Nippon Chemical Industrial Co., Ltd.

Mitsubishi Hitachi Power Systems, Ltd.

Hokkaido University

Olympus Corporation

Ken Tamura

Tsuneo Imamoto

Natsuhiro Sano

Yosuke Takubo

Takanori Tsutsumi

Takashi Fujii

Masashi Sugiya

Hajime Ito

Takashi Kijima

Hiroaki Iwamoto

Yoshinori Koyama

Kazuhiro Nakatsui

Yoshifusa Hara

Masato Murayama

Yoshirou Kaneda

Zhenfeng Zhang

Daisuke Mayama

Satoshi Takeshita

Eiichi Tatsuya

Yuki Sawatsugawa

In the method for producing an optically active 2,3-bisphosphinopyrazine derivative of the present invention, an optically active 2,3-bisphosphinopyrazine derivative represented by the following formula (3) is produced by the step of: preparing solution A containing 2,3-dihalogenopyrazine represented by the following formula (1) and a carboxylic acid amide coordinating solvent, lithiating an optically active R- or S-isomer of a hydrogen-phosphine borane compound represented by the following formula (2) to give a lithiated phosphine borane compound; adding solution B containing the lithiated phosphine borane compound to the solution A to perform an aromatic nucleophilic substitution reaction; and then performing a deboranation reaction. (For symbols in the formulas, see the description.)

Method for producing optically active 2, 3-bisphosphinopyrazine derivative and method for producing optically active phosphine transition metal complex

An optical fiber bundle manufacturing apparatus includes: a winding member; a guide member movable in a direction parallel to a rotary axis, the guide member being configured to guide an optical fiber wire to any one of first winding positions, a converging winding position and second winding positions; and a processor configured to perform processing to move the guide member such that a first branching portion branching into p branches, a converging portion converging the first branching portion branching into p branches into one, a second branching portion branching into q branches, and a connecting portion connecting the first branching portion and the second branching portion are formed in this order by the optical fiber wire.

Optical fiber bundle manufacturing apparatus, light guide, endoscope having light guide, and method of manufacturing optical fiber bundle

The silyl phosphine compound of the present invention is represented by the formula (1) and has an arsenic content of not more than 1 ppm. The process for producing a silyl phosphine compound of the present invention is a process comprising mixing a basic compound, a silylating agent and phosphine to obtain a solution containing a silyl phosphine compound, removing a solvent from the solution to obtain a concentrated solution of a silyl phosphine compound, and distilling the concentrated solution, wherein an arsenic content in the phosphine is adjusted to not more than 1 ppm by volume in terms of arsine. The process for producing InP quantum dots of the present invention uses, as a phosphorus source, a silyl phosphine compound represented by the formula (1) and having an arsenic content of not more than 1 ppm by mass. 

Silyl phosphine compound, process for producing silyl phosphine compound and process for producing InP quantum dots

The silyl phosphine compound is represented by the following general formula (1). A content of a compound represented by the following general formula (2) is not more than 0.3 mol %. In the general formula (1), each R is independently an alkyl group having not less than 1 and not more than 5 carbon atoms or an aryl group having not less than 6 and not more than 10 carbon atoms. In the general formula (2), R is the same as in the general formula (1). 

Process for producing silyl phosphine compound and silyl phosphine compound

There is provided a novel optically active bisphosphinomethane useful as a ligand for an asymmetric catalyst, excellent in oxidation resistance in air, and easy in handling. There is also provided a transition metal complex using the optically active bisphosphinoraethane having excellent asymmetric catalytic ability as a ligand. The optically active bisphosphinomethane is represented by the general formula (1), and the transition metal complex has the optically active bisphosphinomethane as a ligand. (In the formula, Rrepresents an adamantyl group; Rrepresents a branched alkyl group having 3 or more carbon atoms; and * represents an asymmetric center on a phosphorus atom.)

Optically active bisphosphinomethane, method for producing the same, and transition metal complex and asymmetric catalyst

A production method by which a biarylphosphine useful as a Buchwald phosphine ligand can be obtained in high purity is provided through an industrially advantageous process. The production method of a biarylphosphine comprises a step A of reacting a lithiated product obtained through lithiation of a halogenated benzene derivative with a benzene derivative to obtain a biphenyl derivative, and a step B of the reacting the biphenyl derivative with a halogenated phosphine. In the step A, the charge molar ratio of the halogenated benzene derivative to the benzene derivative is preferably 1.0 to 5.0.

Production method of biarylphosphine

Provided is a 2,3-bisphosphinopyrazine derivative represented by the following general formula (1), wherein R, R, R, and Rrepresent an optionally substituted straight-chain or branched alkyl group having 1 to 10 carbon atoms, an optionally substituted cycloalkyl group, an optionally substituted adamantyl group, or an optionally substituted phenyl group, Rrepresents an optionally substituted alkyl group having 1 to 10 carbon atoms or an optionally substituted phenyl group, each Rmay be the same group or a different group, Rrepresents a monovalent substituent, n denotes an integer of 0 to 2. 

2,3-bisphosphinopyrazine derivative, method for producing same, transition metal complex, asymmetric catalyst, and method for producing organic boron compound

An optically active 2,3-bisphosphinopyrazine derivative represented by the following general formula (1): wherein Rrepresents a group selected from a branched alkyl group having 3 or more carbon atoms, an adamantyl group, an optionally substituted cycloalkyl group, and an optionally substituted aryl group; Rrepresents a group selected from a branched alkyl group having 3 or more carbon atoms, an adamantyl group, and an optionally substituted cycloalkyl group, provided that when Ris a tert-butyl group, Rand Rare not the same; Rrepresents a monovalent substituent; n represents an integer of 0 to 4; and * represents an asymmetric center on a phosphorus atom.

Optically active substituted 2,3-bisphosphinoquinoxalines and processes for producing the same

The process for producing a silyl phosphine compound of the present invention comprises a first step of mixing a solvent having a relative dielectric constant of not more than 4, a basic compound, a silylating agent and phosphine to obtain a solution containing a silyl phosphine compound, a second step of removing the solvent from the solution containing a silyl phosphine compound to obtain a concentrated solution of a silyl phosphine compound, and a third step of distilling the concentrated solution of a silyl phosphine compound to obtain the silyl phosphine compound. The silyl phosphine compound of the present invention is a silyl phosphine compound represented by the following general formula (1), wherein a content of a compound represented by the following general formula (2) is not more than 0.5 mol %. (For explanatory notes of the formulas, see the specification.)

A control device for a power generation system whereby power is generated by a first power source that operates by burning a fuel. The control device identifies, on the basis of a pressure difference in a prior-stage mechanism that supplies the fuel to the first power source, a fuel capacity that compensates for the pressure difference in the prior-stage mechanism. The pressure difference is the difference between a pressure set for the fuel before a load change in the prior-stage mechanism and a pressure set for the fuel after the load change in the prior-stage mechanism. The control device calculates a fuel supply command value, which is a command value for adjusting the amount of fuel supplied to a fuel supply device that supplies the fuel to the first power source, and is output to the fuel supply device using a fuel supply acceleration command value.

Control device and control method using fuel supply acceleration command value

This IGCC plant is provided with an ASU which separates oxygen gas and nitrogen gas from air, a coal gasification furnace which uses an oxidizing agent to gasify coal, and a gas turbine which is driven by the combustion gas resulting from burning a gas generated by means of the coal gasification furnace. This IGCC plant control device () is provided with an air separation amount determination unit () which determines the production amount of nitrogen gas produced by the ASU depending on the operating load of the IGCC plant, and supplies to the coal gasification furnace the entire amount of oxygen gas generated as a byproduct in response to the determined nitrogen gas production amount. By this means, the IGCC plant can minimize blow-off of oxygen gas produced from the air.

Gasification power plant control device, gasification power plant, and gasification power plant control method

An IGCC plant includes a coal gasifier that gasifies coal by using an oxidizer, a gas turbine that is driven by combustion gas generated by combustion of fuel gas obtained by purifying gas generated by the coal gasifier in gas clean-up equipment, and an oxidizer supply path for supplying air extracted from an air compressor of the gas turbine or oxygen separated from the air as an oxidizer for the coal gasifier. A control unit () for the gasification power generation plant controls the amount of the oxidizer that is supplied to the coal gasifier to be less than or equal to a predetermined upper-limit value, while allowing deviation of an air ratio from a predetermined set value, the air ratio representing the ratio of the amount of air that is supplied to the coal gasifier relative to a theoretical amount of air for combustion of carbon, in accordance with variations in an operating-state quantity of the coal gasifier or variations in a load of the IGCC plant. Accordingly, the capacity of the oxidizer supplying equipment need not be increased in the IGCC plant, and it is possible to quickly stabilize control of the plant as a whole.

Control unit for gasification power generation plant, gasification power generation plant, and control method for gasification power generation plant

Provided are a novel 1,2-bis(dialkylphosphino)-4,5-(methylenedioxy)benzene derivative that forms a metal complex having particularly high asymmetry induction capacity and catalytic activity on &#x3b2;-dehydroamino acids, a method for manufacturing the same, a metal complex having this 1,2-bis(dialkylphosphino)-4,5-(methylenedioxy)benzene derivative as a ligand, and an asymmetric hydrogenation method using this metal complex. A 1,2-bis(dialkylphosphino)-4,5-(methylenedioxy)benzene derivative represented by general formula (1). (In the formula, Rand Rrepresent an alkyl group having 1-10 carbon atoms, and Rand Rhave different numbers of carbon atoms.) 

Device and method for evaluating organic material for organic solar cell

An industrially advantageous method for producing an optically active 1,2-bis(dialkylphosphino)benzene derivative of the present invention is provided. The method is characterized in that a phosphine-borane compound represented by the following general formula (1) is subjected to a deboronation reaction, followed by lithiation, then the reaction product is subjected to reaction with an alkyldihalogenophosphine represented by RPX', and thereafter the reaction product is subjected to reaction with a Grignard reagent represented by RMgX&#x2033; to produce an optically active 1,2-bis(dialkylphosphino)benzene derivative (A). Rand Rrespectively represent an alkyl group having 1 to 8 carbon atoms, and the number of carbon atoms is different between Rand R. Ris either Ror Rand Ris the other of Rand R. X, X&#x2032;, and X&#x2033; each represent a halogen atom. 

Method for producing optically active 1,2-bis(dialkylphosphino)benzene derivative

A novel phosphine compound capable of forming a metal complex useful as a catalyst for various asymmetric synthesis reactions, a production method thereof, and a metal complex comprising the aforementioned compound as a ligand.

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Tokyo, Japan

Ken Tamura