Nec Corporation

Other

Kiyohiko Toyama

Masatoshi Iji

Shukichi Tanaka

Midori Shimura

Kunihiko Ishihara

Toshie Miyamoto

Mina Shimizu

Makoto Soyama

Yutaro Shimode

A cellulose derivative having a long-chain organic group having 5 or more carbon atoms and a short-chain organic group having 4 or less carbon atoms which are introduced by use of hydroxy groups of a cellulose, and including a crystal structure derived from a cellulose derivative portion to which the short-chain organic group is linked, wherein an average number of hydroxy groups per glucose unit is of 1.0 or less.

Cellulose derivative and resin composition for molding

A cellulose resin composition comprising a cellulose derivative and a lubricant, wherein the cellulose derivative is an acylated cellulose obtained by substituting at least a part of hydrogen atoms of hydroxy groups of a cellulose with an acyl group having 2 to 4 carbon atoms, and the content of the lubricant is in the range of 0.1 to 10% by mass. A cellulose resin composition capable of forming a molded body having a high-quality appearance and scratch resistance is provided.

Cellulose resin composition, molded body and product using same

A cellulose resin composition comprising a cellulose derivative (A) and a lubricant (B), wherein the cellulose derivative (A) is a cellulose derivative obtained by substituting at least a part of hydrogen atoms of hydroxyl groups of a cellulose with a short-chain organic group having 2 to 4 carbon atoms and a long-chain organic group having 8 to 30 carbon atoms with specific degrees of substitution; the lubricant (B) is at least one selected from the group consisting of a urea compound (B1) having a urea group (&#x2014;NH&#x2014;C(&#x2550;O)&#x2014;NH&#x2014;) and an acyclic aliphatic group having 6 to 33 carbon atoms, an amide compound (B2) having an amide group (&#x2014;C(&#x2550;O)&#x2014;NH&#x2014;) and an acyclic aliphatic group having 6 to 33 carbon atoms, a fatty acid metal salt (B3), and a silicone-based lubricant (B4); and a content of the lubricant (B) is in a range of 0.1 to 10% by mass. A cellulose resin composition capable of forming a molded body having a high-quality appearance and scratch resistance is provided.

Cellulose resin composition, molded body and product using same, and a method for producing cellulose resin composition

A method for producing a cellulose derivative, including reacting a mixed acid anhydride having two particular types of acyl groups with cellulose in the presence of a base catalyst in an organic solvent having an electron pair-donating property to form a cellulose derivative with the two types of acyl groups derived from the mixed acid anhydride, the acyl groups being introduced at hydroxy groups in the cellulose.

Method for producing cellulose derivative, and cellulose derivative

A cellulose resin composition containing a cellulose resin (A) and a high refractive-index organic material (B), in which the cellulose resin (A) is a cellulose derivative obtained by substituting at least part of hydrogen atoms of hydroxy groups of a cellulose with an acyl group having 2 to 4 carbon atoms and a long-chain organic group having 7 or more carbon atoms, and the mass fraction (B/A) of the high refractive-index organic material (B) to the cellulose resin (A) falls within the range of 10/90 to 70/30.

A cellulose derivative obtained by substituting at least part of hydrogen atoms of hydroxy groups of a cellulose with an acyl group having 2 to 4 carbon atoms, a long-chain organic group having 7 or more carbon atoms and a high refractive-index organic group.

Cellulose derivative, cellulose resin composition, molded body and product using same

To provide a cellulose derivative excellent in thermoplasticity, water resistance and strength (elastic modulus, impact strength), a cellulose derivative, which is obtained by introducing a short-chain organic group (acetyl group), a medium-chain organic group having 3 to 5 carbon atoms and a long-chain organic group having 6 to 30 carbon atoms at the following substitution degrees DSs into a cellulose, is used: Short-chain organic group: 0.7&#x2264;DS&#x2264;1.5; Medium-chain organic group: 0.5&#x2264;DS&#x2264;2.0; Long-chain organic group: 0.1&#x2264;DS&#x3c;0.5; and 2.4&#x2264;DS+DS+DS&#x2264;3.

Cellulose derivative and use thereof

Resin compositions according to exemplary embodiments of the present invention are first compositions containing a polylactic acid resin, an aliphatic polyester resin, a surface-treated metal hydrate, and a carbodiimide compound, or second compositions containing a polysiloxane-mixed polyester resin, a phosphorus-containing flame retardant, a metal hydrate and a fluorine-containing polymer in specific ratios.

Polylactic acid resin composition and polyester resin composition, and method for producing the same and molded body thereof

A cellulose resin composition comprising a cellulose resin, a high refractive-index organic material and a carbon black, in which the cellulose resin is an acylated cellulose obtained by substituting at least part of hydrogen atoms of hydroxy groups of a cellulose with an acyl group having 2 to 4 carbon atoms, the carbon black is an acidic carbon black, the mass fraction (B/A) of the high refractive-index organic material (B) to the cellulose resin (A) falls within the range of 10/90 to 70/30, and the content of the carbon black (C) relative to the total of the cellulose resin composition falls within the range of 0.05 to 10% by mass.

A process for producing a cellulose derivative, comprising: a first step including reacting a cellulose and a first reactant comprising a long-chain reactant for reacting with a hydroxy group of the cellulose to introduce a long-chain organic group having 5 or more carbon atoms, in a solid-liquid heterogeneous system, to form a cellulose derivative in a swollen state, the cellulose derivative having the long-chain organic group having 5 or more carbon atoms introduced therein and having a part of hydroxy groups of the cellulose remained, and performing solid-liquid separation to obtain the cellulose derivative as an intermediate; and a second step including reacting the intermediate cellulose derivative and a second reactant comprising a short-chain reactant for reacting with a remaining hydroxy group of the intermediate cellulose derivative to introduce a short-chain organic group having 4 or less carbon atoms to form a final cellulose derivative having the short-chain organic group having 4 or less carbon atoms introduced therein.

Process for producing cellulose derivative and cellulose derivative

A process for producing a cellulose derivative, including reacting a reactant and a cellulose or a derivative thereof in a solid-liquid heterogeneous system to form a cellulose derivative containing a long-chain organic group having 5 or more carbon atoms introduced therein, in a swollen state, and performing solid-liquid separation to obtain the cellulose derivative containing a long-chain organic group introduced therein.

Growing community of inventors

Tokyo, Japan

Kiyohiko Toyama