Massachusetts Institute of Technology

Quantum Energy Technologies LLC

Keith H Johnson

Brian S Ahern

Harry R Clark

Bin Zhang

Charles W Haldeman

Harry C Clark

The invention provides a scheme for combusting a hydrocarbon fuel to generate and extract enhanced translational energy. In the scheme, hydrocarbon fuel is nanopartitioned into nanometric fuel regions each having a diameter less than about 1000 angstroms; and either before or after the nanopartitioning, the fuel is introduced into a combustion chamber. In the combustion chamber, a shock wave excitation of at least about 50,000 psi and with an excitation rise time of less than about 100 nanoseconds is applied to the fuel. A fuel partitioned into such nanometric quantum confinement regions enables a quantum mechanical condition in which translational energy modes of the fuel are amplified, whereby the average energy of the translational energy mode levels is higher than it would be for a macro-sized, unpartitioned fuel. Combustion of such a nanopartitioned fuel provides enhanced translational energy extraction by way of, e.g., a reciprocating piston because only the translational energy mode of combustion products appreciably contributes to momentum exchange with the piston. The shock wave excitation provided by the invention, as applied to combustion of any fuel, and preferably to a nanopartitioned fuel, enhances translational energy extraction and exchange during combustion by enhancing translational energy mode amplification in the fuel and by enhancing transfer of an appreciable amount of energy from that translational mode to the piston before the combusted fuel re-equilibrates the translational energy into other energy modes.

Combustion of nanopartitioned fuel

Supercritical water fuel composition and combustion system. In one aspect, the invention is a composition of matter comprising a mixture of 5-50% water and a hydrocarbon wherein the water/hydrocarbon mixture is near the critical point such that the mixture is a homogeneous single phase. A suitable temperature is 400.degree. C. and a suitable pressure is 4,000psi. In another aspect, the invention is a fuel system including structure containing a water/hydrocarbon fuel mixture near the critical point such that the mixture is a homogeneous single phase. Structure is provided for delivering the mixture for combustion. Combustion may occur in an internal combustion engine, turbine engine or other burner.

Supercritical water fuel composition and combustion system

The present invention provides combustible compositions utilizing water clusters characterized by high oxygen reactivity due to protruding, delocalized p.pi. orbitals. In preferred embodiments, the compositions include one or more surfactants having molecular orbitals that interact with and participate in the delocalized p.pi. orbitals. The invention also provides methods of designing, producing, and using the compositions.

Stabilized water nanocluster-fuel emulsions designed through quantum

The present invention provides water cluster compositions characterized by high oxygen reactivity due to protruding, delocalized p.pi. orbitals. The invention also provides methods of producing the structures. The invention further provides methods of using the water clusters, for example in combustion, and compositions associated therewith.

Water clusters and uses therefor

For a condensed matter system containing a guest interstitial species such as hydrogen or its isotopes dissolved in the condensed matter host lattice, the invention provides tuning of the molecular orbital degeneracy of the host lattice to enhance the anharmonicity of the dissolved guest sublattice to achieve a large anharmonic displacement amplitude and a correspondingly small distance of closest approach of the guest nuclei. The tuned electron molecular orbital topology of the host lattice creates an energy state giving rise to degenerate sublattice orbitals related to the second nearest neighbors of the guest bonding orbitals. Thus, it is the nuclei of the guest sublattice that are set in anharmonic motion as a result of the orbital topology. This promotion of second nearest neighbor bonding between sublattice nuclei leads to enhanced interaction between nuclei of the sublattice. In the invention, a method for producing dynamic anharmonic oscillations of a condensed matter guest species dissolved in a condensed matter host lattice is provided. Host lattice surfaces are treated to provide surface features on at least a portion of the host lattice surfaces; the features have a radius of curvature less than 0.5 microns. Upon dissolution of the guest species in the treated host lattice in a ratio of at least 0.5, the guest species undergoes the dynamic anharmonic oscillations.

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Cambridge, MA, United States of America

Keith H Johnson