Nippon Shokubai Co., Ltd.

Nippon Shokubai Kagaku Kogyo Co., Ltd.

Fuji Photo Film Company, Limited

Kiichiro Mitsui

Kunio Sano

Akira Inoue

Yusuke Shiota

Tohru Ishii

Tooru Ishii

Keniti Shishida

Motonobu Kobayashi

Sadao Terui

Kazuyoshi Nishikawa

Toshihide Kanzaki

Seiji Suzuki

Kiyotaka Hori

Takehiko Suzuki

Hideki Sogabe

Futoru Kinoshita

Junichi Miyake

Yoku Nanba

Toru Ishii

Kuinio Sano

The present invention relates to an apparatus including a pressure layer having an ability of following up the deformation or movement of a packed bed of a solid catalyst and/or solid adsorbent which is provided on the packed bed. Specifically, the present invention relates to an apparatus in which a pressure layer having an ability of following up the deformation of the top surface of the solid catalyst packed bed is provided on the packed bed, or in which a water-permeable pressure layer having an ability of following up the deformation of the solid catalyst packed bed is provided on the packed bed. Such pressure layers are effective in sufficiently preventing the solid catalyst from moving in the packed bed. As a result, there is no problem such as the abrasion of solid catalyst mainly caused by its movement, the deterioration of the performance thereof, and an increase in pressure loss, thereby treating waste water in a stable manner for a long period of time.

Apparatus for treating waste water

An object of the present invention is to provide a simple method which can efficiently convert dioxins and/or PCBs contained in liquid into unharmful substances. Such a method according to the present invention is by introducing a liquid containing dioxins and/or PCBs, and oxygen containing gas to a reactor in which catalystexists, and conducting wet-oxidation reaction under liquid phase condition of the introduced liquid. According to the present inventive method, a simple method which can efficiently extract dioxins, PCBs and/or component containing thereof, from soil may be provide by a method comprising of; contacting soil and/or ash containing dioxins and/or PCBs with a liquid. Further, the present invention provides a method for cleaning the unit used for decomposing or oxidizing dioxins and/or PCBs contained in liquid by introducing cleaning solution to the unit and conducting cleaning operation under liquid phase condition.

Method for decomposing or oxidizing dioxins and/or poly chlorinated biphenyls contained in liquid

A catalyst for the treatment of a waste water comprises an oxide and/or a composite oxide of manganese, the oxide and/or the composite oxide of at least one metal selected from the group consisting of iron, titanium, and zirconium, and optionally a precious metal. A method for the production of this catalyst is also disclosed. A method for the treatment of a waste water comprises subjecting the waste water to wet oxidation treatment with an oxygen-containing gas by the use of a catalyst under pressure such that the waste water retains the liquid phase thereof.

Catalyst for treatment of waste water, method for production thereof and

The present invention provides a catalyst used in wastewater treatment process wherein not only an organic compound not containing nitrogen, sulfur or halogen is decomposed, but also a nitrogen-containing compound, a sulfur-containing compound and an organic halogeno compound are effectively decomposed, thereby wastewater are treated with excellent efficiency for a long period of time. The invention also provides a production process for the catalyst and said wastewater treatment process. The first catalyst comprises: an oxide of iron as an A component; and at least one kind of element as a B component selected from a group consisting of cobalt, nickel, cerium, silver, gold, platinum, palladium, rhodium, ruthenium and iridium. The second catalyst comprises: an oxide as an A component containing iron and at least one kind of element selected from a group consisting of titanium, silicon and zirconium; and at least one kind of element as a B component selected from a group consisting of cobalt, nickel, cerium, silver, gold, platinum, palladium, rhodium, ruthenium and iridium.

Catalyst for treating wastewater, process for producing it, and process

A process for purifying a photographic waste solution is disclosed. The photographic waste solution is purified by successively performing: noncatalytic wet oxidation at a temperature of from 140.degree. C. up to 370.degree. C. under such a pressure as to hold said waste solution in a liquid phase while supplying an oxygen-containing gas thereto; solid-liquid separation of the solid matters and/or suspended matters thus formed; catalytic wet oxidation at a temperature of from 140.degree. C. up to 370.degree. C. under such a pressure as to hold said waste solution in a liquid phase while supplying an oxygen-containing gas thereto; and a biological treatment comprising a combination of an aerobic biological treatment with an anaerobic biological treatment.

Process for treating photographic waste solution

Method for disposing of organohalogen compounds by oxidative

Catalyst for treating wastewater

This invention relates to a catalyst for use in water treatment and to a method for the water treatment by the use of the catalyst. The catalyst comprises a first catalyst component e.g. the oxide of titanium, silicon, aluminum and zirconium, and a second catalyst component e.g. manganese, iron, cobalt, nickel, cerium, tungsten, copper, silver, gold, platinum, palladium, rhodium, ruthenium, and iridium or a sparingly water-soluble compound of the metal.

Catalyst for water treatment

A method for the purification of waste water by the use of a heat-exchanger type reaction vessel composed of a plurality of inner tubes and a shell defining jointly with the outer peripheries of the inner tubes a passage for the flow of a heat transfer medium, which method comprises passing said waste water through said inner tubes and, at the same time, feeding a molecular oxygen-containing gas to the flow of said waste water thereby establishing contact between said waste water and said feed gas and consequently effecting wet oxidation of the impurities present in said waste water.

Method for purification of waste water

A catalyst for the purification of a gas containing ozone or a component of offensive odor is composed of (A) a composite oxide comprising (a) titanium and (b) at least one element selected from the group consisting of Si, Zr, and P and (B) at least one element selected from the group consisting of Mn, Fe, Co, Ni, Ag, Pt, Pd, and Rh.

Method for purification of gas

A method for the treatment of waste water, which comprises wet oxidizing said waste water with a molecular oxygen-containing gas of an amount 1.0 to 1.5 times the amount thereof theoretically necessary for decomposing at least one substance selected from the group consisting of organic substances and inorganic substances present in said waste water to nitrogen, carbon dioxide, and water at a temperature not exceeding 370.degree. C. under a pressure enough for said waste water to retain a liquid phase in the presence of a solid catalyst comprising of a first catalytic component formed of titanium dioxide, a second catalytic component formed of the oxide of an element of lanthanide series, and a third catalytic component containing at least one metal selected from the group consisting of manganese, iron, cobalt, nickel, tungsten, copper, silver, gold, platinum, palladium, rhodium, ruthenium, and iridium or a water-insoluble or sparingly water-soluble compound of said metal.

Method for treatment of waste water

A carrier for a waste gas-treating catalyst, comprising an inorganic refractory oxide containing a composite oxide of titanium and zirconium possessing a crystalline structure of ZrTiO.sub.4, which is produced by heat-treating a substance containing a titanium compound and a zirconium compound at a temperature in the range of 600.degree. to 1,000.degree. C., and a catalyst for treatment of a waste gas comprising the carrier deposited a catalytically active component.

Carrier for gas-treating catalyst, method for production thereof and

A method for the removal of nitrogen oxides from the exhaust gas of a diesel engine through catalytic reduction by the use of honeycomb catalyst in the presence of ammonia, which method comprises feeding ammonia into said exhaust gas proportionately to the product of the revolution number of said diesel engine multiplied by the torque of said diesel engine.

Method for removal of nitrogen oxides from exhaust gas of diesel engine

Efficient treatment of waste water is accomplished by subjecting the waste water to wet oxidation under continued supply of an oxygen containing gas at a temperature of not more than 370.degree. C. under a pressure enough for the waste water to retain the liquid phase thereof intact, in the presence of a catalyst containing a composite oxide of at least two metals selected from the group consisting of Ti, Si, and Zr and at least one metal selected from the group consisting of Mn, Fe, Co, Ni, W, Cu, Ce, Ag, Pt, Pd, Rh, Ru, and Ir or a compound of the one metal mentioned above.

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Akashi, Japan

Kiichiro Mitsui