Kansas State University Research Foundation

Nanoscale Corporation

Nanoscale Materials, Inc.

Other

United States Air Force

Nantek, Inc.

Kenneth J Klabunde

Olga B Koper

Shawn P Decker

Paul S Malchesky

Abbas Khaleel

Kyle B Knappenberger

Lisa S Martin

Slawomir Winecki

Christopher Sorensen

Bill Sanford

Laura L Hladky

John S Klabunde

Stephen T Hobson

Shyamala Rajagopalan

Erich K Lehnert

Savka Stoeva

Ravichandra S Mulukutla

Ronaldo Maghirang

P Jeevanandam

Craig L Hill

Aaron Ranson

Ernest H Braue, Jr

Douglas A Espin

Mariela G Araujo

Jeffrey T Rhule

Eric Boring

Michael Wayne Sigel

Dajie Zhang

Yuzo Imizu

Bhagavatula L V Prasad

Aleksandr F Bedilo

Corrie L Carnes

Ernest H Braue

Naijian Sun

Compositions and methods for destroying biological agents such as toxins and bacteria are provided wherein the substance to be destroyed is contacted with finely divided metal oxide or hydroxide nanocrystals. In various embodiments, the metal oxide or metal hydroxide nanocrystals have reactive atoms stabilized on their surfaces, species adsorbed on their surfaces, or are coated with a second metal oxide. The desired metal oxide or metal hydroxide nanocrystals can be pressed into pellets for use when a powder is not feasible. Preferred metal oxides for the methods include MgO, SrO, BaO, CaO, TiO, ZrO, FeO, VO, VO, MnO, FeO, NiO, CuO, AlO, SiO, ZnO, AgO, [Ce(NO)&#x2014;Cu(NO)]TiO, Mg(OH), Ca(OH), Al(OH), Sr(OH), Ba(OH), Fe(OH), Cu(OH), Ni(OH), Co(OH), Zn(OH), AgOH, and mixtures thereof.

Reactive nanoparticles as destructive adsorbents for biological and chemical contamination

Methods of reducing smoke levels in smoke-affected areas, reducing the level of toxic compounds produced by fires, fire suppression, and increasing flame retardancy. In particular, methods according to the present invention comprise dispersing nanocrystalline particles in the areas affected by smoke for sorption of smoke particulates and toxic compounds produced from a fire. The nanocrystalline particles are also effective for use in methods of fire suppression and flame retardancy.

Metal oxide nanoparticles for smoke clearing and fire suppression

Compounds and methods for sorbing organosulfur compounds from fluids are provided. Generally, compounds according to the present invention comprise mesoporous, nanocrystalline metal oxides. Preferred metal oxide compounds either exhibit soft Lewis acid properties or are impregnated with a material exhibiting soft Lewis acid properties. Methods according to the invention comprise contacting a fluid containing organosulfur contaminants with a mesoporous, nanocrystalline metal oxide. In a preferred embodiment, nanocrystalline metal oxide particles are formed into pellets () and placed inside a fuel filter housing () for removing organosulfur contaminants from a hydrocarbon fuel stream.

Method of sorbing sulfur compounds using nanocrystalline mesoporous metal oxides

Method for biological and chemical contamination

Novel siloxanes are provided in the form of nanoscale bodies having discrete, observable structures, such as elongated wires, tubes, filaments and coils, having a length of at least about 100 nm and a diameter of from about 2-200 nm. The siloxanes are synthesized by reacting a substituted silane in a solvent system comprising water and a polar organic solvent, and in the presence of a metallic nanoparticle catalyst such as gold.

Siloxanes and methods of synthesis thereof using metallic nanoparticle catalysts

Pelletized adsorbent compositions and methods of adsorbing toxic target compounds are provided for the destructive adsorption or chemisorption of toxic or undesired compounds. The pelletized adsorbents are formed by pressing together powder nanocrystalline particles comprising a metal hydroxide or a metal oxide at pressures of from about 50 psi to about 6000 psi to form discrete self-sustaining bodies. The pelletized bodies should retain at least about 25% of the surface area/unit mass and total pore volume of the starting metal particles.

Porous pellet adsorbents fabricated from nanocrystals

Compositions and methods for destroying chemical and biological agents such as toxins and bacteria are provided wherein the substance to be destroyed is contacted with finely divided metal oxide nanoparticles. The metal oxide nanoparticles are coated with a material selected from the group consisting of surfactants, waxes, oils, silyls, synthetic and natural polymers, resins, and mixtures thereof. The coatings are selected for their tendency to exclude water while not excluding the target compound or adsorbates. The desired metal oxide nanoparticles can be pressed into pellets for use when a powder is not feasible. Preferred metal oxides for the methods include MgO, SrO, BaO, CaO, TiO, ZrO, FeO, VO, VO, MnO, FeO, NiO, CuO, AlO, SiO, ZnO, AgO, the corresponding hydroxides of the foregoing, and mixtures thereof.

Air-stable metal oxide nanoparticles

Composites for destroying chemical and biological agents such as toxins and bacteria, and methods of preparing and using those composites are provided. According to the invention, the substance to be destroyed is contacted with the inventive composites which comprise finely divided metal oxide nanoparticles at least partially coated with carbon. Advantageously, the composites exclude water while not excluding the target compound or adsorbates. The desired metal oxide nanoparticles can be pressed into pellets for use when a powder is not feasible. Preferred metal oxide nanoparticles include MgO, SrO, BaO, CaO, TiO, ZrO, FeO, VO, VO, MnO, FeO, NiO, CuO, AlO, SiO, ZnO, AgO, and mixtures thereof.

Carbon-coated metal oxide nanoparticles

Improved area decontamination products and methods of use thereof are provided which include reactive nanoparticles (e.g., metal oxides, hydroxides and mixtures thereof) with one or more biocides and a liquid carrier for the nanoparticles and biocide(s). The products may be formulated for area decontamination as sprays, fogs, aerosols, pastes, gels, wipes or foams, and the presence of reactive nanoparticles enhances the neutralization of undesirable chemical or biological compounds or agents. The nanoparticles may be from the group consisting of the alkali metal, alkaline earth metal, transition metal, actinide and lanthanide oxides and hydroxides and mixtures thereof. In preferred forms, nanocrystalline oxides and hydroxides of Al, Ca, Ce, Mg, Sr, Sn, Ti and Zn are employed having single crystallite sizes of up to about 20 nm and surface areas of at least about 15 m /g.

Decontaminating systems containing reactive nanoparticles and biocides

A method for removing at least one contaminant selected from the group consisting of H S and CO from contaminating streams, including the steps of providing an above ground stream comprising hydrocarbon containing the at least one contaminant, and positioning metal-containing nanoparticles having a particle size of less than or equal to about 100 nm in the stream, the metal-containing nanoparticles being selected from the group consisting of metal oxides, metal hydroxides and combinations thereof, whereby the nanoparticles adsorb the contaminants from the stream.

Method for removing H2S and CO2 from above ground hydrocarbon streams

Compositions and methods for destroying biological agents such as toxins and bacteria are provided wherein the substance to be destroyed is contacted with finely divided metal oxide or hydroxide nanocrystals. In various embodiments, the metal oxide or metal hydroxide nanocrystals have reactive atoms stabilized on their surfaces, species adsorbed on their surfaces, or are coated with a second metal oxide. The desired metal oxide or metal hydroxide nanocrystals can be pressed into pellets for use when a powder is not feasible. Preferred metal oxides for the methods include MgO, SrO, BaO, CaO, TiO , ZrO , FeO, V O , V O , Mn O , Fe O , NiO, CuO, Al O , SiO , ZnO, Ag O, &lsqb;Ce(NO ) &mdash;Cu(NO ) &rsqb;TiO , Mg(OH) , Ca(OH) , Al(OH) , Sr(OH) , Ba(OH) , Fe(OH) , Cu(OH) , Ni(OH) , Co(OH) , Zn(OH) , AgOH, and mixtures thereof.

A method of forming ligated nanoparticles of the formula Y(Z) where Y is a nanoparticle selected from the group consisting of elemental metals having atomic numbers ranging from 21-34, 39-52, 57-83 and 89-102, all inclusive, the halides, oxides and sulfides of such metals, and the alkali metal and alkaline earth metal halides, and Z represents ligand moieties such as the alkyl thiols. In the method, a first colloidal dispersion is formed made up of nanoparticles solvated in a molar excess of a first solvent (preferably a ketone such as acetone), a second solvent different than the first solvent (preferably an organic aryl solvent such as toluene) and a quantity of ligand moieties; the first solvent is then removed under vacuum and the ligand moieties ligate to the nanoparticles to give a second colloidal dispersion of the ligated nanoparticles solvated in the second solvent. If substantially monodispersed nanoparticles are desired, the second dispersion is subjected to a digestive ripening process. Upon drying, the ligated nanoparticles may form a three-dimensional superlattice structure.

Synthesis of substantially monodispersed colloids

Growing community of inventors

Manhattan, KS, United States of America

Kenneth J Klabunde