University of Nevada

Other

Reactive Innovations, LLC

Kenneth R Czerwinski

David W Hatchett

Cassara Higgins

Janelle Droessler

Katherine Luebke

Daniel T Rego

Michael C Kimble

Karen D Jayne

Kyle G Boutin

John Kinyanjui

Cynthia-May S Gong

Frederic Poineau

Described are methods for the recovery of uranium from uranium hexafluoride dissolved directly into ionic liquids.

Conversion of uranium hexafluoride and recovery of uranium from ionic liquids

A process for recovering a rare earth element. The process includes adding water and a nonaqueous acid to an ionic liquid, and dissolving an oxide of a first rare earth element directly into the ionic liquid to form an ionic solution comprising at least about 0.1 weight percent water, the acid and an ion of the first rare earth element. The process further includes applying a potential to the ionic solution to deposit the first rare earth element onto an electrode as a metal.

Processes for recovering rare earth elements

This document provides a dual flask for laboratory use, methods of using a dual flask, and systems including a dual flask. A dual flask can include a first flask structure and a second flask structure. Each flask structure can include a body and a neck. The first body and the second body in a dual flask provided herein can be connected together and have a filter there between such that fluids can be filtered between said first and second bodies.

Dual flask

Uranic and transuranic metals and metal oxides are first dissolved in ozone compositions. The resulting solution in ozone can be further dissolved in ionic liquids to form a second solution. The metals in the second solution are then electrochemically deposited from the second solutions as room temperature ionic liquid (RTIL), tri-methyl-n-butyl ammonium n-bis(trifluoromethansulfonylimide) [MeNBu][TFSI] providing an alternative non-aqueous system for the extraction and reclamation of actinides from reprocessed fuel materials. Deposition of U metal is achieved using TFSI complexes of U(III) and U(IV) containing the anion common to the RTIL. TFSI complexes of uranium were produced to ensure solubility of the species in the ionic liquid. The methods provide a first measure of the thermodynamic properties of U metal deposition using Uranium complexes with different oxidation states from RTIL solution at room temperature.

Room temperature electrodeposition of actinides from ionic solutions

A spent fuel reprocessing method contacts an aqueous solution containing Technetium(V) and uranyl with an acidic solution comprising hydroxylamine hydrochloride or acetohydroxamic acid to reduce Tc(V) to Tc(II, and then extracts the uranyl with an organic phase, leaving technetium(II) in aqueous solution.

Process for the extraction of technetium from uranium

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Kenneth R Czerwinski