Daikin Industries, Ltd.

Hiroshima University

Ken Okanishi

Takafumi Yamato

Yoshichika Komiya

Tsuyoshi Miyamori

Takahisa Aoyama

Tetsuo Shimizu

Tatsuo Suzuki

Minoru Yoshida

Nobuhiko Tsuda

Masahiko Oka

Toshiyuki Fukushima

Ryoichi Fukagawa

Masamichi Hikosaka

Yasuyuki Yamaguchi

Kiyoka Okada

Kyouhei Sawaki

Shinji Murakami

Keizo Shiotsuki

Keisuke Matsumoto

Masaki Takakura

A molded article containing a crystal of a fluoropolymer. The fluoropolymer contains at least one selected from vinylidene fluoride/tetrafluoroethylene copolymer, polychlorotrifluoroethylene, an ethylene/tetrafluoroethylene copolymer, a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer and a tetrafluoroethylene/hexafluoropropylene copolymer. Further, the crystal is a nano-oriented crystal having a size of 300 nm or smaller.

Molded article

The present invention provides a processing additive which can bring about improvements in moldability at Mooney viscosity levels at which the dispersibility in a melt-processable resin is high and which further can work at reduced addition levels. The present invention is a processing additive comprising a fluoropolymer having an acid value of not lower than 0.5 KOH mg/g.

Processing additive, molding composition masterbatch of processing additive and molding article

The invention provides a processing aid enabling short-time disappearance of melt fracture occurred in extrusion-molding a melt-fabricable resin at a high shear rate, a great reduction in extrusion pressure, and production of molded articles with good appearance. The processing aid contains a polymer containing a fluorine-containing elastomeric polymer segment and a fluorine-containing non-elastomeric polymer segment.

Processing aid

The present invention provides a processing aid for polyolefins capable of improving the processability in processing polyolefins at a temperature lower than 220&#xb0; C. and a high shear rate. The processing aid for polyolefins is intended to be used in processing a polyolefin at a temperature lower than 220&#xb0; C., and contains a fluoropolymer that includes a polymerized unit (a) based on CF&#x2550;CFCFand a polymerized unit, (b) based on at least one selected from the group consisting of monomers represented by CH&#x2550;CXYand monomers represented by CF&#x2550;CXY.

Processing aid for polyolefins and a polyolefin composition

The present invention provides a processing aid for polyolefins which can eliminate melt fracture occurring at the start of molding in a short time even when a polyolefin, which is a melt-processable polymer, is extrusion-molded at a high speed. The present invention also aims to provide a polyolefin composition containing such a processing aid for polyolefins and a polyolefin. The processing aid for polyolefins contains an ethylene/tetrafluoroethylene copolymer as the only fluoropolymer, the ethylene/tetrafluoroethylene copolymer having a melting point of 170&#xb0; C. to 270&#xb0; C.

Processing aid, and composition

There are provided a resin film being excellent in blocking resistance, scratch resistance, transparency, water resistance and chemical resistance and a member having the resin film as an outermost layer. The resin film comprises a vinylidene fluoride (VdF) copolymer and an acrylic polymer as essential components, in which a heat of fusion of crystal derived from the VdF copolymer in the resin film is from 15 to 30 J/g when measured with a differential scanning calorimeter (DSC), and light transmittance (light transmittance at 600 nm of 50 &#x3bc;m thick resin film) is not less than 85%. The member has the resin film as an outermost layer.

Vinylidene fluoride copolymer resin film

Spherulites in a molded article obtained from a melt-processable crystalline fluorine-containing resin composition are minimized to give the transparent molded article having a smooth surface and being resistant to contamination. An agent for minimizing spherulite size which comprises an amorphous fluorine-containing polymer or a fluorine-containing multi-segment polymer. The fluorine-containing multi-segment polymer comprises an amorphous segment and a crystalline segment.

Spherulite-micronizing agent for crystalline fluororesin crystalline fluororesin composition containing micronizing agent

Agent for minimizing size of spherulite of crystalline fluorine-containing resin and crystalline resin and crystalline fluorine-containing resin composition comprising said agent

A fluorine-containing copolymer comprising ethylene, tetrafluoroethylene, a fluorovinyl compound of the formula: CH &boxH;CFRf in which Rf is a fluoroalkyl group having 2 to 10 carbon atoms, and hexafluoropropylene, in which a molar ratio of tetrafluoroethylene to ethylene is from 40:60 to 90:10, the content of the above fluorovinyl compound of the formula: CH &boxH;CFRf is from 0.1 to 10 mole % based on the whole copolymer, and the content of hexafluoropropylene is from 0.1 to 30 mole % based on the whole copolymer. This fluorine-containing copolymer can provide films having good transparency and high tear strength, and such films are useful as weather-resistant protective films, films for agricultural housings, films for constructions, and the like.

Growing community of inventors

Osaka, Japan

Ken Okanishi