Kuraray Noritake Dental Inc.

Kuraray Co., Ltd.

Hgst Netherlands, B.v.

Stelic Institute & Co.

(national University Corporation) Niigata University

Fujitsu Corporation

Hitachi Global Storage Technologies Netherlands B.v.

Hitachi Global Storage Technologies Japan, Ltd.

Kenji Suzuki

Misaki Ito

Kenji Shachi

Mizuho Maeda

Kouki Uefune

Takashi Fukumoto

Daiki Noguchi

Hiroyuki Yoneyama

Harukazu Miyamoto

Shigeo Nakamura

Takuya Matsumoto

Toshihiko Shimizu

Shingo Tsuda

Takako Hayakawa

Junguo Xu

Irizo Naniwa

Kazuhiko Maekawa

Masaru Furukawa

Mitsuru Takei

Shumei Ishihara

Naoko Hayashida

Osamu Beppu

Naoki Nishigaki

Nobusuke Kashiki

Tatsuya Kajikawa

Hirotaka Horiguchi

Seiya Shimizu

Yuki Nishijima

Michiya Kawana

Hidemi Nakayama

Ai Hinamoto

Hiroyuki Sakamoto

Masashi Inoue

Hayato Miyakawa

Makoto Satou

Hirotsugu Ida

Hideaki Kuzuoka

Seiya Ichikawa

Akihiro Kotaka

The present invention provides a resin composition for stereolithography that enables easy stereolithographical fabrication; and that can produce a cured object having desirable strain recovery, desirable toughness, and desirable water resistance. The present invention relates to a resin composition for stereolithography comprising a polymerizable compound (A) whose homopolymer has a glass transition temperature (Tg) of 37° C. or higher; and a photopolymerization initiator (B), and having a tan δ at 37° C. of 0.3 or less after cure.

Resin composition for stereolithography

A resin composition for optical shaping comprising: an α,β-unsaturated double bond group-containing compound (A) having a ring structure (a) containing a nitrogen atom; a (meth)acrylic acid ester compound (B) having a boiling point of 280° C. or more at normal pressure, having a carbocyclic group, and having no nitrogen-containing heterocyclic group; a photopolymerization initiator (C); and optionally, a polyfunctional polymerizable monomer (E) having a molecular weight of 500 or less and not comprised in the α,β-unsaturated double bond group-containing compound (A) and the (meth)acrylic acid ester compound (B), wherein the content of the polyfunctional polymerizable monomer (E) having a molecular weight of 500 or less is 20 mass % or less relative to the total amount of polymerizable compounds comprised in the resin composition for optical shaping.

Resin composition for optical shaping

The present invention provides a resin composition for stereolithography that is easily shapable with good shape precision while reducing sedimentation of inorganic particles during storage, and a obtained three-dimensional shaped article thereby excels in mechanical characteristics such as flexural strength and flexural modulus, in addition to having a desirable shade and good shade stability. The present invention relates to a resin composition for stereolithography comprising a polymerizable monomer (a), a photopolymerization initiator (b), an inorganic particle (c) having an average particle diameter of 5 to 500 nm, and a hindered phenolic compound (d), wherein the content of the photopolymerization initiator (b) is 0.1 to 10 parts by mass relative to 100 parts by mass of the polymerizable monomer (a), the content of the inorganic particle (c) is 50 to 400 parts by mass relative to 100 parts by mass of the polymerizable monomer (a), and the content of the hindered phenolic compound (d) is 0.1 to 500 parts by mass relative to 100 parts by mass of the photopolymerization initiator (b).

A resin composition for stereolithography may emit a weak odor, enable easy fabrication of an object, and may be made into a cured product having desirable toughness and water resistance when used for stereolithographical fabrication. A resin composition for stereolithography may include: an α,β-unsaturated double bond group-containing compound (A) having a homopolymer glass transition temperature (Tg) of 40° C. or more, having a plurality of independent aromatic rings, and having no urethane bond; an α,β-unsaturated double bond group-containing compound (B) having a homopolymer glass transition temperature (Tg) of less than 40° C., having a ring structure, and having a normal boiling point of 250° C. or more; and a photopolymerization initiator (C).

A dental restorative curable compositions may have a high mechanical strength and excellent water resistance and polishability in the form of a cured product. A dental composite resin may include such compositions. A dental mill blank may include the cured product of such compositions. A dental restorative curable composition may include: a (meth)acrylic acid ester compound (A) having two or more (meth)acryloyloxy groups per molecule; a mono(meth)acrylic acid ester compound (B); an inorganic filler (C) having an average primary particle diameter of 0.01 to 5 μm; and a polymerization initiator (D). The mono(meth)acrylic acid ester compound may include at least one selected from the group consisting of a mono(meth)acrylic acid ester compound (B-1) of formula (I): anda mono(meth)acrylic acid ester compound (B-2) of formula (II):

Dental restorative curable composition

A method for manufacturing a mouthpiece includes manufacturing the mouthpiece that is to be placed within an oral cavity to cover teeth by an additive manufacturing device and laminating hardened layers not to form an annular lamination trace in a buccal portion that covers a buccal surface of a front tooth.

Mouthpiece and mouthpiece manufacturing method

A curable composition contains 79.0 to 99.0% by mass of a polymerizable monomer (a), 0.1 to 10.0% by mass of a photopolymerization initiator (b), and 0.01 to 20.0% by mass of a compound represented by the following general formula (I) as a polyfunctional polymerizable compound (c): wherein Rand Reach independently represent at least one kind selected from the group consisting of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 2 to 6 carbon atoms, an aryl group, and an aralkyl group; Rrepresents at least one kind of a polymerizable functional group selected from the group consisting of a (meth)acryloyl group, a 4-vinylphenyl group, and an alkenyl group having 2 to 5 carbon atoms; and n represents an arbitrary integer of 0 to 5.

Curable composition and stereolithographic resin composition comprising same

The present invention provides a resin composition for stereolithographic modeling emitting a weak odor, having desirable shape accuracy, and made into a cured product having desirable strength, toughness, and color tone when used for stereolithographic modeling. The present invention relates to a resin composition for stereolithographic modeling, comprising: a polymerizable monomer (A); a photopolymerization initiator (B), and an organic peroxide (C), wherein the polymerizable monomer (A) comprises a (meth)acrylic acid ester compound (A-1) having a viscosity of 1,000 mPa·s or less and a normal boiling point of 270° C. or more and/or a (meth)acrylamide compound (A-2) having a viscosity of 1,000 mPa·s or less and a normal boiling point of 200° C. or more, and the photopolymerization initiator (B) is at least one selected from a (bis)acylphosphine oxide, an α-hydroxyketone compound, an α-aminoketone compound, a benzoin alkyl ether compound, a thioxanthone, a ketal, an α-diketone, and an anthraquinone.

Resin composition for stereolithographic modeling

To provide a curable composition that is readily modeled with low viscosity and excellent curing capability in modeling by stereolithography, and provides a cured article excellent in toughness and water resistance, and a resin composition for stereolithography prepared therefrom. To provide a resin composition for stereolithography that is favorable particularly for a dental mouthpiece and a denture base material. A curable composition containing 79.0 to 99.0% by mass of a polymerizable monomer (a), 0.1 to 10.0% by mass of a photopolymerization initiator (b), and 0.01 to 20.0% by mass of a compound (c) represented by the following general formula (I):

Curable composition, and resin composition for stereolithography prepared therefrom

The present invention provides a resin composition for optical shaping that, with its low viscosity, enables easy stereolithographical fabrication of an object, and that can produce an object having desirable toughness and desirable water resistance, particularly for dental mouthpieces and denture base materials. The present invention relates to a resin composition for optical shaping comprising a urethanized (meth)acrylic compound (A) and a photopolymerization initiator (B), the urethanized (meth)acrylic compound (A) being a (meth)acrylate containing at least one polyol moiety and a urethane bond per molecule, said at least one polyol moiety being selected from the group consisting of a polyester, a polycarbonate, a polyurethane, and a polyether each having a structure derived from a C4 to C18 aliphatic chain diol unit (a) having a branched structure.

The present invention provides methods for retaining and expressing physiologically active substances in a target tissue-specific-manner, by administering the physiologically active substances to target submucous tissue. Specifically, the present inventors demonstrated that, when physiologically active substances were directly administered into submucous tissues without using a carrier, the physiologically active substances were effectively and safely retained at the administration sites over long periods without loss and diffusion, and produced the effect acting in a reservoir-like fashion. The physiologically active substances administered as described above were demonstrated to produce the therapeutic effect without having an influence on organs other than the administered organ.

Method of fixing and expressing physiologically active substance

The present invention provides a resin composition for stereolithography that, with its low consistency, enables easy fabrication while ensuring good shape accuracy and desirable color masking properties in the cured product. The present invention relates to a resin composition for stereolithography comprising: an 80 to 99 mass % polymerizable monomer (a); a 0.1 to 10 mass % photopolymerization initiator (b); a 0.1 to 5.0 mass % inorganic particle (c) having an average particle diameter of 5 to 200 nm; and a 0.01 to 10 mass % metal oxide particle (d) having an average particle diameter of 0.1 to 10 &#x3bc;m, the inorganic particle (c) being different from the metal oxide particle (d).

The present invention provides a container used in a stereolithography apparatus and having excellent transparency, shape accuracy, and durability. The present invention relates to a container for holding a photocurable composition (), the container being used in a stereolithography apparatus comprising a container (), an active energy beam irradiation apparatus (), and an actuator (), wherein the container () comprises a bottom (') and a wall, the bottom (&#x2032;) comprises a first layer (X) comprising a hard resin, a second layer (Y) comprising a soft resin, and a third layer (Z) comprising a fluorine resin, the second layer (Y) is laminated on the first layer (X) and the third layer (Z) is laminated on the second layer (Y), the pencil hardness measured according to JIS K 5600-5-4:1999 for the first layer (X) is 3 B or harder, the hardness measured for the second layer (Y) using a type A durometer compliant with JIS K 6253-3:2012 is 10 to 90, and the third layer (Z) has a thickness of 0.1 to 5.0 mm.

Container for stereolithography apparatus

The present invention provides a photocurable resin composition that has good fabricability, and that exhibits superior flexibility, fracture resistance, and water resistance in the form of a cured product. The present invention relates to a photocurable resin composition comprising:

Photocurable resin composition

A determination apparatus includes one or more memories, and one or more processors configured to perform, on the basis of data detected by a sensor that measures a first user who operates a first avatar, detection of a first behavior of the first user, determine a first type of behavior corresponding to the detected first behavior by referring to information indicating correspondence between a plurality of behaviors and a plurality of types of behavior, and perform, on the basis of a behavior tendency of the first user determined in accordance with the first type of behavior, control of an output to an environment where the first avatar exists.

Growing community of inventors

Niigata, Japan

Kenji Suzuki