Idemitsu Kosan Company, Limited

Kenji Mogami

Tatsuya Egawa

Nobuaki Shimizu

Yasuhiro Kawaguchi

Masato Kaneko

Toshinori Tazaki

Hirotaka Yamasaki

Satoshi Nagao

Toyokazu Handa

Hirotaka Yamazaki

The present invention proposes a lubricating oil for refrigerators comprising, as the base oil, a polyester-based derivative or a polyvinyl ether derivative and a polycarbonate-based oxygenated compound; a polyoxyalkylene glycol derivative; or a polyester-based derivative or a polyvinyl ether derivative and a polyoxyalkylene glycol derivative. The lubricating oil exhibits excellent miscibility with a refrigerant having one carbon atom and no chlorine atoms and, in particular, with difluoromethane and provides a hydraulic fluid composition exhibiting excellent antiwear, lubricity and stability.

Lubricating oil for refrigerator and hydraulic fluid composition for refrigerator using the same

A lubricating oil for compression-type refrigerators using a refrigerant containing pentafluoroethane which lubricating oil comprises a polyvinyl ether compound having (a) a constituting unit represented by general formula (I):

Lubricating oil for compression-type refrigerators containing pentafluoroethane and a polyvinyl ether

A method of production of polyvinyl ether compound by which the polyvinyl ether compound having a desired degree of polymerization is produced reliably, safely and efficiently and a novel polyvinyl ether compound useful as lubricating oil for compression-type refrigerators, electric insulation oil and the like are disclosed. The method of production of the present invention is a method of producing a polyvinyl ether compound which comprises polymerizing a vinyl ether compound in the presence of a Lewis acid catalyst and a specific acetal or a method of producing a polyvinyl ether compound which comprises forming an acetal by reaction of a vinyl ether compound with a specific alcohol in the presence of a Lewis acid catalyst, then adding the vinyl ether compound to the acetal and polymerizing the vinyl ether compound. The polyvinyl ether compound of the present invention is homopolymer or a copolymer of an alkyl vinyl ether comprising the constituting unit expressed by the general formula: ##STR1## (R.sup.15 : an alkyl group of C.sub.1 .about.C.sub.3) and having weight average molecular weight of 300 to 1200 and one end having a specific structure.

Method of producing a polyvinyl ether compound

A method of production of an ether compound from an acetal compound or a ketal compound which is excellent in conversion and selectivity and does not cause corrosion of apparatuses and a novel useful polyvinyl ether compound as lubricating oil for compression-type refrigerators, electric insulation oil and the like are disclosed. The method of production of the present invention comprises reaction of an acetal compound or a ketal compound with hydrogen in the presence of a solid catalyst having acidic property and hydrogenation ability to produce the corresponding ether compound. The polyvinyl ether compound of the present invention comprises the constituting unit expressed by the general formula: ##STR1## (characters in the general formula are the same as those described in the specification), contains none of unsaturated bond, acetal structure and aldehyde structure in the molecule and has weight average molecular weight in the range of 300 to 3000.

Process of producing ether compound

A method of production of an ether compound from an acetal compound or a ketal compound which is excellent in conversion and selectivity and does not cause corrosion of apparatuses and a novel useful polyvinyl ether compound as lubricating oil for compression-type refrigerators, electric insulation oil and the like are disclosed. The method of production of the present invention comprises reaction of an acetal compound or a ketal compound with hydrogen in the presence of a solid catalyst having acidic property and hydrogenation ability to produce the corresponding ether compound.

Process of producting ether compound

A lubricating oil for compression-type refrigerators which comprises as the main component thereof a polyvinyl ether compound having excellent compatibility with a hydrofluorocarbon or a hydrochlorofluorocarbon, such as 1,1,1,2-tetrafluoroethane and the like, which can be used as the refrigerant to replace compounds causing environmental pollution, such as dichlorofluoroethane and the like, and having an excellent lubricating property is disclosed. The lubricating oil for compression-type refrigerators comprises as the main component thereof a polyvinyl ether compound having the constituting units expressed by the general formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 are H or a hydrocarbon group of C.sub.1.about.8, R.sup.4 is a bivalent hydrocarbon group of C.sub.2.about.10, R.sup.5 is a hydrocarbon group of C.sub.1.about.10 and m is 0.about.10.

Growing community of inventors

Sodegaura, Japan

Kenji Mogami