, unsubstituted alkyl group, unsubstituted alkenyl group, ##STR2## (in this case the compound is p-toluene sulfonate), NH.sub.2 CH.sub.2 -- (in this case the compound is p-toluene sulfonate), acyl group, ClCH.sub.2 CONH--, or alkyl group substituted by substituents such as R.sub.1 COO--, CH.sub.3 COS--, R.sub.2 O--, R.sub.2 S--, HO--, HOOC--, CH.sub.3 CONH--, acyl group, alkoxyacyl group, where R.sub.1 is lower-alkyl group or alkenyl group, R.sub.2 is lower-alkyl group or benzyl group;

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Funabashi, Japan

Kiyomi Ozawa