Panasonic Intellectual Property Management Co., Ltd.

Panasonic Corporation

Kiyohiro Isii

Akira Kano

Ryohei Miyamae

Kensuke Nakura

Junichi Sakamoto

Hideki Shimamoto

Susumu Nomoto

Yasuyuki Ito

Nao Matsumura

Takuma Asari

Chiho Nobumori

Atsuro Shirakami

Shotaro Doi

Junko Fujisawa

A lithium secondary battery includes an electrode group and a nonaqueous electrolyte having lithium ion conductivity. A negative electrode includes a negative electrode current collector. The negative electrode current collector has a first surface facing an outward direction of winding of the electrode group and a second surface facing an inward direction of the winding of the electrode group. Lithium metal is deposited on the first surface and the second surface by charge. The negative electrode further includes first protrusions protruding from the first surface and second protrusions protruding from the second surface. A ratio A/Ais greater than a ratio A/A. Ais a sum of projected areas of the first protrusions on the first surface. Ais an area of the first surface. Ais a sum of projected areas of the second protrusions on the second surface. Ais an area of the second surface.

Lithium secondary battery including nonaqueous electrolyte having lithium-ion conductivity

A lithium secondary battery comprises an electrode group and a nonaqueous electrolyte having lithium-ion conductivity. A negative electrode current collector has a first surface facing outward of winding of the electrode group and a second surface facing inward of the winding of the electrode group. At least the first surface or the second surface includes a first region and a second region that is closer to an innermost circumference of the winding of the electrode group than the first region. Protrusions include outer-circumference-side protrusions disposed on the first region and inner-circumference-side protrusions disposed on the second region. In at least the first surface or the second surface, a first area rate is larger than a second area rate.

A lithium metal secondary battery includes a positive electrode, a negative electrode, a separator, and a nonaqueous electrolyte. The positive electrode and the negative electrode are wound to form an electrode group. The positive and negative electrodes face each other with the separator between the positive and negative electrodes. The electrode group has a space for accommodating at least part of the nonaqueous electrolyte when fully discharged. X and Y satisfy 1.00&#x2264;X/Y&#x3c;1.20, where X is a calculated thickness of the lithium metal which is calculated from design capacity per unit area of the positive electrode, and Y is a virtual thickness of the space when the space is assumed to be formed only between the negative electrode and the separator.

Lithium metal secondary battery and method for producing the same

A method for manufacturing an electrochemical device includes the following steps: a step of preparing a positive electrode, the positive electrode including a first current collector and a positive electrode layer containing a conductive polymer; a step of preparing a negative electrode, the negative electrode including a second current collector and a negative electrode layer; and a step of sealing the positive electrode, the negative electrode, and an electrolytic solution in an exterior body. The step of preparing the positive electrode includes a step of holding the positive electrode in depressurized atmosphere and then introducing gas containing COas a primary component into the depressurized atmosphere.

Method for manufacturing electrochemical device, and electrochemical device

A lithium secondary battery includes an electrode group and a nonaqueous electrolyte having lithium ion conductivity. A negative electrode includes a negative electrode current collector. The negative electrode current collector has a first surface facing an outward direction of winding of the electrode group and a second surface facing an inward direction of the winding of the electrode group. Lithium metal is deposited on the first surface and the second surface by charge. The negative electrode further includes first protrusions protruding from the first surface and second protrusions protruding from the second surface. A ratio A/Ais less than a ratio A/A. Ais a sum of projected areas of the first protrusions on the first surface. Ais an area of the first surface. Ais a sum of projected areas of the second protrusions on the second surface. Ais an area of the second surface.

Lithium secondary battery incuding nonaqueous electrolyte having lithium-ion conductivity

A lithium secondary battery comprises an electrode group and a nonaqueous electrolyte having lithium-ion conductivity. A negative electrode current collector has a first surface facing outward of winding of the electrode group and a second surface facing inward of the winding of the electrode group. At least the first surface or the second surface includes a first region and a second region that is closer to an innermost circumference of the winding of the electrode group than the first region. Protrusions include outer-circumference-side protrusions disposed on the first region and inner-circumference-side protrusions disposed on the second region. In at least the first surface or the second surface, a first area rate is smaller than a second area rate.

A lithium secondary battery comprises an electrode group and a nonaqueous electrolyte having lithium-ion conductivity. A negative electrode current collector has a first surface facing outward of winding of the electrode group and a second surface facing inward of the winding of the electrode group. At least the first surface or the second surface includes a first region and a second region that is closer to an innermost circumference of the winding of the electrode group than the first region. Protrusions include outer-circumference-side protrusions disposed on the first region and inner-circumference-side protrusions disposed on the second region. A first average height of the outer-circumference-side protrusions is smaller than a second average height of the inner-circumference-side protrusions.

A lithium secondary battery includes a wound electrode group and a lithium-ion conductive nonaqueous electrolyte. The wound electrode group includes a positive electrode, a negative electrode, and a separator between the positive electrode and the negative electrode. The negative electrode includes a negative electrode current collector. The negative electrode current collector includes: a layer having a first surface facing outward of the winding of the electrode group and a second surface facing inward of the winding of the electrode group; first protrusions protruding from the first surface; and second protrusions protruding from the second surface. Lithium metal is deposited on the first surface and the second surface by charging. A second average height of the second protrusions is higher than a first average height of the first protrusions.

Lithium secondary battery including lithium-ion conductive nonaqueous electrolyte

A lithium secondary battery comprises an electrode group and a nonaqueous electrolyte having lithium-ion conductivity. A negative electrode current collector has a first surface facing outward of winding of the electrode group and a second surface facing inward of the winding of the electrode group. At least the first surface or the second surface includes a first region and a second region that is closer to an innermost circumference of the winding of the electrode group than the first region. Protrusions include outer-circumference-side protrusions disposed on the first region and inner-circumference-side protrusions disposed on the second region. A first average height of the outer-circumference-side protrusions is larger than a second average height of the inner-circumference-side protrusions.

A lithium secondary battery includes a wound electrode group and a lithium-ion conductive nonaqueous electrolyte. The wound electrode group includes a positive electrode, a negative electrode, and a separator between the positive electrode and the negative electrode. The negative electrode includes a negative electrode current collector. The negative electrode current collector includes: a layer having a first surface facing outward of the winding of the electrode group and a second surface facing inward of the winding of the electrode group; first protrusions protruding from the first surface; and second protrusions protruding from the second surface. Lithium metal is deposited on the first surface and the second surface by charging. A first average height of the first protrusions is higher than a second average height of the second protrusions.

A capacitor electrode includes a collector, and an electrode layer disposed in contact with the collector and capable of inserting and releasing cations. The electrode layer includes first carbon material particles capable of inserting and releasing cations and second carbon material particles capable of inserting and releasing cations. The average particle diameter of primary particles of the second carbon material particles is smaller than the average particle diameter of primary particles of the first carbon material particles. In the electrode layer, the content amount of the second carbon material particles is smaller than the content amount of the first carbon material particles.

Electrode for capacitor and capacitor using same

A negative electrode for an electrochemical capacitor includes a current collector having electric conductivity, and an electrode layer formed on a surface of the current collector and having cations stored therein. In at least a part of the electrode layer, a value of ratio I/Iof peak value Iindicating a presence of an anion decomposition compound and peak value Iindicating a presence of an electrolyte in a spectrum of an atom forming the anion is 0.45 or more and less than 2.55 as measured using X-ray photoelectron spectroscopy.

Electrode for electrochemical capacitor and electrochemical capacitor using same

The present invention provides an electrolyte highly reliable in charge and discharge in a high voltage condition, and an electrochemical capacitor using the same. The electrolyte of the present invention includes a solvent, an electrolyte salt having an anion having a perfluoro alkyl group represented by a following composition formula, and an acid inducing substance having a fluorine atom for an anion, characterized in that the weight ratio of the acid inducing substance is in a range of 0.0001 to 2.0 wt %:()](wherein Q is a group 13 or group 15 element in the periodic table, Ris a perfluoro alkyl group (CF), n is a natural number, 1&#x2266;y&#x3c;6, 1&#x2266;z&#x3c;6, Mis a cation of Xth valence, and X is a natural number from 1 to 3). Thereby, since excessive electric potential decline of the negative electrode by the electrolyte salt and destruction of the negative electrode protection film by HF are restrained at the same time, deterioration of the cycle characteristics is restrained even in the case of charge and discharge in a high temperature or high voltage condition.

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Osaka, Japan

Kiyohiro Isii