Gas Research Institute

Gas Technology Institute

Kevin Krist

Ashok V Joshi

Yousheng Shen

Anil Vasudeo Virkar

Meilin Liu

Estela T Ong

Chakravarthy Sishtla

Anthony F Sammells

Ralph T Yang

Dale M Taylor

Randy Petri

Dave Goodwin

John R Jewulski

Joe Pondo

Michael J Boettcher

A direct carbon fuel cell having an anode electrode of carbon particles pre-wetted with carbonate, a cathode electrode, and an electrolyte layer disposed between the anode electrode and the cathode electrode and containing a molten carbonate. The fuel cell includes a wicking feature whereby excess carbonate produced during the operation of the fuel cell is removed. The use of carbonate pre-wetted carbon particles as the anode provides a network of empty voids, facilitating the removal of COgas from the cell, thereby enhancing fuel cell performance.

Direct carbon fuel cell with pre-wetted carbon particles

A method for separation of molecular hydrogen from a gaseous mixture containing the molecular hydrogen, which method employs a dense mixed oxide ion/electronic/hydrogen atom conducting membrane or separator having a feed side and a permeate side that enables two mechanisms for hydrogen separation&#x2014;ambi-polar conduction and hydrogen atom conduction. In this method, at least a portion of the molecular hydrogen is converted on the feed side of the membrane to hydrogen atoms, which hydrogen atoms are conducted through the membrane to the permeate side thereof where they are converted back to molecular hydrogen. The permeate side of the membrane is contacted with steam, forming water and/or steam on the feed side of the membrane and additional molecular hydrogen on the permeate side of the separator.

Hydrogen separation process using mixed oxide ion/electronic/hydrogen atom conducting membranes

A generally planar, rectangular solid oxide fuel cell stack having a plurality of fuel cell units, each of the fuel cell units having an anode, a cathode and an electrolyte disposed there between, at least one bipolar separator plate disposed between the anode electrode of one fuel cell unit and the cathode electrode of an adjacent fuel cell unit, an oxidant manifold for delivering oxidant to the cathode electrode, a fuel manifold for delivering fuel to the anode electrode, an anode exhaust gas removal manifold for removing anode exhaust gases from the solid oxide fuel cell stack, and a cathode exhaust gas removal manifold for removing cathode exhaust gases from the solid oxide fuel cell stack. At least one ducted gas flow panel is disposed proximate the fuel cell stack and configured in combination with the fuel cell stack to preheat oxidant gas flowing therethrough and, thus, maintain the fuel cell stack in an operational condition without supplemental heating of the oxidant after entering the at least one ducted gas flow panel.

Gas flow panels integrated with solid oxide fuel cell stacks

Selective and thermally reversible adsorption of NO.sub.x from a mixture of hot gases is achieved by contact with an adsorbent of active copper in the form of CuO on a support of TiO.sub.2 and SiO.sub.2 and in the form of Cu.sup.+2 on a support of pillared clay.

Selective nitrogen oxides adsorption from hot gas mixtures and thermal

Enhancement of mechanical properties of ceramic membranes by introduction of a uniformly distributed high-temperature oxidation-resistant metal phase into the brittle ceramic phase to achieve mechanically strong ceramic/metal composites operable in an oxidation atmosphere and at elevated temperatures.

Enhancement of mechanical properties of ceramic membranes and solid

Composite ceramic mixed ionic and electronic conducting materials having high ambipolar activity which can be fabricated into thin membranes for high efficiency oxygen separation from air at intermediate temperatures. The mixed conducting materials have composite non-homogeneous microstructures of a separate predominantly oxygen ion conductive phase and a predominantly electronic conductive phase. Preferred predominantly oxygen ion conducting phases include bismuth, cerium and zirconium oxide based materials and predominantly electronic conducting phases include at least one metal electronic conductor material.

Mixed ionic-electronic conducting composites for oxygen separation and

A composite ceramic mixed oxygen ion and electronic conducting materials having high ambipolar activity which can be fabricated into thin membranes for high efficiency oxygen separation from air at intermediate temperatures. The mixed conducting materials have composite non-homogeneous microstructures of a separate predominantly oxygen ion conductive phase and a predominantly electronic conductive phase. Predominantly oxygen ion conducting phases include bismuth, cerium and thorium oxide based materials and predominantly electronic conducting phases include at least one metal, metal oxide of at least one metal, and at least one perovskite-type electronic conductor material.

Composite mixed ionic-electronic conductors for oxygen separation and

Mixed oxygen ion and electronic conducting bismuth oxide based ceramic materials having high ambipolar activity which can be fabricated into thin membranes for high efficiency oxygen separation from air at intermediate temperatures. The ceramic materials may be homogeneous microstructures in the form of solid solutions or compounds or may be composite non-homogeneous microstructures of a separate substantially continuous oxygen ion conductive phase and a substantially continuous electronic conductive phase.

Mixed ionic-electronic conductors for oxygen separation and

A solid electrolyte electrochemical cell and process for concurrent gas phase electrocatalytic oxidative dimerization of methane at one side of the solid electrolyte and reduction of carbon dioxide to gaseous hydrocarbon products at the opposite side of the solid electrolyte. The electrochemical cell may use a solid electrolyte of an oxygen vacancy conducting type or a proton transferring type capable of transferring any proton mediating ion.

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Palatine, IL, United States of America

Kevin Krist