Exxonmobil Research and Engineering Company

Exxonmobil Technology and Engineering Company

Exxon Research and Engineering Company

Kenneth C H Kar

Sheryl B Rubin-Pitel

Scott K Berkhous

Erin R Fruchey

Timothy J Anderson

Lisa M Guay

Shifang Luke Luo

Marcia E Dierolf

Aditya S Shetkar

Suzanne R Golisz

Stephen Harold Brown

Teng Xu

David T Ferrughelli

Randolph John Smiley

Kendall S Fruchey

Federico Barrai

Xinrui Yu

Brian A Cunningham

Anthony S Mennito

Ian J Laurenzi

Krystal B Wrigley

Alexander S Freer

Heather D Hamje

Dongil Kang

Yi Xu

Shifang Lou

Charles D Lund

Logan P Renninger

Donald J Mattran

Geert W Steenbeke

Provided are marine fuel compositions having acceptable wax behavior. In one form, the marine fuel composition has the following enumerated properties: a kinematic viscosity at 50° C. of about 5 cSt to about 700 cSt; a wax endpoint temperature of less than about 100° C.; and a ratio of kinematic viscosity at 100° C. to operating viscosity greater than 1, wherein the operating viscosity is at least about 2 cSt. The marine fuel composition exists in a liquid phase with essentially all the wax in the composition melted (essentially free of solid wax) prior to fuel injection into a marine engine.

Marine fuel compositions with acceptable wax behavior

Provided are marine fuels or fuel blending compositions, methods of making such fuels or compositions and methods of potentially reducing the life cycle carbon intensity of marine fuels or a fuel blending compositions. The marine fuel or fuel blending composition disclosed herein includes at least 20 vol % of a resid-containing fraction, and from 5 vol % to 80 vol % of one or more renewable fuel blending components. The one or more renewable fuel blending components includes one or more fatty acid alkyl esters. Optionally the one or more renewable fuel blending components may include gas-to-liquid hydrocarbons from renewable synthesis gas, hydrotreated natural fat or oil, hydrotreated waste cooking oil, hydrotreated tall oil, pyrolysis gas oil, or combinations thereof. Optionally, the resulting marine fuel or fuel blending composition can have a BMCI&#x2212;TE difference value of 15 or less.

Marine fuel compositions

Hydroprocessed residual fuel and/or fuel blending components are provided that have a sulfur and nitrogen level comparable to liquefied natural gas (LNG). Because of the low starting level of sulfur and/or nitrogen, the severity of the hydroprocessing that is needed for the crude oil or bottoms fraction in order to remove sulfur to a level that is comparable to LNG is reduced or minimized. This can allow the resulting marine residual fuels to have low carbon intensity, low SOx and NOx emission and high energy density. Since the hydroprocessed fractions correspond to a fuel oil product, the resulting marine fuel can be used in existing fleets, and can be distributed in existing bunkering systems.

Ultra low sulfur marine fuel compositions

Distillate boiling range and/or diesel boiling range compositions are provided that are formed from crude oils with unexpected combinations of high naphthenes to aromatics weight and/or volume ratio and a low sulfur content. This unexpected combination of properties is characteristic of crude oils that can be fractionated to form distillate/diesel boiling range compositions that can be used as fuels/fuel blending products with reduced or minimized processing. The resulting distillate boiling range fractions and/or diesel boiling range fractions can have an unexpected combination of a high naphthenes to aromatics weight and/or volume ratio, a low but substantial aromatics content, and a low sulfur content. By reducing, minimizing, or avoiding the amount of hydroprocessing needed to meet fuel and/or fuel blending product specifications, the fractions derived from the high naphthenes to aromatics ratio and low sulfur crudes can provide fuels and/or fuel blending products having a reduced or minimized carbon intensity.

High napthenic content distillate fuel compositions

Marine diesel fuel/fuel blending component compositions and fuel oil/fuel blending component compositions are provided that are derived from crude oils having high naphthenes to aromatics volume and/or weight ratios and a low sulfur content. In addition to having a high naphthenes to aromatics ratio, a low sulfur content, and a low but substantial content of aromatics, such fuels and/or fuel blending components can have a reduced or minimized carbon intensity relative to fuels derived from conventional sources. The unexpected ratio of naphthenes to aromatics contributes to the fuels and/or fuel blending components further having additional unexpected properties, including low density, low kinematic viscosity, and/or high energy density.

High napthenic content marine fuel compositions

High naphthenic content marine fuel compositions

Fuel compositions that are low sulfur and have adequate combustion quality are disclosed. An example fuel composition that is low sulfur may have the following enumerated properties: a sulfur content of about 0.50% or less by weight of the fuel composition; a calculated carbon aromaticity index of about 870 or less; a density at 15&#xb0; C. of about 900 kg/mto about 1,010 kg/m; a kinematic viscosity at 50&#xb0; C. of about 100 centistokes to about 700 centistokes; and an estimated cetane number of about 7 or greater.

Low sulfur fuel with adequate combustion quality

Diesel boiling-range fuel blends including renewable diesel, biodiesel, and petrodiesel, where the diesel boiling-range fuel blend is capable of producing a minimal volume change of at least one swellable elastomer in a diesel boiling-range fuel system are provided herein. Methods of making the diesel boiling-range fuel blend as well as methods of reducing swellable elastomer shrinkage are also provided herein.

Diesel boiling-range fuel blend and methods of making the same

This disclosure relates to compositions and methods of making an additized fuel composition comprising a base fuel composition and a randomly branched nitrate composition. The randomly branched nitrate composition includes a plurality of primary nitrate molecules, each molecule therein having an empirical chemical formula of CNO, wherein Cis a branched aliphatic moiety which may be the same or different for each molecule, n is an integer selected from the group consisting of 8, 9, 10, 11 and 12, at least one carbon atom in the branched aliphatic moiety being bound to three or more carbon atoms, a branching index ranging from 1.8 to 2.2, and greater than 80% of the branches in the aliphatic moiety being in other than the alpha position. The additized fuel composition may be diesel fuel composition or a gasoline fuel composition.

Fuel additives with low NOx emissions

Marine fuel compositions that are low sulfur and have improved wax flow viscosity are disclosed. An example marine fuel composition may have the following enumerated properties: a sulfur content of about 0.50% or less by weight of the marine fuel composition; a density at 15&#xb0; C. of about 0.86 g/cmto about 1.01 g/cm; a kinematic viscosity at 50&#xb0; C. of about 1 centistoke to about 700 centistokes; and a ratio of kinematic viscosity to wax flow viscosity of greater than 1, wherein the wax flow viscosity is determined using a minimum operating viscosity of about 8 centistokes at 50&#xb0; C.

Wax flow viscosity for fuels

Marine gas oil compositions corresponding to fuels and/or fuel blending components are provided that can provide improved friction properties within an engine. Addition of lubricant base stock to a marine gas oil composition can reduce frictional losses within an engine during operation. The benefits in reduction of frictional losses can be observed based on the difference between the indicated mean effective pressure and the actual work delivered by an engine, where the difference corresponds to the frictional mean effective pressure.

Marine fuel compositions with reduced engine frictional losses

Compositions corresponding to marine diesel fuels, fuel oils, jet fuels, and/or blending components thereof are provided that include at least a portion of a natural gas condensate fraction. Natural gas condensate fractions derived from a natural gas condensate with sufficiently low API gravity can provide a source of low sulfur, low pour point blend stock for formation of marine diesel and/or fuel oil fractions. Natural gas condensate fractions can provide these advantages and/or other advantages without requiring prior hydroprocessing and/or cracking.

Natural gas condensates in fuel compositions

Growing community of inventors

Philadelphia, PA, United States of America

Kenneth C H Kar