Momentive Performance Materials Gmbh

Princeton University

Crompton Gmbh

General Electric Company

Cornell University

Other

Witco Corporation

Keith James Weller

Paul J Chirik

Johannes G P Delis

Kenrick M Lewis

Susan Adams Nye

Eric Raymond Pohl

Richard W Cruse

Robert J Pickwell

Aroop Kumar Roy

Tianning Diao

Julie Boyer

Aaron M Tondreau

Renyuan Yu

Crisita Carmen Hojilla Atienza

Indumathi Ramakrishnan

Prashant G Joshi

Lesley Hwang

Philbert E Ramdatt

Karthikeyan Murugesan

Robert F Hayes

Leda N Gonzalez

Andreas Haeuseler

Scot M Turner

Martin Hofstetter

Raghuraman Govindan Karunakaran

Anne Kathryn McMullen

Enrico J Pepe

Cristia Carmen Hojilla Atienza

Crista Carmen H Atienza

Sarah Kathleen Russell

Wesley E Sloan

Crisita Carmen H Atienza

Johannes GP Delis

Julie L Boyer

Disclosed herein is the use of manganese, iron, cobalt, or nickel complexes containing tridentate pyridine di-imine ligands as hydrosilylation catalysts. These complexes are effective for efficiently catalyzing hydrosilylation reactions, as well as offering improved selectivity and yield over existing catalyst systems.

Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity

The present technology relates to an antifog coating composition comprising a matrix, a hydrophilic compound, and a surfactant. The antifog coating composition may further comprise a thermal or a photo-initiator. The antifog coating composition may be applied to a polycarbonate substrate.

Antifog coating composition and method of making thereof

The present invention is directed to a selective and efficient process for the hydrosilylation of compounds containing terminally unsaturated 1,3-dienes using iron-based hydrosilylation catalysts. The resulting 1,2-addition products are useful as precursors for various silicone materials or silane- or silyl/silicone-functionalized polyolefins.

Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts

Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient, reusable, and selective dehydrogenative silylation, crosslinking, and tandem dehydrogenative silylation-hydrogenation catalysts.

Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation

Disclosed herein are cobalt complexes containing pyridine di-imine ligands and chelating alkenyl-modified silyl ligands, and their use as hydrosilylation and/or dehydrogenative silylation and crosslinking catalysts. The cobalt complexes also exhibit adequate air stability for handling and manipulation.

Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation

Disclosed herein are cobalt terpyridine complexes containing a single ligand coordinated to the cobalt, and their use as hydrosilylation and/or dehydrogenative silylation and crosslinking catalysts. The cobalt complexes also exhibit adequate air stability for handling and manipulation.

Disclosed herein are cobalt complexes containing terpyridine ligands and chelating alkene-modified silyl ligands, and their use as hydrosilylation and/or dehydrogenative silylation and crosslinking catalysts. The cobalt complexes also exhibit adequate air stability for handling and manipulation.

Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient and selective dehydrogenative silylation, hydrosilylation, and crosslinking catalysts.

Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts

A method for treating filler material includes contacting the filler material with a silane which, upon hydrolysis, produces substantially no significant amount of volatile organic compound and/or the hydrolyzate of the silane to provide a treated filler which can then be incorporated into a matrix to provide a composite body.

Filler treatments utilizing low VOC silanes

Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient and selective dehydrogenative silylation and crosslinking catalysts.

Dehydrogenative silylation and crosslinking using cobalt catalysts

Disclosed herein is the selective synthesis of mono-hydrosilylated derivatives of polyunsaturated compounds, such as trivinylcyclohexane using non-precious metal based pyridinediimine and terpyridine complex as selective hydrosilylation catalysts.

Selective non-precious metal-catalyzed mono-hydrosilylation polyunsaturated compounds

Disclosed herein is a process for the hydrosilylation of a composition containing a silyl hydride and a compound containing at least one unsaturated group, the process comprising contacting a non-previous metal based complex as a catalyst precursor with an activator being a reducing agent shortly before, simultaneously or after contacting the complex with the composition, to cause the silyl hydride to react with the compound containing at least one unsaturated group to produce a hydrosilylation product.

In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts

Disclosed herein are manganese, iron, cobalt, or nickel complexes containing 2,8-bis(imino)quinoline ligands and their use as catalysts or catalysts precursors for hydrosilylation reactions.

Non-precious metal-containing 2,8-bis(imino)quinoline complexes and their use as hydrosilylation catalysts

A process for crosslinking polymers employs a silane crosslinker which, upon hydrolysis, produces a reduced quantity of volatile organic compound.

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Rensselaer, NY, United States of America

Keith James Weller