Nalco Chemical Company

Kenneth G Phillips

Edward G Ballweber

Wun T Tai

John R Hurlock

Roger H Jansma

Alvin J Frisque

Paul J Harris

Robert A Miller

Lawrence A Mura

Mary E Bingham

Karen A Nordquist

Dodd W Fong

James F Kneller

Manuel Slovinsky

Radhakrishnan Selvarajan

Wood E Hunter

Patrick J Marek

Robert Bernot

John G Premo

Richard F Krebs

A method of rapidly dissolving finely divided individual particles of water-soluble vinyl addition polymers which comprises adding to water which contains from 0.5 to 10% by weight of a water-soluble surfactant, dry particles of a vinyl addition polymer, which particles have been coated with an oil-soluble emulsifier to provide a discrete organic solvent-free coating about such individual particles, having an HLB value between 4 and 9.

Rapid solubilization of dry polymers

A method of producing acrylamide from acrylonitrile in the presence of a metallic conversion catalyst which comprises contacting an oil-in-water emulsion of acrylonitrile, said water phase being the continuous phase and containing up to 7% acrylonitrile and said oil phase being the dispersed phase and containing the remaining acrylonitrile to be converted to acrylamide, whereby a substantial portion of the acrylonitrile is converted to acrylamide which remains in the aqueous phase of the oil-in-water emulsion, and then an additional low HLB emulsifier is added to invert the oil-in-water emulsion to a water-in-oil emulsion containing acrylamide.

Acrylamide synthesis from an oil-in-water emulsion containing

A tire tread adhesive or cement having superior green tack, excellent cured adhesion, and rapid drying time is disclosed. The tread cement comprises a water-in-oil emulsion having an oil continuous phase in which is dissolved a vulcanizable rubber compound. The water-in-oil emulsion tread adhesive may contain from 20-80% water, thereby minimizing environmental contamination on drying.

Tire tread adhesives

A method of producing acrylamide from acrylonitrile in the presence of a metallic conversion catalyst which comprises contacting a water-in-oil emulsion of acrylonitrile which is contained in the dispersed aqueous phase of the emulsion under conditions whereby a substantial portion of the acrylonitrile is converted to acrylamide which remains in the aqueous phase of the emulsion.

Method of producing acrylamide from water-in-oil emulsion of

The abstract of the disclosure is a method of rapidly preparing a dilute aqueous solution of poly N,N lower dialkylaminomethyl acrylamide and copolymers thereof having a molecular weight greater than 500,000 and a cationic charge of 1-90% which comprises:

Compositions for on-site mannich polymer process

An improved process for synthesizing high molecular weight polyamines utilizing a self-limiting neutralizing agent to maintain a generally constant alkaline ph over the course of the synthesis reaction, and the improved high molecular weight polyamines produced thereby.

Method of preparing high molecular weight polyamines

An improved process for synthesizing high molecular weight polyamines utilizing a self-limiting neutralizing agent to maintain a generally constant alkaline pH over the course of the synthesis reaction, and the improved high molecular weight polyamines produced thereby.

Improved method of preparing high molecular weight polyamines

This invention relates to a method for the hydrolysis of acrylamide polymers utilizing less than stoichiometric amounts of a hydrolysis agent selected from the group consisting of alkali metal hydroxides and alkali metal sulfites. The process is conducted with a water-in-oil emulsion (latex) of the acrylamide polymer at an elevated temperature and pressure.

Hydrolysis of acrylamide polymers

The dissolution rate of water-soluble polymers in water can be precisely controlled. This is accomplished by inverting a water-in-oil emulsion containing the water-soluble vinyl polymer into water which contains at the time of inversion an exact amount of an emulsifier system having an HLB number which has been predetermined to produce a specific solubility rate for the water-soluble vinyl polymer.

Method for precisely controlling the dissolution rate of high molecular

In a process for recovering oil from underground formations of the type wherein a dilute aqueous solution of an acrylamide polymer is injected into one or more wells the improvement which comprises: establishing near the one or more wells a small chemical plant and a source of acrylonitrile for producing an acrylamide polymer in the form of water-in-oil emulsion, which plant performs the following sequence of steps:

Large scale production of inexpensive flooding polymers for tertiary oil

A blend which contains homopolymers useful for imparting wet and dry strength to pulp and paper fibers which comprises a major amount of non-ionic polyacrylamide, together with glyoxal to impart crosslinking and a cationic regulator selected from the group consisting of a low molecular weight dimethyl amine epichlorohydrin copolymer, a low molecular weight ethylene dichloride ammonia condensation polymer, and a polyvinyl benzyl trimethyl ammonium chloride polymer. A buffer such as tetrasodium pyrophosphate may be used. A dosage of 0.2-5% by weight (preferred 0.5-2% by weight) based on the dry weight of fiber is utilized.

Cationic polymeric composition for imparting wet and dry strength to

Grouting composition containing acrylate salts of iron

A blend which contains homopolymers useful for imparting wet and dry strength to pulp and paper fibers which comprises a major amount of non-ionic polyacrylamide, together with glyoxal to impart crosslinking and polymeric diallyldimethyl ammonium chloride (DADMAC) as a cationic modifier. A buffer such as tetrasodium pyrophosphate may be used. A dosage of 0.2-5% by weight (preferred 0.5-2% by weight) based on the dry weight of fiber is utilized.

Paper fiber additive containing polyacrylamide blended with glyoxal and

A method of producing a water-in-oil emulsion of ammonium polyacrylate which comprises polymerizing a water-in-oil emulsion of ammonium acrylate in the presence of a water-in-oil emulsifier, and a free radical polymerization catalyst with the amount of oil initially present in said emulsion being at least 15% by weight, continuing said polymerization until substantially all of the ammonium acrylate has polymerized to form ammonium polyacrylate, allowing a major portion of the oil in the oil phase of the emulsion to separate as a polymer-free upper layer, thus leaving as a lower layer a water-in-oil emulsion of ammonium polyacrylate, which emulsion contains less than 10% by weight of oil. Also described are the polymeric emulsions produced using the above described method.

Polymerization of water soluble polymers in water-in-oil latex form to

Quarternary modified water-soluble polymers can be conveniently prepared in solid form by precipitation of the polymer with a water-in-oil emulsion of the polymer utilizing water-soluble organic solvents which are non-solvents for the cationic polymer.

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River Forest, IL, United States of America

Kenneth G Phillips