Sumitomo Metal Mining Company, Ltd.

Akzo Nobel N.v.

Nippon Ketjen Co., Ltd.

Kikoo Uekusa

Satoshi Matsumoto

Toshio Yamaguchi

Kazuomi Ryoshi

Masao Wakabayashi

Hideharu Yokozuka

Eiji Yamaguchi

Yuji Uragami

Takao Suzuki

Yukuaki Mitarai

Tetsuro Kamo

Naoto Kinbara

Eiji Funatsu

Katsuzo Shiraishi

Satoshi Abe

A positive electrode active material precursor for a nonaqueous electrolyte secondary battery is provided that includes a nickel-cobalt-manganese carbonate composite represented by general formula NiCoMnMCO(where x+y+z+t=1, 0.05≤x≤0.3, 0.1≤y≤0.4, 0.55≤z≤0.8, 0≤t≤0.1, and M denotes at least one additional element selected from a group consisting of Mg, Ca, Al, Ti, V, Cr, Zr, Nb, Mo, and W) and a hydrogen-containing functional group. The ratio H/Me of the amount of hydrogen H to the amount of metal components Me included in the positive electrode active material precursor is less than 1.60. The positive electrode active material further includes a secondary particle formed by a plurality of primary particles that have been aggregated.

Positive electrode active material precursor for nonaqueous electrolyte secondary battery and method for manufacturing positive electrode active material precursor for nonaqueous electrolyte secondary battery

A positive-electrode active material precursor for a nonaqueous electrolyte secondary battery is provided that includes a nickel-cobalt-manganese carbonate composite represented by general formula NiCoMnMCO(where x+y+z+t=1, 0.05&#x2264;x&#x2264;0.3, 0.1&#x2264;y&#x2264;0.4, 0.55&#x2264;z&#x2264;0.8, 0&#x2264;t&#x2264;0.1, and M denotes at least one additional element selected from a group consisting of Mg, Ca, Al, Ti, V, Cr, Zr, Nb, Mo, and W) and a hydrogen-containing functional group, wherein H/Me representing the ratio of the amount of hydrogen to the amount of metal components Me included in the positive-electrode active material precursor is greater than or equal to 1.60.

Positive-electrode active material precursor for nonaqueous electrolyte secondary battery and method for manufacturing positive-electrode active material precursor for nonaqueous electrolyte secondary battery

A positive electrode active material precursor for a nonaqueous electrolyte secondary battery is provided that includes a nickel-cobalt-manganese carbonate composite represented by general formula NiCoMnMCO(where x+y+z+t=1, 0.05&#x2264;x&#x2264;0.3, 0.1&#x2264;y&#x2264;0.4, 0&#x2264;t&#x2264;0.1, and M denotes at least one additional element selected from a group consisting of Mg, Ca, Al, Ti, V, Cr, Zr, Nb, Mo, and W) and a hydrogen-containing functional group. The ratio H/Me of the amount of hydrogen H to the amount of metal components Me included in the positive electrode active material precursor is less than 1.60. The positive electrode active material further includes a secondary particle formed by a plurality of primary particles that have been aggregated.

Positive electrode active material precursor for nonaqueous electrolyte secondary battery, positive electrode active material for nonaqueous electrolyte secondary battery, method for manufacturing positive electrode active material precursor for nonaqueous electrolyte secondary battery, and method for manufacturing positive electrode active material for nonaqueous electrolyte secondary battery

Positive-electrode active material precursor for nonaqueous electrolyte secondary battery, positive-electrode active material for nonaqueous electrolyte secondary battery, method for manufacturing positive-electrode active material precursor for nonaqueous electrolyte secondary battery, and method for manufacturing positive-electrode active material for nonaqueous electrolyte secondary battery

Production of spherical catalyst carrier

The invention pertains to a process for activating a hydrotreating catalyst comprising a Group VIII hydrogenation metal and a Group VI hydrogenation metal, which are substantially in the oxide form, on a carrier in which the hydrotreating catalyst is contacted with an additive which is at least one compound selected from the group of compounds comprising at least two hydroxyl groups and 2-10 carbon atoms, and the (poly)ethers of these compounds, after which the catalyst is dried under such conditions that at least 50% of the additive remains in the catalyst. The additive is preferably at least one compound selected from ethylene glycol, diethylene glycol, and polyethylene glycol, or a saccharide or a polysaccharide. The invention additionally pertains to the catalyst obtainable by this process, which shows high activity in hydrodesulphurization and hydrodenitrogenation reactions, and to the use of the catalyst in hydrotreating.

Hydrotreating catalyst: composition, preparation, and use thereof

A process for producing spherical catalyst carrier of silica, silica-alumina composition, zirconia-alumina composition, titania-alumina composition, boria-alumina composition, or boria-silica-alumina composition which has almost the same pore characteristics as alumina hydrate gel, silica-alumina hydrate gel, zirconia-alumina hydrate gel, or titania-alumina hydrate gel (or alumina hydrate paste, boria-alumina hydrate paste, or boria-silica-alumina hydrate paste) as the major raw material, having uniform sphericity and smooth surface and homogeneity, and has a macropore volume that can be controlled includes adding a polysaccharide solution to any of alumina, silica-alumina, zirconia-alumina, or titania-alumina in the form of hydrate gel, or alumina, boria-alumina, or boria-silica-alumina in the form of hydrate paste, mixing them to form a slurry with a controlled concentration, dropping the slurry into a solution containing multivalent metal ions, thereby forming spherical hydrogel, and performing the additional steps of aging, washing, drying, and calcining.

Catalysts for hydrodesulfurization and hydrodenitrogenation of hydrocarbon oils are provided which have high catalytic activity, excellent productivity and low pollution. The catalysts are made from an alumina carrier substance, at least one active metal element selected from the Group VI metals in the periodic table, at least one active metal element chosen from the Group VIII metals in the periodic table, phosphoric acid, and an additive agent. The additive agent is at least one substance selected from dihydric or trihydric alcohols having 2-10 carbon atoms per one molecule, ethers of the alcohols, monosaccharides, disaccharides, and polysaccharides. A method for preparing the catalysts is also provided and includes impregnating the alumina carrier substance with a solution mixed with a certain amount of the active metal elements, phosphoric acid and the additive agent, and drying the impregnated carrier substance at a temperature of less than 200.degree. C.

Catalysts for hydrotreating hydrocarbon oils and method of preparing the

Disclosed is a catalyst for hydrotreating a coal liquefaction and circulation solvent, in which .gamma.-alumina carrier carries at least one metal of Group VI of the Periodic Table in an amount of from 15 to 15% by weight as the oxide thereof and at least one metal of Group VIII of the same Table in an amount of from 3 to 10% by weight as the oxide thereof and the pore distribution as measured by mercury pressure porosimetry satisfies the conditions that the pores having a diameter of from 40 to 600 .ANG. have a mean diameter of from 9 to 150 .ANG. and the capacty of the pores having a diameter falling within the range of the mean diametr plus/minus 10 .ANG. is 65% or more of the capacity of the pores having a diameter of from 40 to 600 .ANG.. The catalyst is highly active for both hydrogenation and denitrogenation of coal-liquefying solvents.

Growing community of inventors

Niihama, Japan

Kikoo Uekusa