Talres Development (n.a.) N.v.

Other

Kenneth C Symes

Christopher J Lawson

Kishor K Mistry

A process for producing novel water-soluble compounds of the formula (HO).sub.m --A--(OCH.sub.2 NR.sup.1 COR).sub.p comprises forming a dispersion of an aqueous solution of a substrate A(OH).sub.n which is an alcohol or, preferably, a carbohydrate and a derivatising reagent HOCH.sub.2 NR.sup.1 COR.sup.2 in a water immiscible liquid and azeotroping the dispersion to remove water and thereby to drive the condensation reaction. The process can achieve high degrees of substitution and is of particular use in the production of water-soluble unsaturated polymersable products, preferably methylol acrylamide derivatives, in a process in which the aqueous dispersed phase contains a water-soluble polymerisation inhibitor. The unsaturated products may be used as cross-linking monomers in many aqueous polymerisation reactions, for instance an aqueous composition containing them with a water-soluble photo-initiator system including a dye are used as curing inks.

Process for producing derivatives of hydroxy compounds, the products and

Indican, a polysaccharide comprising (1.fwdarw.3) glucose, (1.fwdarw.4) mannose, (1.fwdarw.4) rhamnose and (1.fwdarw.3 or 4) -0-(1-carboxyethyl)rhamnose units in a molar ratio of about 2:1:1-2:1 respectively; containing 12-15% by weight acetyl units [.alpha.].sub.D.sup.20 about -61.degree.; having principle absorption bands in the infra red band at 3390, 1735, 1615, 1375, 1250 and 1050 cm.sup.-1 ; a solubility of at least 1% by weight in methanol and in ethylene glycol, and an inherent viscosity of about 33.5 dl/g. has useful thixotropic properties and provides a method of modifying the viscosity of a liquid by incorporating indican therein. The liquid may be aqueous or organic solvent-based. Thickened and stabilised products are also provided.

Suspensions and gels of indican and their uses

Indican, a polysaccharide comprising (1.fwdarw.3) glucose, (1.fwdarw.4) mannose, (1.fwdarw.4) rhamnose and (1.fwdarw.3 or 4) -0-(1-carboxyethyl)-rhamnose units in a molar ratio of about 2:1:1-2:1 respectively; containing 12-15% by weight acetyl units; [.alpha.]D.sup.20 about -61.degree.; having principle absorption bands in the infra red band at 3390, 1735, 1615, 1375, 1250 and 1050 cm.sup.-1 ; a solubility of at least 1% by weight in methanol and in ethylene glycol, and an inherent viscosity of about 33.5 dl/g. has useful thixotropic properties and provides a method of modifying the viscosity of a liquid by incorporating indican therein. The liquid may be aqueous or organic solvent-based. Thickened and stabilized products and a method of preparing indican by culture of an indican-producing microorganism are also provided.

Growing community of inventors

Reading, United Kingdom

Kenneth C Symes