Pilot Industries, Inc.

Kenneth J Kuenzel

Edward K Krause

Frederick W Woodward

Jerry J Smith

Described herein is a method of preparing a fluoropolymer composite comprising the steps of activating the fluoropolymer substrate and thereafter applying a layer of a different polymer to the activated fluoropolymer substrate. The activation step can be described as a mixed gas plasma discharge or an electrically formed plasma. Also described herein are other methods of surface activation including exposure to excimer laser, gamma rays, x-ray flux, electron beam, sodium naphthalate bath, coupling or curing agents, and others. In particular, described is a fuel pipe comprised of an inner fluorocarbon layer having electrostatic discharge resistance and hydrocarbon evaporative emission resistance chemically bonded to an outer layer of a cross-linked polyethylene polymer. There is no need for additional adhesives. Fluoropolymer layers have excellent chemical resistance.

Fluoropolymer composite tube and method of preparation

Described herein is a method of preparing a fluoropolymer composite tube comprising the steps of forming a fluoropolymer substrate, and thereafter layering and chemically bonding the fluoropolymer with a polymer layer, preferably a thermosetting or thermoplastic elastomer. The fluoropolymer substrate can be activated by subjecting the substrate to a charged gaseous atmosphere formed by electrically ionizing a gas which contacts the substrate. Thereafter, a layer of a thermosetting or thermplastic elastomer is applied to the activated fluoropolymer substrate resulting in a stronger chemical bond. The ionizing step can be described as a mixed gas plasma discharge or an electrically formed plasma. The thermosetting elastomer can, but does not have to contain a curing agent. In particular, this invention describes a fuel pipe comprised of an inner fluorocarbon layer having electrostatic discharge resistance and hydrocarbon evaporative emission resistance, and on top of and integral with the fluorocarbon layer, an outer layer of a thermosetting or thermoplastic elastomer chemically bonded to the fluorocarbon layer. Fluoropolymer layers have excellent chemical resistance.

Described herein is a method of preparing a fluoropolymer composite comprising the steps of exposing a formed fluoropolymer substrate to a flame, then activating the fluoropolymer substrate by subjecting the substrate to a charged gaseous atmosphere formed by electrically ionizing a gas which contacts the substrate and thereafter applying a layer of a thermoplastic or thermoset polymer to the activated fluoropolymer substrate. The ionizing step can be described as a mixed gas plasma discharge or an electrically formed plasma. Also described herein are other methods of surface activation including exposure to excimer laser, gamma rays, x-ray flux, electron beam, sodium naphthalate bath, and others. In particular, described is a fuel pipe comprised of an inner fluorocarbon layer having electrostatic discharge resistance and hydrocarbon evaporative emission resistance chemically bonded to an outer layer of a thermoplastic or thermoset polymer. There is no need for additional adhesives. Fluoropolymer layers have excellent chemical resistance.

Described herein is a method of preparing a fluoropolymer composite tube comprising the steps of activating a formed fluoropolymer substrate by subjecting the substrate to a charged gaseous atmosphere formed by electrically ionizing a gas which contacts the substrate and thereafter applying a layer of a thermoplastic polymer to the activated fluoropolymer substrate. The ionizing step can be described as a corona discharge or an electrically formed plasma. In particular, described is a fuel pipe comprised of an inner fluorocarbon layer having electrostatic discharge resistance and hydrocarbon evaporative emission resistance and on top of and integral with, the fluorocarbon layer an outer layer of a thermoplastic polymer. Fluoropolymer layers have excellent chemical resistance.

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Grass Lake, MI, United States of America

Kenneth J Kuenzel