Daidousanso Co., Ltd.

Daido Hoxan Inc.

Maizuru Kogyo Co., Ltd.

Maizura Kogyo Co., Ltd.

Kenzo Kitano

Masaaki Tahara

Haruo Senbokuya

Teruo Minato

Tadashi Hayashida

Akira Yoshino

Takakazu Tomoda

Massaki Tahara

Akio Hashigami

Takashi Muraoka

Masaki Tahara

A method of carburizing austenitic stainless steel comprising the steps of holding austenitic stainless steel in a fluorine- or fluoride-containing gas atmosphere with heating prior to carburizing and carburizing the austenitic stainless steel at a temperature not more than 680.degree. C. wherein said austenitic stainless steel is stable austenitic stainless steel having 1 to 6 weight % molybdenum or 13 to 25 weight % chromium, wherein a carburized hard layer having corrosion resistance superior to base material forms and austenitic stainless steel products obtained thereby.

Method of carburizing austenitic stainless steel and austenitic

A method of nitriding steel which comprises reacting the steel surface with nitrogen so as to form a hard nitrided layer, and, prior to nitriding, holding steel under a gas atmosphere containing fluorine compound gas or fluorine gas and also containing air of 0.5 to 20 volume % of the total or oxygen gas of 0.1 to 4 volume % of the total with heating, whereby occurrence of uneven nitriding is prevented and at the same time savings in consumption of expensive fluorine- or fluoride-containing gas can be realized.

Method of nitriding steel

A method of carburizing austenitic metal comprising the steps of holding austenitic metal in a fluoride-containing gas atmosphere with heating prior to carburizing and carburizing the austenitic metal at a temperature not more than 680.degree. C. and austenitic metal products obtained thereby.

Method of carburizing austenitic metal

A method for carburizing austenitic metal comprising fluorinating the austenitic metal and consecutive carburizing at a low temperature not more than 680.degree. C. A carburizing temperature can be lowered by such a fluorination. As a result, carbide of chrome component in the austenitic metal can be prevented from depositing. That is, much chrome component remains in the austenitic metal. Therefore, the austenitic metal surface can be hardened and also superior anti-corrosion property can be maintained.

The present invention relates to nickel alloy products with their surfaces nitrided and hardened which are formed by pressure casting nickel alloy material, and nitrided and hardened layers are formed in surface layers. Since the nitrided and hardened surfaces of the nickel alloy products according to the invention have much better corrosion resistance than iron products have, anticorrosion treatment such as plating is not required, and rich lubricity and excellent tightening property can be obtained without having seizure and scuffing phenomena.

Process of producing nitrided and hardened nickel alloy products

This invention allows to form a nitrided hard layer on the surface of an austenitic stainless steel screw by forming a nitrided layer thereon and to prevent causing rust on some parts such as a screw head portion which is in contact with the outside air by removing the nitrided hard layer to expose austenitic stainless steel base which has sufficient corrosion resistance. On the contrary, in a thread part and the like of the screw, the nitrided hard layer is left and to thereby improves hardness and the like to strengthen tapping functions and the like of the screw. In the method for manufacturing the austenitic stainless steel screw according to the invention, the austenitic stainless steel screw is held in a fluorine- or fluoride-containing gas atmosphere prior to nitriding to form a fluorided film on its surface and then is nitrided in that state. Accordingly, so formed nitrided hard layer becomes uniform and deep to obtain an austenitic stainless steel screw having excellent surface properties.

Hard austenitic stainless steel screw and a method for manufacturing the

A loom guide bar blade for automatic weaving machinery such as an air or water jet loom wherein the surface of the blade which contacts yarn is nitrided to form a nitrided hardened layer. When this blade is used in automatic high-speed weaving machinery, wearing and the like at contacting points of the blade with the yarn are prevented. As a result yarn fluffing from its being abraded by a roughened blade surface is minimized.

Loom guide bar blade with its surface nitrided for hardening

Nickel alloy products with their surfaces nitrided and hardened

This invention allows the surface of an austenitic stainless steel screw surface to be formed into a hard nitrided layer so as to harden and a part such as a screw head which is in contact with outside air is removed its own ultra hard surface layer in the hard nitrided layer by scouring or the like to be rust preventive. Even if the ultra hard surface layer is thus removed, an inner hard layer in the hard nitrided layer is present beneath the surface layer to be able to maintain a hard state of the screw surface. In the method for manufacturing the austenitic stainless steel screw according to the invention, upon forming said hard nitrided layer on the screw surface by nitriding, the austenitic stainless steel screw surface is cleaned with a fluorine- or fluoride-containing gas prior to nitriding. Thereby remained foreign matter, oxidized layer and the like on the screw surface are removed and at the same time the screw surface is activated and so N atoms easily penetrate and diffuse when nitriding to form a uniform nitrided layer.

The surface layer of a hard austenitic stainless steel screw is formed as nitrided layer and then is covered by a plating coat or a resin coat to give properties such as shortening the boring time as well as heightening the surface hardness of the screw itself.

Hard austenitic stainless steel screw

Nitrided stainless steel products having a base material of stainless steel containing austenitic stainless steel. At least a portion of the surface layer of the base material is composed of a nitrided hard layer in accordance with the following conditions (A) and (B):

Nitrided stainless steel products

Upon forming a plating coat on steel works, the works are held in a fluorine- or fluoride-containing gas atmosphere in a heated condition to thereby remove oxidized scales such as SiOx, MnOx and the like on the surface layer of the work and to form a fluoride layer to prevent forming new oxidized scale. The fluoride layer is easily eliminated by an action of added flux to a plating bath or by heating the fluorinated steel works in an atmosphere containing hydrogen prior to dipping in the plating bath to activate the steel surface. The activated steel surface is improved in compatibility with the plating bath and the like to realize a good quality plating coat formation.

Method of plating steel

A hard nitrided layer is formed on austenitic stainless steel by holding the austenitic stainless steel in a heated condition under a fluorine- or fluoride-containing atmosphere and then nitriding it so that a close uniform nitriding layer can be formed, resulting the remarkable improvement in the surface hardness of the above-mentioned austenitic stainless steel. The temperature in the above-mentioned nitriding treatment is set below 450.degree. C. so that high anti-corrosion property, originally inherent in austenitic stainless steel, can be retained without deterioration.

Method of nitriding austenitic stainless steel products

An austenitic stainless steel screw having a nitride hard layer on its surface to prevent corrosion on parts of the screw such as a screw head which is in contact with the environment by removing a portion of the nitride hard layer to expose austenitic stainless steel base. By contrast, in the thread part and the like of the screw, the nitride hard layer is retained to improve the hardness and the tapping functions of the screw. In the method for manufacturing, the austenitic stainless steel screw is exposed to a fluorine-or fluoride-containing gas atmosphere prior to nitriding to form a fluoride film on its surface and then is nitrided in that state. Accordingly, the so formed nitride hard layer becomes uniform and deep to obtain an austenitic stainless steel screw having excellent surface properties.

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Kawachinagano, Japan

Kenzo Kitano