Lg Chem, Ltd

Ulsan National Institute of Science and Technology

Unist-academy Industry Research Corporation

Lg Energy Solution, Ltd.

Lg Chemical Ltd.

Unist, Inc.

Ki-Tae Kim

Je-Young Kim

Yo-Han Kwon

Heon-Cheol Shin

Hye-Ran Jung

Hyung-Man Cho

Byung-Hun Oh

Sang-Young Lee

Jaephil Cho

Hyo-Jeong Ha

Sang-Wook Woo

Hyun-Jung Kim

Soon-Ho Ahn

Dong-Sub Jung

Jae-Bum Choo

Byung-Hee Han

Yong-Ju Lee

Pil-Kyu Park

Sang-Hoon Choy

Ki-Young Lee

Hye-Min Ji

Mi-Hee Park

Min-Gyu Kim

Seo-Jae Lee

Young-Sun Park

Byoung-Hoon Ahn

Myoung-Hun Lee

Chan-Soo Jun

Kyung-Taek Kim

Min-Ho Seo

Hye-Jung Kim

Jae-Phil Cho

Yo- Han Kwon

Jae-Won Lg Chem Reasearch Park Lee

Won-Seok Chang

Ou-Jung Kwon

Won-Seok Rm 402 Jungwon Jutaek Chang

Sco-Jae Lee

Complex particles for a negative electrode active material according to the present disclosure have no problem with reduced capacity and output by virtue of sufficient electrochemical reaction sites between a solid electrolyte and an electrode active material. The complex particles according to the present disclosure include carbon particles of a carbon material such as flaky graphite, which are spherical in shape by shape modification, and a solid electrolyte and a conductive material filled between the particles, and thus have the increased contact area between the active material and the solid electrolyte increases, and ion conduction and electron conduction paths extended and maintained to the inside of the active material particles.

Complex particles for negative electrode active material and negative electrode for all-solid type battery comprising the same

The present invention relates to an anode active material for a lithium secondary battery, comprising a carbon material, and a coating layer formed on the surface of particles of the carbon material and having a plurality of Sn-based domains having an average diameter of 1 &#x3bc;m or less. The inventive anode active material having a Sn-based domains coating layer on the surface of a carbon material can surprisingly prevent stress due to volume expansion which generates by an alloy of Sn and lithium. Also, the inventive method for preparing an anode active material can easily control the thickness of the coating layer.

Anode active material for lithium secondary battery and preparation thereof

Provided is a method for manufacturing an anode of a cable-type secondary battery having a solid electrolyte layer, including preparing an aqueous solution of an anode active material, making an anode by immersing a core as a current collector having a horizontal cross section of a predetermined shape and extending longitudinally in the aqueous solution, then applying an electric current to form a porous shell of the anode active material on the surface of the core, and forming a solid electrolyte layer on the surface of the anode by passing the anode through a solid electrolyte solution. The anode has a high contact area to increase the mobility of lithium ions, thereby improving battery performance. Also, the anode is capable of relieving stress and pressure in the battery, such as volume expansion during charging and discharging, thereby preventing battery deformation and ensuring battery stability.

Anode of cable-type secondary battery and manufacturing method thereof

An anode active material for a lithium secondary battery and a lithium secondary battery having the same are disclosed. The anode active material for a lithium secondary battery includes a silicon alloy consisting of silicon and at least two kinds of metals other than silicon, each having the heat of mixing with the silicon of &#x2212;23 kJ/mol or less. The anode active material for a lithium secondary battery has a high capacity, and thus, is useful in fabricating a high-capacity lithium secondary battery. Also, the anode active material for a lithium secondary battery has a small crystal size of a silicon phase and consequently a small change in volume during charging/discharging, and thus, ensures excellent cycle life characteristics in applications to batteries.

Anode active material for lithium secondary battery and lithium secondary battery having the same

The present invention relates to a method for preparing a negative-electrode active material for rechargeable lithium battery, wherein the negative-electrode active material comprises a core comprising material capable of doping and dedoping lithium; and, a carbon layer formed on the surface of the core, wherein the carbon layer has a three dimensional porous structure comprising nanopores regularly ordered on the carbon layer with a pore wall of specific thickness placed therebetween. In some embodiments, the method comprises modifying a material capable of doping and dedoping lithium with an organic functional group, mixing the modified material with an inorganic oxide, heating the mixture, and removing the inorganic oxide to form the negative-electrode active material.

Negative-electrode active material for rechargeable lithium battery

Disclosed is an anode for a lithium secondary battery. The anode includes a current collector in the form of a wire and a porous anode active material layer coated to surround the surface of the current collector. The three-dimensional porous structure of the active material layer increases the surface area of the anode. Accordingly, the mobility of lithium ions through the anode is improved, achieving superior battery performance. In addition, the porous structure allows the anode to relieve internal stress and pressure, such as swelling, occurring during charge and discharge of a battery, ensuring high stability of the battery while preventing deformation of the battery. These advantages make the anode suitable for use in a cable-type secondary battery. Further disclosed is a lithium secondary battery including the anode.

Anode for cable-type secondary battery and cable-type secondary battery including the anode

The present invention relates to negative-electrode active material for a lithium secondary battery exhibiting excellent capacity property and cycle life property, a method of preparing the same, and a lithium secondary battery using the negative-electrode active material, wherein the negative-electrode active material for a lithium secondary battery comprises a nanotube having a tube shape defined by an outer wall with a thickness of nanoscale, the outer wall of the nanotube comprises at least one non-carbonaceous material selected from the group consisting of silicon, germanium and antimony, and an amorphous carbon layer with a thickness of 5 nm or less is formed on the outer wall of the nanotube.

Negative-electrode active material for lithium secondary battery and method of preparing the same

Provided is a cable-type secondary battery including an inner electrode comprising at least two anodes arranged in parallel that extend longitudinally and have a horizontal cross section of a predetermined shape, an electrolyte layer serving as an ion channel surrounding the inner electrode, an outer electrode comprising a tubular cathode having a horizontal cross section of a predetermined shape and surrounding the electrolyte layer, and a protection coating surrounding the outer electrode. The cable-type secondary battery has free shape adaptation due to its linearity and flexibility. A plurality of inner electrodes within a tubular outer electrode leads to an increased contact area therebetween and consequently a high battery rate. It is easy to control the capacity balance between the inner and outer electrodes by adjusting the number of inner electrodes.

Cable-type secondary battery

Disclosed is an electrolyte for an electrochemical device. The electrolyte includes a composite of a plastic crystal matrix electrolyte doped with an ionic salt and a crosslinked polymer structure. The electrolyte has high ionic conductivity comparable to that of a liquid electrolyte due to the use of the plastic crystal, and high mechanical strength comparable to that of a solid electrolyte due to the introduction of the crosslinked polymer structure. Further disclosed is a method for preparing the electrolyte. The method does not essentially require the use of a solvent. Therefore, the electrolyte can be prepared in a simple manner by the method. The electrolyte is suitable for use in a cable-type battery whose shape is easy to change due to its high ionic conductivity and high mechanical strength.

Electrolyte for electrochemical device, method for preparing the electrolyte and electrochemical device including the electrolyte

The present invention provides a method of preparing a negative active material for a rechargeable lithium battery, comprising the steps of: mixing a silicon precursor, a surfactant comprising an ammonium halide salt having a organic group, an initiator, and a solvent; heat-treating the mixture; cooling the heat-treated mixture to room temperature; washing the cooled, heat treated mixture; and calcining the washed product.

Method of preparing negative active material containing a carbon-coated silicon core for a rechargeable lithium battery and a rechargeable lithium battery

The present invention relates to a cable-type secondary battery comprising an inner electrode comprising at least two anodes arranged in parallel, the anode extending longitudinally and having a horizontal cross section of a predetermined shape, the anode having an electrolyte layer thereon serving as an ion channel; an outer electrode comprising a cathode including a cathode active material layer surrounding the inner electrode; and a protection coating surrounding the outer electrode. The cable-type secondary battery has free shape adaptation due to its linearity and flexibility. A plurality of inner electrodes within a tubular outer electrode lead to an increased contact area therebetween and consequently a high battery rate. It is easy to control the capacity balance between the inner and outer electrodes by adjusting the number of inner electrodes. A short circuit is prevented due to the electrolyte layer formed on the inner electrode.

An anode active material for a lithium secondary battery includes a silicon alloy that includes silicon and at least one kind of metal other than silicon, the silicon alloy allowing alloying with lithium. A volume of an inactive region in the silicon alloy, which is not reacted with lithium, is 50 to 75% of the entire volume of an active material. The anode active material has a large capacity in comparison to carbon-based anode active materials, and also ensures small volume expansion and high capacity retention ratio after charging/discharging, resulting in excellent cycle characteristics.

A method for manufacturing a cable-type secondary battery includes: preparing a first polarity current collector having a long and thin shape; forming at least two first polarity electrode active material layers on the first polarity current collector to be spaced apart from each other in the longitudinal direction; forming an electrolyte layer to surround the at least two first polarity electrode active material layers; forming at least two second polarity electrode active material layers on the electrolyte layer to be spaced apart from each other at positions corresponding to the first polarity electrode active material layers; forming an electrode assembly by surrounding the second polarity electrode active material layers with a second polarity current collector; surrounding the electrode assembly with a cover member; and bending the electrode assembly and the cover member into a serpentine configuration with the active regions spaced apart from one another.

Cable-type secondary battery and method for manufacturing the same

Growing community of inventors

Daejeon, South Korea

Ki-Tae Kim