Sanyo Electric Co., Ltd.

Mitsubishi Chemical Corporation

Kanto Denka Kogyo Co., Ltd.

Keiji Saisho

Hidekazu Yamamoto

Masahiro Takehara

Hiroshi Watanabe

Satoshi Narukawa

Yoshio Kato

Shigeki Matsuta

Takanobu Chiga

Ikuro Nakane

Osamu Omae

Ryo Mogi

Norio Tsujioka

The present invention provides a non-aqueous electrolyte secondary battery wherein a reaction between a non-aqueous electrolyte and an electrode is suppressed and decrease in battery capacity under high temperature is restricted, so that long time excellent battery characteristics can be obtained. A non-aqueous solvent of the non-aqueous electrolyte contains: chain fluorinated carboxylic acid ester represented by the formula R1-CH&#x2014;COO&#x2014;R2 where R1 represents hydrogen or alkyl group and R2 represents alkyl group and the sum of the carbon numbers of R1 and R2 is 3 or less, and in the case that R1 is hydrogen, at least one part of hydrogen in R2 is replaced with fluorine, and, in the case that R1 is alkyl group, at least one part of hydrogen in R1 and/or R2 is replaced with fluorine; and a film forming chemical compound decomposed in the range of +1.0 to 3.0 V based on an equilibrium potential between metal lithium and lithium ion.

Non-aqueous electrolyte for secondary battery and non-aqueous electrolyte secondary battery

The objective of the present invention is to prevent deterioration and expanding of anode active material and to improve charge-discharge cycle characteristics in a non-aqueous electrolyte secondary battery comprising an anode of which current collector has thereon a thin layer of an anode active material containing a metal. To solve this problem, in a non-aqueous electrolyte secondary battery wherein a thin layer of anode active material containing a metal which absorbs and discharges lithium is formed on a current collector and the thin layer of the anode active material is divided into columns by a gap formed along the thickness thereof, a compound represented by the following formula is contained in the non-aqueous electrolyte.A-N&#x2550;C&#x2550;O In the above formula, A represents an element or a group other than hydrogen.

Non-aqueous electrolyte secondary battery and non-aqueous electrolyte

The objective of the present invention is to prevent deterioration and expanding of anode active material and to improve charge-discharge cycle characteristics in a non-aqueous electrolyte secondary battery comprising an anode of which current collector has thereon a thin layer of an anode active material containing a metal. To solve this problem, in a non-aqueous electrolyte secondary battery wherein a thin layer of anode active material containing a metal which absorbs and discharges lithium is formed on a current collector and the thin layer of the anode active material is divided into columns by a gap formed along the thickness thereof, a compound represented by the following formula is contained in the non-aqueous electrolyte.A-N&#x2550;C&#x2550;OIn the above formula, A represents an element or a group other than hydrogen.

Disclosed is a nonaqueous electrolyte secondary battery which has a negative electrode containing silicon as a negative active material, a positive electrode containing a positive active material, a nonaqueous electrolyte and a separator. Characteristically, an additive which retards oxidation of silicon during operation of the battery is contained either in an interior or surface portion of the positive electrode, or in an interior or surface portion of the negative electrode, or in an interior or surface portion of the separator.

Nonaqueous electrolyte secondary battery including a negative electrode containing silicon and an additive which retards oxidation of silicon during battery operation

In a non-aqueous secondary cell having a positive electrode, a negative electrode, a nonaqueous electrolyte, a separator interposed between the positive electrode and the negative electrode, the positive electrode having a positive electrode active material including a chemical compound capable of reversibly intercalating lithium and the negative electrode having a negative electrode active material including a material capable of reversibly intercalating lithium, the separator has through holes formed therein for passing lithium dendrites therethrough.

Growing community of inventors

Kobe, Japan

Keiji Saisho