Konishi Co., Ltd.

Shin-etsu Chemical Co., Ltd.

Kenji Ueji

Masakazu Komemushi

Kenji Idemoto

Ichiro Ono

Kenichi Isobe

Kuniharu Harada

Hironori Tsukada

Syunsuke Shibahara

Shinsa Hamada

Shigeru Nagasawa

Kunihiko Asano

Toshiyuki Uenoyama

Kiichi Ito

Self-curable water-based solid adhesives of this invention include the following components (A), (B), (C), and (D): (A) an anionic-group-containing polymer terminally having an alkoxysilyl group, the polymer being a reaction product of a compound (A1) containing no anionic group and having plural isocyanate-reactive groups, a compound (A2) having an anionic group and plural isocyanate-reactive groups, a polyisocyanate compound (A3), and an alkoxysilane compound (A4) containing an isocyanate-reactive group; (B) a basic compound; (C) water; and (D) a gelling agent. The self-curable water-based solid adhesives of the present invention can be applied with good workability, have good fitting after attachment, have good adhesion to plastics, metals and glass and exhibit excellent heat resistance and water resistance after curing. They are highly safe to humans and the environment. They also have excellent shape retention and slidability and can be easily applied. In addition, they can bond adherends by contact bonding despite that they are water-based solid adhesives. Accordingly, the self-curable water-based solid adhesives of this invention are very useful as stick adhesives.

Self-curable water-based solid adhesive and bonding method using the self-curable water-based solid adhesive

Self-curable water-based solid adhesives of this invention include the following components (A), (B), (C), and (D): The self-curable water-based solid adhesives of the present invention can be applied with good workability, have good fitting after attachment, have good adhesion to plastics, metals and glass and exhibit excellent heat resistance and water resistance after curing. They are highly safe to humans and the environment. They also have excellent shape retention and slidability and can be easily applied. In addition, they can bond adherends by contact bonding despite that they are water-based solid adhesives. Accordingly, the self-curable water-based solid adhesives of this invention are very useful as stick adhesives.

Self-reactive/curable water-based solid adhesive and method of bonding with the self-reactive/curable water-based solid adhesive

An antislipping composition for a fastener having a head portion, comprising a crosslinked polymer prepared by the polymerization of an olefinic unsaturated carboxylic acid and a compound represented by a general formula (1) given below ##STR1## where R is a hydrogen atom or a methyl group, and the sum of 1, m and n is larger than 0 and not larger than 500, except that where R is a hydrogen atom and n is zero, l+m is not 1, a liquid medium containing at least one compound selected from the group consisting of glycol ethers and glycerin, and silicon carbide particles having acute corner portions.

Antislipping composition

Disclosed is a water repellent for fibers, comprising an acryl-silicone graft copolymer which is prepared by a radical copolymerization reaction of an organopolysiloxane compound containing one radical polymerizable group with radical polymerizable monomers including an acrylate, a methacrylate or a mixture thereof as a main member.

Agent for water-repellent treatment of fibers

Disclosed is a felt-tipped pen type adhesive applier comprising: a container for adhesive; valve mechanism provided on the container for controllably supplying the adhesive from the container; and a server for receiving the adhesive supplied through the valve mechanism in order to serve the adhesive. The server comprises: a holder covering the outside of the valve mechanism; a member permeable to the adhesive and extending from the inside of the holder to the outside thereof and being axially slidably and fittingly supported by the holder, the permeable member cooperating with the valve mechanism to operate the valve mechanism in response to axial movement of the permeable member; a support for slidably and fittingly supporting the permeable member inside of the holder to facilitate transportation of the adhesive from the valve mechanism to the permeable member; and mechanism for preventing the adhesive from leaking out of the server due to pressure change inside the server. The preventing mechanism includes a pair of notches which are symmetrically formed on the support with respect to the permeable member. Water emulsion adhesive is stored in the container.

Felt-tipped pen type adhesive applier

Growing community of inventors

Kawachinagano, Japan

Kenji Ueji