Akzo Nobel N.v.

Keimpe Jan Van Den Berg

Arie Noomen

Huig Klinkenberg

Klaus Hobel

Josephus Christiaan Van Oorschot

Frederik Rous

Martinus Adrianus Koenraadt

Edith Hulsbos

Heert Andringa

Wincenty Lambertus Pilaszek

Thomas Mezger

Judith Johanna Maria Adriana Loenen

Ignace Damiaan Christiaan Rood

Jan Wilhelm Moos

Johannes Adrianus Pardoen

Klaas Jan Hendrik Kruithof

Kenny Abdoel Nassier Raghosing

Jan Cornelis Van Beelen

Ann Kerstin Birgitta Lindell Kjellqvist

Marcel Johannes Antonius Mensink

Eric Gerardus Johanus Oude Spraakste

The invention relates to a coating composition comprising an acetal-functional binder and a thiol-functional cross-linker, wherein the acetal-functional binder is represented by the following formula wherein P is a binder backbone, K is a divalent and/or trivalent organic moiety having 1 to 30 carbon atoms and having one or two links to the binder backbone, A is selected from oxygen, sulphur, and NR, wherein Ris hydrogen or an alkyl group with 1 to 4 carbon atoms, m is an integer from 1 to 50, n is an integer from 1 to 10, and R and R' may be the same or different and represent alkyl groups with 1 to 4 carbon atoms. In a further aspect, the invention relates to acetal-functional binders, acetal-functional monomers, a process for the preparation of said monomers, coating compositions comprising said acetal-functional binders, and to a process for the preparation of a coating composition comprising an acetal-functional polyurethane dispersion and a thiol-functional cross-linker.

Coating composition comprising an acetal-functional binder

The invention pertains to a coating composition comprising a compound comprising at least one spiro-ortho silicate group and a hydroxyl-reactive cross-linker, to a process for curing the composition, and to the use of the composition. The coating composition of the current invention can be formulated to a coating composition having a low content of volatile organic solvents, is curable at a temperature as low as 5&#xb0; C., and the cured coating composition of the current invention is essentially free of unreacted low-molecular weight blocking agents. Further, the pot life: drying time ratio of coating compositions according to the invention is particularly favorable.

Coating composition comprising a compound comprising a spiro-ortho silicate group

Photoactivatable water born coating composition comprising Preferably, the (meth)acryloyl-functional polyurethane comprises 8 to 18 wt. % of alkylene oxide groups. More preferably, the coating composition comprises a reactive diluent. The (meth)acryloyl-functional polyurethane is obtainable by reaction of: The water born coating composition is especially suitable for application as a clear coat.

Photoactivatable water borne coating composition

Aqueous cross-linkable binder composition and its use in the production of lacquer coatings

The invention pertains to a coating composition comprising a first compound comprising at least one bicyclo- or spiro-orthoester group and a second compound comprising at least two hydroxyl-reactive groups. The invention also comprises a process for curing the present coating composition. More particularly, the latent hydroxyl groups of the bicyclo- or spiro-orthoester groups have to be deblocked and reacted with the hydroxyl-reactive groups of the second compound if the present coating composition is to be cured. Further, a process for making bicyclo-orthoester compounds from the corresponding oxetane compound is described, as are polymers comprising at least one bicyclo- or spiro-orthoester group.

Coating composition comprising a bicyclo- or spiro-orthoester functional compound

Coating composition comprising a bicyclo-orthoester-functional compound, an isocyanate-functional compound, and a thiol-functional compound

A non-aqueous coating composition based on an oxidatively drying alkyd resin and a photo-initiator. An acid or latent acid and one or more compounds of the group of vinyl ethers, acetals, and alkoxysilanes which are reactive in the presence of an acid are incorporated into the coating composition. The vinyl ethers, acetals, and alkoxysilanes preferably are covalently bounded to the alkyd resin. The ratio of the number of oxidatively drying groups present in the alkyd resin to the number of groups reactive in the presence of an acid preferably is in the range of 1/10 to 15/1. The acid preferably is the phosphoric acid dibutyl ester.

Non-aqueous coating composition based on an oxidatively drying alkyd resin and a photo-initiator

Proposed is a thermosetting powder coating composition comprising a mixture of particles reactive towards one another and a catalyst, with a portion of the reactive particles comprising a polymer reacting with epoxy to form ester forming or ether forming groups, while another portion comprises an at least bifunctional cross-linking agent which contains 2-oxo-1,3-dioxolan-4-yl groups, hereinafter referred to as cyclocarbonate groups, and, optionally, epoxy groups, with both the polymer reacting with epoxy to form ester forming and/or ether forming groups and the cross-linking agent being obtained by means of a non-vinylic addition and/or polymerization process. The catalyst used as ring opener for the cyclocarbonate groups is present in a quantity of 0.01 to 10, preferably 0.1 to 5, parts by weight per 100 parts by weight of the mixture of particles reactive towards one another. The quantity of epoxy oxygen present in the cross-linking agent after CO.sub.2 unblocking preferably is at least 0.4 wt. %. The reactive polymer preferably is a polymer containing groups reactive towards epoxy such as carboxyl, anhydride and/or hydroxyl groups, with preference being given to polyesters and/or polyurethanes.

Thermosetting powder coating composition

The present invention pertains to coating compositions including a particular class of internally blocked polyamines as replacement for traditional blocked and unblocked polyamine crosslinkers. The use of these internally blocked polyamines results in better appearance characteristics and a lower VOC than are generally available with the traditional blocked varieties.

Internally blocked polyamine crosslinkers and coating compositions

Proposed is a thermosetting powder coating composition comprising a mixture of particles reactive towards one another, optionally in combination with a catalyst, with a portion of the reactive particles comprising a polymer reactive towards oxetane groups while another portion comprises an oxetane groups-containing cross-linking agent having an oxetane functionality of more than 1. The quantity of oxetane oxygen in the cross-linking agent preferably is at least 0.4 wt. %. The reactive polymer preferably is a polymer having groups reactive towards oxetane, such as carboxyl, epoxy, oxetane, anhydride, and hydroxyl, with preference being given to a polyester or a hydroxypolyacrylate.

Oligomeric sterically hindered polyamine crosslinkers and coating

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Sassenheim, Netherlands

Keimpe Jan Van Den Berg