Texaco Inc.

Kenoth H Flournoy

George Kalfoglou

Joseph T Carlin

Ricardo L Cardenas

William B Braden

Robert B Alston

A method for transporting heavy crude oil through a pipeline which involves introducing into a pipeline or well-bore with the viscous hydrocarbons an aqueous solution containing (1) a sulfonate surfactant, (2) a rosin soap or a naphthenic acid soap and, optionally (3) a coupling agent whereby there is spontaneously formed a low viscosity, salt tolerant, oil-in-water emulsion.

Aqueous surfactant solutions and oil-in-water emulsions

A method for transporting heavy crude oil through a pipeline which involves introducing into a pipeline or well-bore with the viscous hydrocarbons an aqueous solution containing (1) a sulfonate surfactant, (2) a rosin soap or a naphthenic acid soap and, optionally (3) coupling agent whereby there is spontaneously formed a low viscosity, salt tolerant, oil-in-water emulsion. Also disclosed is a method of recovery of hydrocarbons from a hydrocarbon bearing formation employing an aqueous solution containing (1) a sulfonate surfactant, (2) a rosin soap or a naphthenic acid soap and, optionally (3) a coupling agent.

Process for recovering hydrocarbons from a hydrocarbon-bearing formation

A method for transporting viscous hydrocarbons which involves introducing into a pipeline or well-bore with the viscous hydrocarbons a solution containing (1) an anionic surfactant such as sodium tridecyl sulfate, sodium oleate, etc., or an oxyalkylated anionic surfactant of the sulfonate or sulfate type, and mixtures of the surfactants mentioned and (2) an alkalinity agent such as sodium hydroxide, thereby forming a low viscosity, salt-tolerant, oil-in-water emulsion. Optionally, the solution may contain a small amount of a guanidine salt or a water-soluble oxyalkylated, nitrogen-containing aromatic compound such as ethoxylated-8-hydroxy quinoline.

Oil-in-water emulsion

An adjusted salinity and hardness, aqueous preflush containing a thickening material which can be, for example, a hydrophilic material such as polyacrylamide, polysaccharide, polyvinyl aromatic sulfonate, polyethylene oxide, methyl cellulose, etc. or colloidal silica, etc. in a concentration sufficient to increase the viscosity of the adjusted salinity aqueous preflush fluid is injected into a subterranean, petroleum-containing formation. Optionally, the preflush fluid may contain a sacrificial agent, such as sodium tripolyphosphate, etc. The high salinity formation water is efficiently displaced by viscous low salinity aqueous preflush fluid to increase the effectiveness of a subsequently injected high salinity sensitive single surfactant solution. The surfactant may be displaced by a mobility buffer solution, which then may be displaced by water.

Tertiary oil recovery process utilizing a preflush

A method of transporting viscous hydrocarbons which involves introducing into a pipeline or well-bore with the viscous hydrocarbons a solution containing an oxyalkylated anionic surfactant such as sodium nonyl phenol polyoxyethylene sulfonate or a mixture of such surfactants and, optionally, with an alkalinity agent thereby forming a low-viscosity, salt-tolerant oil-in-water emulsion.

Method for transportation of viscous hydrocarbons by pipeline

Oil-in-water emulsions

Solution for transporting hydrocarbons in a pipeline

Pipeline transportation of heavy crude oil

Pipeline method for transporting viscous hydrocarbons

A novel, thickened, miscible flooding medium to displace petroleum in subterranean reservoirs is a dispersion of light hydrocarbons, water and a surfactant system. The water may have from about 1500 to 12,000 parts per million polyvalent ions such as calcium and/or magnesium. The surfactant system comprises a water soluble salt of an alkyl or an alkylaryl sulfonate plus a water soluble salt of an alkyl or alkylaryl polyethoxy sulfate anionic surfactant plus a nonionic surfactant such as a polyethoxylated alkyl phenol, a polyethoxylated aliphatic alcohol or a fatty acid mono or dialkanolamide.

Micellar dispersions with tolerance for extreme water hardness for use

A method of transporting viscous hydrocarbons which involves introducing into a pipeline or well-bore with the viscous hydrocarbons a solution containing an anionic surfactant or soap such as sodium tridecyl sulfate or sodium oleate together with a guanidine salt and optionally with an alkalinity agent and/or a nonionic surfactant such as a polyethoxylated alcohol thereby forming a low viscosity salt tolerant oil-in-water emulsion.

Growing community of inventors

Levelland, TX, United States of America

Kenoth H Flournoy