Eastman Chemical Company

Southwall Technologies Inc.

Massachusetts Institute of Technology

Svaya Nanotechnologies, Inc.

Kevin C Krogman

Lee Campbell Boman

Anthony Brian Port

Michael Hawkins

J Wallace Parce

Benjamin Wang

Kayur Ashwin Patel

Brija Nand

Paula T Hammond

Melissa Fardy

Siglinde Schmid

David Olmeijer

James Yancy Farrow

David Lee Honeycutt

Jeremy L Isbell

Nicole S Zacharia

Bruce Robert Lang

Daniel Lewis Hodder

Yuriy Borisovich Matus

Gregory C Rutledge

Thomas Workman

Julius G Kozak

Jeremy B Stegall

William Edward Jarvis

Genichi Minase

Rajul Shah

Randall M Hill

Jung Ah Lee

Thomas Fong

Steven D White

Tom Hood

Ralph Peter Schultz

Timofey Gerasimov

Yuriy Matus

Optical products are disclosed that include a polymer substrate; a composite coating, deposited on the polymer substrate; a permeating adhesive, which permeates the composite coating and is in contact with the polymer substrate; and a protective layer, secured to the composite coating by the permeating adhesive. The composite coating includes at least a first layer and a second layer, each of which is provided with a binding group component which together form a complementary binding group pair. The optical products exhibit improved resistance to delamination during storage and use.

Laminated optical products and methods of making them

Optical products that include a composite coating, deposited on a substrate, provided with at least one bilayer having a first layer and a second layer, each provided with a binding group component which together form a complementary binding group pair. The at least one bilayer comprises a pigment blend that includes: a) at least two pigments that, when mixed together and formed into a bilayer, exhibit a color reflection value that is less than about 2.5; and b) one or more pigments that when mixed and formed into a bilayer selectively block visible light in a wavelength range of interest.

Selective light-blocking optical products having a neutral reflection

Optical products that comprise a composite coating having multiple bilayers of a first layer and a second layer, each provided with a binding group component which together form a complementary binding group pair, the multiple bilayers comprising: at least one bilayer a) comprised of a first pigment or pigment blend that exhibits a color reflection value that is less than about 2.5; at least one bilayer b) comprised of a pigment or pigment blend that selectively blocks visible light in a wavelength range of interest; and at least one bilayer c) comprised of a second pigment or pigment blend that exhibits a color reflection value that is less than about 2.5, wherein the optical product selectively blocks visible light in the wavelength range of interest, while exhibiting a color reflection value that is less than about 2.5.

Optical products are disclosed that include a polymeric substrate, provided with an infrared-reflective metal layer on an outer surface thereof that is subject to oxidation. The optical products are further provided with a protective coating, comprising one or more of a metal oxide or a metal nitride, deposited directly on the infrared-reflective metal layer using chemical vapor deposition. The optical products are further provided with a composite pigment coating, deposited on the protective coating, that include at least a first layer and a second layer, at least one of which layers comprises a first pigment, wherein each of the first layer and the second layer includes a binding group component, each of which binding group components together form a complementary binding group pair.

Infrared-rejecting optical products having pigmented coatings

An electromagnetic energy-absorbing optical product useful as a composite for coloring an opaque article such as a paint composite or car wrap is disclosed. The electromagnetic energy-absorbing optical product includes a polymeric substrate and a composite coating with the composite coating including first and second layers each containing a binding group component which together form a complimentary binding group pair.

Electromagnetic energy-absorbing optical product and method for making

An electromagnetic energy-absorbing optical product useful particularly for automotive and architectural window films is disclosed. The electromagnetic energy-absorbing optical product includes a polymeric substrate and a composite coating with the composite coating including first and second layers each containing a binding group component which together form a complimentary binding group pair.

The disclosure provides methods and materials for preparing a titania nanoparticle product. For example, titania nanoparticle products having desirable optical properties such as a desirable refractive index are prepared according to the methods provided herein.

Synthesis of metal oxide, titania nanoparticle product, and mixed metal oxide solutions

Traditional solar control applications rely on thin metal films to reflect EM radiation with wavelengths longer than that of the visible spectrum. Unfortunately such films also block radiation in cellular, GPS, and radio frequency bands. In one aspect, the disclosure provides a selectively-blocking filter that uses one or more optical filters tuned to a specific range(s) of wavelengths (e.g. for blocking IR radiation), while readily transmitting other wavelengths (e.g. both visible light and cellular/GPS signals). The filters can be manufactured on both flexible and rigid substrates.

Broadband solar control film

The invention provides materials and methods for forming coatings on substrates. The coatings are durable and resistant to damage from environmental, chemical, thermal, and/or radiative sources. In some embodiments, the coatings comprise bilayers of electrostatically charged materials. The bilayers are created by alternately applying solutions comprising water-soluble, electrostatically charged materials. Durability is imparted to the coatings by the formation of crosslinks that are formed within and between layers after deposition of the coatings.

Methods and materials for functional polyionic species and deposition thereof

The disclosure provides materials, apparatuses, and methods for making multilayer coatings with a high degree of efficiency and control. In some aspects, for example, coatings are described having multiple layers of nanoparticles and a polyelectrolyte, wherein the nanoparticles form tightly packed monolayers. The interface between monolayers may include polyelectrolyte material. One or more aspects of such monolayers and interfaces are controllable.

Methods, materials and apparatus for improving control and efficiency of layer-by-layer processes

One aspect of the invention relates to a method of preparing metal oxide coated substrates for various potential applications, and the coated substrate formed thereby.

Highly reactive multilayer assembled coating of metal oxides on organic and inorganic substrates

The present invention comprises an automated apparatus capable of spray depositing polyelectrolytes via the LbL mechanism with minimal or no human interaction. In certain embodiments, the apparatus sprays atomized polyelectrolytes onto a vertically oriented substrate. To counteract the effects of irregular spray patterns, the substrate is preferably slowly rotated about a central axis. In certain embodiments, the apparatus also includes a forced pathway for the droplets, such as a pathway created by using a vacuum. In this way, a thicker or three-dimensional substrate can be coated. In certain embodiments, the apparatus is designed so as to be scalable. Thus, through the use of multiple instantiations of the apparatus, a large or irregularly shaped substrate can be coated. Rolls of textile can therefore be coated using the apparatus. Additionally, the present invention includes a method to uniformly coat a substrate, such as a hydrophobic textile material, using aqueous solutions of polyelectrolytes.

Automated layer by layer spray technology

The invention provides methods for modifying one or more properties of porous thin films. In such methods, a formulation comprising a reactive species is applied to the porous thin film and allowed to crosslink. In some embodiments, the crosslinked network thus formed imparts increased mechanical strength and wear resistance to the porous thin films.

Growing community of inventors

Santa Clara, CA, United States of America

Kevin C Krogman