Shin-etsu Chemical Co., Ltd.

Ken Nakayama

Shunji Aoki

Yasuyoshi Kuroda

Ataru Kobayashi

Toshiaki Ihara

Tsuyoshi Matsuda

The present invention provides a silicone release agent composition comprising the components (A), (B), (C) and (D): 50 to 99.9 parts by mass of (A) linear or branched organopolysiloxane represented by the general formula (1) and having at least two alkenyl group-containing organic groups and at least one aryl group-containing organic group in one molecule and having no fluorine-containing organic group, wherein a percentage of the number of the alkenyl group-containing organic group is 0.005 to 5% and a percentage of the number of the aryl group-containing organic groups is 0.1 to 40%, each based on the total number of groups each bonded to a silicon atom; 50 to 0.1 part by mass of (B) linear or branched organopolysiloxane having at least one alkenyl group-containing organic group and at least one fluorine-containing organic group in one molecule, wherein a percentage of the number of the fluorine-containing organic group is 3% to 50%, based on the total number of groups each bonded to a silicon atom, provided that the total amount of components (A) and (B) is 100 parts by mass; (C) organohydrogenpolysiloxane having three or more hydrogen atoms each bonded to a silicon atom in one molecule and having no fluorine-containing organic group, in such an amount that a ratio of the number of the SiH group in component (C) to the total number of the alkenyl group in components (A) and (B) is from 0.5 to 15; and a catalytic amount of (D) platinum group metal catalyst, provided that the silicone release agent composition does not comprise (E) organohydrogenpolysiloxane having one or more hydrogen atoms each bonded to a silicon atom and having a fluorine-containing organic group.

Silicone release agent composition and a release paper or film

The object of the present invention is to provide a silicone composition which provides a release coating having excellent adhesion to a substrate, in particular a plastic film substrate, such as a polyester film. Further, an object of the present invention is to provide a release sheet having a cured coating of the silicon composition. It is also an object of the present invention to provide a silicone composition which has improved storage stability and does not cause separation of the functional compound during long-term storage or transportation. The present invention provides a silicone composition comprising the following components (A) to (C):

Silicone composition, a release sheet, a release film and methods for preparing the release sheet and the release film

Provided is a silicone adhesive composition having (A) a condensation product of a linear or branched diorganopolysiloxane having a silicon atom-bonded hydroxy group and/or a silicon atom-bonded alkoxy group having 1 to 10 carbon atoms at a terminal and having no alkenyl group, a linear or branched diorganopolysiloxane having at least two alkenyl groups, and an organopolysiloxane comprising an RSiOunit and an SiOunit and having a silicon atom-bonded hydroxy group and/or a silicon atom-bonded alkoxy group having 1 to 6 carbon atoms, (B) an organohydrogenpolysiloxane having at least three SiH groups and an average polymerization degree of 80 or less in an amount of 0.1 to 5 parts by mass, relative to 100 parts by mass of component (A), and (C) a platinum group metal catalyst in a catalytic amount.

Silicone adhesive composition, adhesive tape, adhesive sheet and double-sided adhesive sheet

An adhesive silicone composition having (A) a linear or branched organopolysiloxane having at least two alkenyl groups in a molecule (B) an organopolysiloxane comprising RSiOunits and SiOunits, wherein Ris, independently of each other, a substituted or unsubstituted, monovalent hydrocarbon group having 1 to 10 carbon atoms, (C) an organohydrogenpolysiloxane having at least three hydrogen atoms each bonded to a silicon atom in a molecule and having no aryl group, and (E) an organohydrogenpolysiloxane having at least three hydrogen atoms each bonded to a silicon atom in a molecule and having an aryl group-containing organic group.

Adhesive silicone composition and an adhesive film or tape

A compound that is devoid of epoxy groups and has a quantity of alkenyl groups corresponding to 5-1000 times the alkenyl content of a base polymer, and/or an organopolysiloxane that is devoid of alkenyl groups, has an average degree of polymerization of 2-50, and contains, per molecule, 30 mol % or more of siloxane units having epoxycyclohexyl groups bonded to silicon atoms via carbon atoms, are/is blended with a silicone composition for a release film as adhesion-enhancing components.

Silicone composition for release paper or release film, and release paper and release film

This ultraviolet curable silicone adhesive composition that contains (wherein Rrepresents H or Me, a represents a number of 1-3, and the broken line represents a bonding hand that is bonded with Si)as Si-bonded groups, and wherein the main chain is composed of repeated diorganosiloxane units, and (wherein a is as defined above, and the broken line represents a bonding hand)at an end of the molecular chain or in a molecular side chain as an Si-bonded group, is rapidly cured by means of irradiation of ultraviolet light, and exhibits good adhesion to a sheet-like substrate.

Ultraviolet curable silicone adhesive composition and silicone adhesive film

Provided is a solventless silicone composition which can form a highly transparent release coating having excellent adhesion to a substrate, in particular to a plastic film substrate, and which can provide a layer of cured product having good adhesion even when the release coating exhibits a small peeling force. Also provided is a release paper and release film having such a cured coating.

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Annaka, Japan

Ken Nakayama