Osram Sylvania Inc.

Gte Laboratories Incorporated

Gte Products Corporation

Whittaker Corporation

University of California

Orsam Sylvania Inc.

Whittaker Technical Products, Inc.

A. Gary Sigai

Keith A. Klinedinst

Keith A Klinedinst

Richard A Gary

Dennis B Shinn

A Gary Sigai

Joseph E Lester

Silvia E Lichtensteiger

Gautam Bandyopadhyay

William D Clark

Robert F Clark

Carl R Schlaikjer

Richard A Fowler

Hongwen Li

Francis G Murphy

Daniel Carril

Christoforos Kazazis

Bing Han

Madis Raukas

Kailash C Mishra

Steven C Schlitt

Jonathan H Tao

Jan B Talbot

Kailash A Mishra

Jonathan Tap

Rare earth-activated aluminum nitride powders are made using a solution-based approach to form a mixed hydroxide of aluminum and a rare earth metal, the mixed hydroxide is then converted into an ammonium metal fluoride, preferably a rare earth-substituted ammonium aluminum hexafluoride ((NH)AlREF), and finally the rare earth-activated aluminum nitride is formed by ammonolysis of the ammonium metal fluoride at a high temperature. The use of a fluoride precursor in this process avoids sources of oxygen during the final ammonolysis step which is a major source of defects in the powder synthesis of nitrides. Also, because the aluminum nitride is formed from a mixed hydroxide co-precipitate, the distribution of the dopants in the powder is substantially homogeneous in each particle.

Rare earth-activated aluminum nitride powders and method of making

A fluorescent tanning lamp having a glass envelope has an ultra-violet light reflecting coating covering at least 180&#xb0; of an inside surface of the envelope; and a phosphor layer covering substantially 360&#xb0; of the inside surface of the envelope, including overlying the ultra-violet reflecting coating. An odor reducing photocatalytic material is provided on an outside surface of the envelope, the photocatalytic material being coextensive with the ultra-violet light reflecting material. A preferred material is anatase TiO; i.e., the crystalline form.

Odor neutralizing fluorescent sunlamp

A method for inhibiting mercury from leaching from a land-filled arc discharge lamp containing a quantity of elemental mercury at least partially convertible to soluble mercury, provides for including within the lamp a quantity of a non-metallic copper-containing compound and an ingredient X, said ingredient X including a noble metal or a noble metal compound selected from the group consisting of silver and compounds of silver, gold and platinum, and a lamp containing same. The inhibiting compound is preferably included with the basing cement.

Method of controlling leachable mercury in lamps

An arc discharge lamp containing a quantity of elemental mercury at least partially convertible to soluble mercury, provides for including within the lamp a quantity of a non-metallic copper-containing compound and an ingredient X, said ingredient X including a noble metal or a noble metal compound selected from the group consisting of silver and compounds of silver, gold and platinum, and a lamp containing same.

Arc discharge lamp containing means for reducing mercury leaching

A moisture-resistant electroluminescent phosphor is provided wherein the individual phosphor particles have a first coating of an inorganic moisture-resistant coating and a second coating of an organic moisture-resistant coating. The process for making the moisture-resistant phosphor comprises applying a first layer of an inorganic moisture-resistant coating to individual particles of an electroluminescent phosphor to form a first-coated phosphor, substantially isolating said first-coated phosphor from contact with atmospheric oxygen and moisture, and applying a second layer of an organic moisture-resistant coating to the first-coated phosphor to form a second-coated phosphor.

Electroluminescent phosphor with plural moisture resistant coatings thereon

A new fluidized bed particle coating method is disclosed by the use of which coatings can be uniformly and conveniently deposited on the surfaces of fluidized particulate materials by vapor deposition processes at temperatures lower than those of the heated coating precursor transport lines. By this method, particle materials with relatively low surface temperatures may be brought into close proximity with a coating precursor containing gas stream characterized by a substantially higher gas volume temperature in such a way that the vaporized precursor molecules are caused to adsorb or condense on the relatively cold particle surfaces without also condensing on any other surface. Further, if the adsorbed precursor molecules are capable of reacting or polymerizing on the relatively cold particle surfaces, thus forming substantially continuous coatings on those surfaces, they may do so without also depositing such coatings on any other surfaces. Such coating deposition processes cannot be carried out using conventional fluidized bed deposition methods or equipment.

Particles with vapor deposition coating

A method for inhibiting the leaching of mercury from a mercury vapor discharge lamp wherein at least a part of the mercury is present as ionic mercury includes depositing a coating of SnO on an interior surface of the lamp envelope. The SnO coating is substantially free of a substance which would cause electrical conductivity of the coating. Further included within the lamp is a quantity of oxidizable iron in an amount equal to at least 1 gram per kilogram of lamp weight.

Control of leachable mercury in fluorescent lamps

Method of coating particles by vapor deposition

A phosphor particle has thereon a moisture resistant treatment of a metallic nitride. By moisture resistant is meant a condition allowing the phosphor particle to function in a humid atmosphere for a significantly longer period of time than an untreated particle. The method of making such phosphors comprises the steps of introducing an inert gas into a reaction vessel; charging phosphor particles into the reaction vessel; heating the reaction vessel to a reaction temperature; introducing a nitride coating precursor into the reaction vessel; introducing a co-reactant into the reaction vessel; and maintaining the inert gas flow, co-reactant flow and precursor supply for a time sufficient to moisture-proof the phosphor particles. The nitride treated phosphor particles produced by this method, which can include the deposition of a nitride coating on the particles, have excellent efficacy ratings and strong luminance values in lamps after 100 hours use in high humidity (i.e., >95%).

Moisture insensitive electroluminescent phosphor

An improvement in a mercury vapor discharge lamp having an envelope of light-transmitting vitreous material containing an inert starting gas and a quantity of elemental mercury at least in part convertible to soluble mercury, and first and second electrodes located within the envelope for an arc discharge therebetween. The improvement comprises an effective amount of a soluble copper-containing compound in combination with an effective amount of a selected one of a group of materials consisting of a soluble chloride, a soluble bromide, a soluble nonmetallic iron-containing compound, and a soluble nonmetallic manganese-containing compound. The copper-containing compound and the material in combination, when the lamp is pulverized into granules and subjected to a suitable aqueous acid solution, produce a concentration of extracted mercury of less than 0.2 mg/l of the aqueous solution. The effective amount of the copper-containing compound is substantially smaller than is required to produce the concentration of extracted mercury without the materials present, and the effective amount of the selected material is smaller than is required to produce the concentration of extracted mercury without the copper-containing compound present.

Mercury vapor discharge lamp containing means for reducing leachable mercury

A phosphor particle having thereon a conformal coating of aluminum nitride. By conformal coating is meant a coating that follows the surface contours of the individual particles. The method of making such phosphors comprises the steps of introducing an inert gas into a reaction vessel; charging phosphor particles into the reaction vessel; heating the reaction vessel to a reaction temperature; introducing a nitride coating precursor into the reaction vessel; introducing a coreactant into the reaction vessel; and maintaining the inert gas flow, coreactant flow and precursor supply for a time sufficient to coat the phosphor particles. The nitride coated phosphor particles produced by this method have excellent efficacy ratings and strong luminance values in lamps after 100 hours use in high humidity (i.e.,&gt;95%).

Nitride coated particle and composition of matter comprised of such

In a mercury vapor discharge lamp having an envelope of light-transmitting vitreous material and containing an inert gas and a quantity of elemental mercury at least partially convertible to soluble mercury, and first and second electrodes disposed within the envelope for establishing an arc discharge therebetween, an improvement comprising an effective amount of a nonmetallic copper-containing compound disposed in the lamp which, when the lamp is pulverized to granules and subjected to a suitable aqueous acid solution, dissolves in the aqueous acid solution, resulting in a concentration of extracted mercury less than 0.2 mg per liter of solution; and a method for reducing the amount of mercury extracted from a mercury vapor discharge lamp when the lamp is pulverized to granules and subjected to a suitable aqueous acid solution, such that the resulting concentration of extracted mercury is less than 0.2 mg per liter of solution, the method comprising the step of placing in the lamp in manufacture thereof an effective amount of a nonmetallic copper-containing compound soluble in the aqueous acid solution.

Mercury vapor discharge lamp having means for reducing mercury leaching

A method for making a tantala/silica interference filter on a vitreous substrate, which filter retains integrity at temperatures in excess of 600.degree. C., includes the steps of depositing by low pressure chemical vapor deposition a first coating of tantala/silica on the substrate, heat treating the first coating, and depositing by low pressure chemical vapor deposition a second coating of tantala/silica, the first and second coatings in combination providing a tantala/silica interference filter with a thickness of at least 3.5 microns on the vitreous substrate. There is further presented an electric lamp having an envelope and an interference filter applied thereto, in accordance with the above method.

Method for making a tantala/silica interference using heat treatment

A method for making a tantala/silica interference filter on the surface of a tungsten-halogen incandescent lamp having molybdenum leads includes depositing on the lamp surface by low pressure chemical vapor deposition the interference filter comprising alternating layers of tantala and silica. Thereafter, the filter is heat treated in an atmosphere of humidified inert gas containing less than 1% oxygen.

Growing community of inventors

Marlboro, MA, United States of America

Keith A Klinedinst