Allied Corporation

Alliedsignal Inc.

University of Kentucky Research Foundation

Other

Kenji Okazaki

David J Skinner

Colin M Adam

Paul A Chipko

Robert G Corey

Richard L Bye, Jr

James R Dickson

Charles E Hamrin, Jr

Thomas H Sanders

Robert J De Angelis

A method is provided for synthesizing high temperature alloys from elemental powders. The method includes the steps of placing the elemental powders to be processed in a die. A relatively high pressure is then applied to the powders. Substantially simultaneously, an electrical discharge is applied to the powders. The discharge is of relatively high voltage and current density to provide alloying. A product fabricated by the present method is also described and claimed.

High temperature alloys synthesis by electro-discharge compaction

The invention provides an aluminum based alloy consisting essentially of the formula Al.sub.bal Fe.sub.a X.sub.b, wherein X is at least one element selected from the group consisting of Zn, Co, Ni, Cr, Mo, V, Zr, Ti, Y and Ce, 'a' ranges from about 7-15 wt %, 'b' ranges from about 2-10 wt % and the balance is aluminum. The alloy has a predominately microeutectic microstructure. The invention also provides a method and apparatus for forming rapidly solidifed metal, such as the metal alloys of the invention, within an ambient atmosphere. Generally stated, the apparatus includes a moving casting surface which has a quenching region for solidifying molten metal thereon. A reservoir holds molten metal and has orifice means for depositing a stream of molten metal onto the casting surface quenching region. A heating mechanism heats the molten metal contained within the reservoir, and a gas source provides a non-reactive gas atmosphere at the quenching region to minimize oxidation of the deposited metal. A conditioning mechanism disrupts a moving gas boundary layer carried along by the moving casting surface to minimize disturbances of the molten metal stream that would inhibit quenching of the molten metal on the casting surface at a quench rate of at least about 10.sup.6 .degree. C./sec. Particles composed of the alloys of the invention can be heated in a vacuum and compacted to form a conslidated metal article have high strength and good ductility at both room temperature and at elevated temperatures of about 350.degree. C. The consolidated article is composed of an aluminum solid solution phase containing a substantially uniform distribution of dispersed intermetallic phase precipitates therein. These precipitates are fine intermetallics measuring less than about 100 nm in all dimensions thereof.

Aluminum-transistion metal alloys having high strength at elevated

A method for fabricating relatively dense monoliths of superconducting material and relatively dense composite monoliths of superconducting material and binder material. The method includes the steps of placing the material to be processed in a die. A relatively high pressure is then applied to the material. Substantially simultaneously, an electrical discharge is applied to the material. The discharge is of a relatively high voltage and current density to provide sharp bonding while maintaining the superconducting properties of the material in the monolith product. A product fabricated by the present method is also described.

Method of processing superconducting materials and its products

The invention provides an aluminum based alloy consisting essentially of the formula Al.sub.bal Fe.sub.a X.sub.b, wherein X is at least one element selected from the group consisting of Zn, Co, Ni, Cr, M, V, Zr, Ti, Y, Si and Ce, 'a' ranges from about 7-15 wt %, 'b' ranges from about 1.5-10 wt % and the balance is aluminium. The alloy has a predominately microeutectic microstructure. The invention provides a method and apparatus for forming rapidly solidified metal within an ambient atmosphere, the rapidly solidified metal being an aluminum based alloy. Generally stated, the apparatus includes a moving casting surface which has a quenching region for solidifying molten metal thereon. A reservoir holds the molten metal and has orifice means for depositing a stream of the molten metal onto the casting surface quenching region. A heating mechanism heats the molten metal within the reservoir, and a gas source provides a non-reactive gas atmosphere at the quenching region to minimize oxidation of the deposited metal. A conditioning mechanism disrupts a moving gas boundary layer carried along by the moving casting surface to minimize disturbance of the molten metal on the casting surface at a quench rate of at least about 10.sup.6 .degree. C./sec.

Method and apparatus for forming aluminum-transition metal alloys having

A method for sintering and forming powder is disclosed. In this method a high voltage of 3 KV or more is applied to a mold filled with powder using an electrode which maintains a high current of 50 KA cm.sup.-2 or greater for a period of time from 10 to 500 microseconds. A device for practicing this method is also disclosed.

Method of sintering powder

The present invention provides a method for producing an aluminum alloy which includes the step of carbo-thermically reducing an aluminous material to provide an alloy consisting essentially of the formula Al.sub.bal TM.sub.d Si.sub.e, wherein TM is at least one element selected from the group consisting of Fe, Ni, Co, Ti, V, Zr, Cu and Mn, 'd' ranges from about 2-20 wt %, 'e' ranges from about 2.1-20 wt %, and the balance is aluminum and incidental impurities. The alloy is placed in the molten state and rapidly solidified at a quench rate of at least about 10.sup.6 K/sec to produce a rapidly solidified alloy composed of a predominately microeutectic and/or microcellular structure.

Rapidly solidified aluminum-transition metal-silicon alloys

The invention provides an aluminum based alloy consisting essentially of the formula Al.sub.bal Fe.sub.a X.sub.b, wherein X is at least one element selected from the group consisting of Zn, Co, Ni, Cr, Mo, V, Zr, Ti, Y and Ce, 'a' ranges from about 7-15 wt. %, 'b' ranges from about 2-10 wt. % and the balance is aluminum. The alloy has a predominately microeutectic microstructure, and is produced by a method and apparatus for forming rapidly solidified metal within an ambient atmosphere. Generally stated, the apparatus includes a moving casting surface which has a quenching region for solidifying molten metal thereon. A reservoir holds molten metal and has orifice means for depositing a stream of molten metal onto the casting surface quenching region. A heating mechanism heats the molten metal contained within the reservoir, and a gas source provides a non-reactive gas atmosphere at the quenching region to minimize oxidation of the deposited metal. A conditioning mechanism disrupts a moving gas boundary layer carried along by the moving casting surface to minimize disturbances of the molten metal stream that would inhibit quenching of the molten metal on the casting surface at a quench rate of at least about 10.sup.6 .degree. C./sec. Particles composed of the alloys of the invention can be heated in a vacuum and compacted to form a consolidated metal article have high strength and good ductility at both room temperature and at elevated temperatures of about 350.degree. C. The consolidated article is composed of an aluminum solid solution phase containing a substantially uniform distribution of dispersed intermetallic phase precipitates therein. These precipitates are fine intermetallics measuring less than about 100 nm in all dimenisons thereof.

An apparatus for forming aluminum-transition metal alloys having high

The invention provides an aluminum based alloy consisting essentially of the formula Al.sub.bal Fe.sub.a X.sub.b, wherein X is at least one element selected from the group consisting of Zn, Co, Ni, Cr, Mo, V, Zr, Ti, Y, Si and Ce, 'a' ranges from about 7-15 wt %, 'b' ranges from about 1.5-10 wt % and the balance is aluminum. The alloy has a predominately microeutectic microstructure. The invention also provides a method and apparatus for forming rapidly solidified metal, such as the metal alloys of the invention, within an ambient atmosphere. Generally stated, the apparatus includes a moving casting surface which has a quenching region for solidifying molten metal thereon. A reservoir holds molten metal and has orifice means for depositing a stream of molten metal onto the casting surface quenching region. A heating mechanism heats the molten metal contained within the reservoir, and a gas source provides a non-reactive gas atmosphere at the quenching region to minimize oxidation of the deposited metal. A conditioning mechanism disrupts a moving gas boundary layer carried along by the moving casting surface to minimize disturbances of the molten metal stream that would inhibit quenching of the molten metal on the casting surface at a quench rate of at least about 10.sup.6 .degree. C./sec. Particles composed of the alloys of the invention can be heated in a vacuum and compacted to form a consolidated metal article have high strength and good ductility at both room temperature and at elevated temperatures of about 350.degree. C. The consolidated article is composed of an aluminum solid solution phase containing a substantially uniform distribution of dispersed intermetallic phase precipitates therein. These precipitates are fine intermetallic measuring less than about 100 nm in all dimensions thereof.

Aluminum-transition metal alloys having high strength at elevated

The present invention provides a method for producing an aluminum alloy which includes the step of carbothermically reducing an aluminous material to provide an alloy consisting essentially of the formula Al.sub.bal TM.sub.d Si.sub.e, wherein TM is at least one element selected from the group consisting of Fe, Ni, Co, Ti, V, Zr, Cu and Mn, 'd' ranges from about 2-20 wt %, 'e' ranges from about 2.1-20 wt %, and the balance is aluminum and incidental impurities. The alloy is placed in the molten state and rapidly solidified at a quench rate of at least about 10.sup.6 K/sec to produce a rapidly solidified alloy composed of a predominately microeutectic and/or microcellular structure.

Method of producing rapidly solidified aluminum-transition metal-silicon

The invention provides an aluminum based alloy consisting essentially of the formula Al.sub.bal Fe.sub.a V.sub.b X.sub.c, wherein X is at least one element selected from the group consisting of Zn, Co, Ni, Cr, Mo, Zr, Ti, Hf, Y and Ce, 'a' ranges from about 7-15 wt %, 'b' ranges from about 2-10 wt %, 'c' ranges from about 0-5 wt % and the balance is aluminum. The alloy has a distinctive microstructure which is at least about 50% composed of a generally spherical, intermetallic O-phase. Particles composed of the alloys of the invention can be heated in a vacuum and compacted to form a consolidated metal article have high strength and good ductility at both room temperature and at elevated temperatures of about 350.degree. C. The consolidated article is composed of an aluminum solid solution phase containing a substantially uniform distribution of dispersed intermetallic phase precipitates therein. These precipitates are fine intermetallics measuring from about 10 nm to about 100 nm in diameter with an average interparticle spacing ranging from 50-500 nm.

Aluminum-iron-vanadium alloys having high strength at elevated

The present invention provides a low density aluminum-base alloy, consisting essentially of the formula Al.sub.bal Zr.sub.a Li.sub.b Mg.sub.c T.sub.d, wherein T is at least one element selected from the group consisting of Cu, Si, Sc, Ti, V, Hf, Be, Cr, Mn, Fe, Co and Ni, 'a' ranges from about 0.25-2 wt %, 'b' ranges from 2.7-5 wt %, 'c' ranges from about 0.5-8 wt %, 'd' ranges from about 0.5-5% and the balance is aluminum. The alloy has a primary, cellular-dendritic, fine-grained, supersaturated aluminum alloy solid solution phase with intermetallic phases of the constituent elements uniformly dispersed therein. A consolidated article can be produced by compacting together particles composed of the aluminum alloy of the invention in a vacuum at elevated temperature. The compacted alloy is solutionized by heat treatment, quenched in a fluid bath, and optionally, stretched and aged. The microstructure of the consolidated article is composed of an aluminum solid solution containing a substantially uniform distribution of fine intermetallic precipitates.

Low density aluminum alloys and method

Rapidly solidified chromium and cobalt free superalloy powders are described. The compositions of the alloys are as follows:

Chromium and cobalt free nickel base superalloy powder

The present invention is for an improved aluminum alloy powder for making consolidated products with an improved combination of strength and ductility. The alloy is cast as ribbon or flake which subsequently pulverized.

Growing community of inventors

Baskingridge, NJ, United States of America

Kenji Okazaki