Kraton Polymers U.S. LLC

Building Materials Investment Corporation

Keith Edward Stephens

Robert Q Kluttz

Denis Muki Tibah

James A Svec

Nicholas R Soto

Carl Lesley Willis

Olan Thomas Leitch

Dale Lee Handlin, Jr

Willem C Vonk

Daniel Coleman DeJarnette

Sean C Marren

Jan Korenstra

William B Corley, Sr

Willie R Grice

Skyler G Hare

Mark T Glover

Billy R Brown

Harriet J S Kendrick

The present invention relates to a method for preparing an industrial asphalt comprising sparging an oxygen containing gas through an asphalt flux in the presence of 0.25 weight percent to about 12 weight percent of a highly saturated rubbery polymer at a temperature within the range of about 400&#xb0; F. to about 550&#xb0; F. for a period of time which is sufficient to increase the softening point of the asphalt flux to a value which is within the range of 185&#xb0; F. to 250&#xb0; F. and a penetration value of at least 15 dmm to produce the industrial asphalt. The highly saturated rubbery polymer can be a styrene-ethylene/butylene-styrene block copolymer rubber or a highly saturated styrene-ethylene/propylene-styrene block copolymer rubber.

Preparation of industrial asphalt

A continuous system for making shingles from recyclable material is provided comprising a milling device to receive recyclable material and process the recyclable material into particulate and a transfer device to receive and transfer the particulate from the milling device. An apparatus receives the particulate from the transfer device and weighs the particulate. A continuous processor receives the particulate and reacts and/or mixes the particulate with at least one admixture to form a homogenous mixture. A filler mixer receives the homogenous mixture and incorporates the homogenous mixture with shingle material to form core product and a control panel controls input of the homogenous mixture into the filler mixer.

System and method for continuous processing of recyclable material

The subject invention provides a method for producing essentially homogeneous asphalt compositions which are comprised of the asphalt, a block copolymer (such as a linear block copolymer or a radial block copolymer), and one or more additional desired additives. This method offers the advantage of being capable of attaining the essentially homogeneous asphalt composition in one pass procedure with a short residence time in the mixing equipment. This greatly reduces the thermal history to which heat sensitive asphalt additives, such as asphalt modification polymers, are exposed. It also simplifies the mixing procedure and can reduce the overall amount of energy required to attain the desired blend. In some case, it allows for the production on a commercial basis of asphalt compositions which would otherwise not be feasible, for instance the production of asphalt compositions which contain high levels of asphalt modifications polymers which are otherwise difficult to process.

Continuous processing of asphalt formulations

The present invention is directed to bituminous emulsions comprising bitumen, water, one or more emulsifiers systems and a diblock copolymer including one block of a monovinylaromatic hydrocarbon and one block of a conjugated diene, wherein the conjugated diene has a peak molecular weight from 30,000 to 78,000 and a vinyl content from 35 to 80 mol percent based on the number of repeat monomer units in the conjugated diene block. A block copolymer comprising at least two blocks of monovinylaromatic hydrocarbon and at least one block of conjugated diene, the block copolymer selected from linear triblock copolymers having a peak molecular weight that is 1.5 to 3.0 times the peak molecular weight of the diblock copolymer, multiarm coupled block copolymers having a peak molecular weight that is 1.5 to 9.0 times the peak molecular weight of the diblock copolymer, and mixtures thereof, wherein each block copolymer has a vinyl content from 35 to 80 mol percent based on the number of repeat monomer units in the conjugated diene block, wherein the ratio of (i) to (ii) in the block copolymer composition is greater than 1:1.

Bituminous emulsions

An impact resistant shingle is provided which includes an asphalt-coated substrate having a first surface and a second surface, the first surface having a headlap portion and an exposure portion. The headlap portion comprises a transition zone disposed at an edge region of the substrate distal to the exposure portion. The first surface of the substrate exclusive of the transition zone comprises granules, wherein the shingle has a smaller thickness dimension at the transition zone than a thickness dimension of a remaining area of the shingle.

Shingle with transition device for impact resistance

A block copolymer composition including a diblock copolymer (I) having one block of a monovinylaromatic hydrocarbon and one block of a conjugated diene having a peak molecular weight from 30,000 to 78,000 and one or more block copolymers (ii) comprising at least two blocks of monovinylaromatic hydrocarbon and at least one block of conjugated diene, the block copolymer selected from linear triblock copolymers having a peak molecular weight that is 1.5 to 9.0 times the peak molecular weight of the diblock copolymer, and mixtures thereof, wherein the ratio of (i) to (ii) is greater than 1:1.

Process for preparing a bituminous binder composition

The present invention is directed to a process for preparing a polymer modified bituminous binder composition in the substantial absence of crosslinking agents by heating a bitumen component in a stirred tank to a temperature from 160&#xb0; C. to 221&#xb0; C.; adding a block copolymer composition to the bitumen component while the bitumen component is being stirred to form a homogeneous mixture of the bitumen component and the block copolymer composition; and continuing to stir the homogeneous mixture while maintaining the temperature from 180&#xb0; C. to 221&#xb0; C. for a total period of time from 4 hours to 30 hours thereby forming a cured polymer modified bituminous binder composition. The block copolymer composition utilized in the process comprises one or more block copolymers having at least one monovinylaromatic block and either (I) at least one polybutadiene block having a vinyl content of less than 15 mol percent and at least one polybutadiene block having a vinyl content of greater than 25 mol percent or (II) at least one polybutadiene block having a vinyl content that tapers from a vinyl content of less than 15 mol percent at the first end adjacent to the monovinylaromatic block to a vinyl content that is greater than 25 mol percent at the second end which is furthest from the monovinylaromatic block and optionally at least one polybutadiene block having a vinyl content of less than 15 mol percent. The present invention is further related to an alternative to this process, a specific class of bituminous binder compositions and concentrates and a specific class of block copolymer compositions.

Bituminous binder composition and process for preparing the same

The present invention is directed to a process for preparing a polymer modified bituminous binder composition in the substantial absence of crosslinking agents by heating a bitumen component in a stirred tank to a temperature from 185&#xb0; C. to 221&#xb0; C.; adding a block copolymer composition to the bitumen component while the bitumen component is being stirred to form a homogeneous mixture of the bitumen component and the block copolymer composition; and continuing to stir the homogeneous mixture while maintaining the temperature from 185&#xb0; C. to 221&#xb0; C. for a period of time from 4 hours to 30 hours thereby forming a cured polymer modified bituminous binder composition. The block copolymer composition utilized in the process comprises a diblock copolymer comprising one block of a monovinylaromatic hydrocarbon and one block of a conjugated diene having a peak molecular weight from 30,000 to 78,000 and a vinyl content from 35 to 80 mol percent based on the number of repeat monomer units in the conjugated diene block, and optionally one or more block copolymers comprising at least two blocks of monovinylaromatic hydrocarbon and at least one block of conjugated diene, the block copolymer selected from linear triblock copolymers having a peak molecular weight that is 1.5 to 3.0 times the peak molecular weight of the diblock copolymer, multiarm coupled block copolymers having a peak molecular weight that is 1.5 to 9.0 times the peak molecular weight of the diblock copolymer, and mixtures thereof, wherein each block copolymer has a vinyl content from 35 to 80 mol percent based on the number of repeat monomer units in the conjugated diene block, wherein when both (i) and (ii) are present in the block copolymer composition, the ratio of (i) to (ii) is greater than 1:1. The present invention is further related to an alternative to this process, a specific class of bituminous binder compositions and concentrates and a specific class of block copolymer compositions.

A process for preparing compatible, selectively hydrogenated block copolymer-modified bituminous compositions comprising blowing a mixture of the block copolymer and bitumen with an oxidizing gas at temperatures of at least 375&#xb0; C. for at least 75 minutes. The modifying polymer is a selectively hydrogenated styrenic block copolymer and no blowing catalyst is required. Stable bituminous compositions comprising 6 to 25 parts by weight of block copolymer per 100 parts of asphalt are also provided as well as their application as roofing shingles.

Blown asphalt compositions

The present invention relates to a bituminous composition comprising a bituminous component, an elastomeric polymer component, and a specific cross-linking composition component comprising elemental sulfur, a sulfur-containing derivative, a sulfur activator, a fatty acid or fatty acid derivative and a polymeric carrier. Compositions according to the invention are particularly useful in preparing polymer-modified asphalt ('PMA') for road applications.

Cross-linking compositions for polymer-modified asphalt compositions

The present invention is a polymer modified bituminous composition having improved phase stability, heat aging and viscosity characteristics. The bituminous compositions are blends comprising bitumen and from about 0.5 to about 25% of a novel anionic block copolymer where one of the blocks is a controlled distribution copolymer of a conjugated diene and a mono-alkenyl arene having a specific arrangement of the monomers in the copolymer block. The composition of the invention is useful for paving, roofing felts, water-proof membrane, adhesive, mopping asphalt, carpet backing and pipe coating applications.

Growing community of inventors

Waxahachie, TX, United States of America

Keith Edward Stephens