Exxonmobil Technology and Engineering Company

Keith R Hajkowski

Anastasios I Skoulidas

Everett J O'Neal

Changmin Chun

Joseph E Gatt

William R Gunther

Wesley Sattler

Ning Ma

Partha Nandi

Vera Grankina

Catalyst systems are provided for reforming of hydrocarbons, along with methods for using such catalyst systems. The catalyst systems can be deposited or otherwise coated on a surface or structure, such as a monolith, to achieve improved activity and/or structural stability. The metal oxide support layer can correspond to a thermally stable metal oxide support layer, such as a metal oxide support layer that is thermally phase stable at temperatures of 800° C. to 1600° C. The catalyst systems can be beneficial for use in cyclical reaction environments, such as reverse flow reactors or other types of reactors that are operated using flows in opposing directions and different times within a reaction cycle.

Catalyst systems for reforming in cyclic flow reactors

Systems and methods are provided for using size-reversing materials in vessels where direct heating is used to at least partially provide heat for reforming reactions under cyclic reforming conditions. An example of a size-reversing material is the combination of NiO and AlO. It has been discovered that size-reversing materials can undergo a phase transition that can assist with re-dispersion of metal at elevated temperatures. This can assist with maintaining catalytic activity for reforming over longer time periods in the presence of cyclic reforming conditions.

Size-reversing materials for reforming in cyclic flow reactors

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Somerset, NJ, United States of America

Keith R Hajkowski