Matsushita Electric Industrial Co., Ltd.

Matushita Electric Industrial Co., Ltd.

Keiichi Yubakami

Hiromu Matsuda

Nobuyoshi Taguchi

Akihiro Imai

Tetsuji Kawakami

Wataru Shimotsuma

Yuji Takashima

Mamoru Soga

Nobuo Sonoda

Hajime Yamamoto

Thermal dye transfer printing systems which are adapted For multiple-use printing modes wherein one dye transfer sheet is repeatedly used and which comprise a dye transfer sheet having, on a substrate, a dye transfer layer containing a sublimable dye and a binder resin and a dye receiving sheet having a dye receiving layer which has a diffusion rate of the dye smaller than the dye transfer layer. This is effective in suppressing a lowering of printing density owing to the increase in number of printing cycles using one dye transfer sheet. Alternatively, the dye transfer sheet is constituted such that the dye transfer layer is made of a plurality of sub-layers in which the concentration of the dye decreases from the sub-layer formed directly on the substrate toward the surface side of the dye transfer layer. The dye is invariably supplied from the higher concentration sub-layers to ensure full color printing with a remarkably increasing number of multiple-use printing cycles.

Method for thermal dye transfer printing, dye transfer sheets and method

It can be obtained a receiving sheet for a dye transfer type thermal printing which is improved in a curing speed, image reliability, recording sensitivity, and dot reproducibility, and useful for high speed and/or relative-speeds printing by arranging a polymer layer on a substrate and then a cured resin layer of a moisture-curable resin on the polymer layer.

Dye-receiving sheets for dye transfer type thermal printing

A method of resistive sheet transfer recording is disclosed, in which the thermal diffusion coefficient of a resistive sheet (1) in the range of 1 to 100.times.10.sup.-6 m.sup.2 /s is combined with that of an electrode head (2) in the range of 0.1 to 50.times.10.sup.6 m.sup.2 /s, thereby making it possible to form a high-quality image at high sensitivity and high speed.

Resistive sheet transfer printing and electrode head

Thermal dye transfer printing systems which are adapted for multiple-use printing modes wherein one dye transfer sheet is repeatedly used and which comprise a dye transfer sheet having, on a substrate, a dye transfer layer containing a sublimable dye and a binder resin and a dye receiving sheet having a dye receiving layer which has a diffusion rate of the dye smaller than the dye transfer layer. This is effective in suppressing a lowering of printing density owing to the increase in number of printing cycles using one dye transfer sheet. Alternatively, the dye transfer sheet is constituted such that the dye transfer layer is made of a plurality of sub-layers in which the concentration of the dye decreases from the sub-layer formed directly on the substrate toward the surface side of the dye transfer layer. The dye is invariably supplied from the higher concentration sub-layers to ensure full color printing with a remarkably increasing number of multiple-use printing cycles.

A dye transfer sheet consisting of a transfer substrate and a coloring material layer comprising a high concentration layer which comprises a dye and is formed on the transfer substrate and a low concentration layer which comprises a water soluble resin or water dispersible resin having a polydimethylsiloxane structure and has a lower dye concentration than the high concentration layer and is formed on the high concentration layer. A dye transfer sheet consisting of a transfer substrate and a coloring material layer comprising a high concentration layer which comprises a dye and a binder polymer cross-linked with a cross-linking agent and is formed on the transfer substrate and a low concentration layer which comprises a water soluble resin or water dispersible resin and has a lower dye concentration than the high concentration layer and is formed on the high concentration layer. The dye transfer sheet of the present invention can be used in a multiple-use mode printing system including a relative speed printing.

Dye transfer type thermal printing sheets

The dye transfer type thermal printing sheet of the present invention comprises

When a dyeable layer comprises cured product of at least one moisture-curable type resin, it can have a high image reliability, permit easy control of the printing sensitivity and serve for both low-speed printing and high-speed printing. A receiving sheet having a dyeable layer excellent in surface slipperiness which is useful for high-speed printing and/or relative-speeds printing, can be obtained when the dyeable layer comprises cured product of a moisture-curable type resin, or reaction cured product of a moisture-curable type resin with a reactive silicone oil.

Receiving sheets for dye transfer type thermal printing

A thermal transfer printing system comprising a dye transfer sheet having a dye carrier layer containing at least one sublimable dye and a dye acceptor sheet having a dye-receiving layer with good affinity for the sublimable dye. The two sheets are arranged during printing operations in such a way that they are facing through a slippage means which is in the form of a layer of particles of lubricating or thermally releasable materials. This system is adapted for a printing process in which a relative speed of the dye transfer sheet to a thermal printing head is smaller than a relative speed of the dye acceptor sheet under which the dye transfer sheet is heated in an imagewise pattern to permit the sublimable dye to deposit on the dye-receiving layer according to the imagewise pattern. The dye transfer sheet and the dye acceptor sheet most suitable for use in the system are also described.

Thermal dye transfer printing systems, thermal printing sheets, and dye

A dye-receiving sheet comprising a substrate and a dye-receiving layer formed on one side of the substrate, the substrate being made of an extruded, biaxially stretched sheet of a mixture of white fine particles and a polyester resin. The extruded, stretched sheet has a specific gravity of from 1.0 to 1.38. A layer of polymer having a thermal deformation temperature or softening point lower than that of the extruded, stretched sheet may be formed on the extruded, stretched sheet. The dye-receiving sheet has high brightness and good flexibility with high printing sensitivity.

Dye-receiving sheets for thermal dye transfer printing

A thermal transfer printing system comprising a dye transfer sheet having a dye carrier layer containing at least one sublimable dye and a dye acceptor sheet having a dye-receiving layer with good affinity for the sublimable dye. The two sheets are arranged during printing operations in such a way that they are facing through a slippage means which is in the form of a layer or particles of lubricating or thermally releasable materials. This system is adapted for a printing process in which a relative speed of the dye transfer sheet to a thermal printing head is smaller than a relative speed of the dye acceptor sheet under which the dye transfer sheet is heated in an imagewise pattern to permit the sublimable dye to deposit on the dye-receiving layer according to the imagewise pattern. The dye transfer sheet and the dye acceptor sheet most suitable for use in the system are also described.

A dye-receiving sheet comprising a substrate and a dye-receiving layer formed on one side of the substrate, the substrate being made of an extruded sheet of a mixture of white fine particles and a polyester resin and a layer of a polymer material or composition whose thermal deformation temperature or softening point is lower than that of the extruded sheet. This sheet has high printing sensitivity.

Dye-receiving sheets for thermal dye transfer printing comprising a

This invention provides a magnetic fluid having a rich hue and containing an organic compound as dispersion medium. The magnetic fluid of this invention is constructed by mixing, into a magnetic dispersion, a colorant prepared by beforehand treating a coloring material with a solubilizing treating agent or a dispersibilizing treating agent. Said solubilizing treating agent or dispersibilizing treating agent has a hydrophobic group and a functional group absorbable or linkable to said coloring material. As said coloring material, a dyestuff, an organic pigment or an inorganic pigment is used. A colorant prepared by subjecting an intermediate of said coloring material to said treatment is also usable. Further, a colorant prepared by pretreating a coloring material so as to give the coloring material an absorbability or a linkability to said solubilizing treating agent or dispersibilizing treating agent and then subjecting the beforehand pretreated coloring material to said treatment is also usable. The magnetic fluid of this invention can retain its initial hue stably for a long period of time, and its hue can be changed without substantially changing the properties of magnetic fluid such as magnetization, viscosity and the like. Accordingly, the magnetic fluid of this invention can be applied extensively to all the use fields of magnetic dispersion, and it exhibits a particularly great effect when applied to uses of developer or ink in the field of printing and recording.

Magnetic fluid

Dye-receiving sheets for heat transfer recording comprising on a substrate, a dye-receiving layer consisting essentially of a cured product of an acrylate having two acrylic or methacrylic unsaturated bonds. The sheet is used in combination with a dye transfer sheet comprising a sublimable dye, and has a high affinity for the dye and a high heat resistance without bleeding of the dye.

Thermal dye transfer assembly for heat transfer recording

Image forming method using electrically conductive, light transmissive

This invention provides a magnetic fluid which is diversified in hue and stable in the electric fields. The magnetic fluid of this invention is composed of a dispersion of ferromagnetic particles dispersed by a surfactant, and a colorant having the same charge as the dispersing medium in said dispersing medium. The dyes effective for use in this invention are the nonionic azo dyes, anthrquinone dyes and metal-containing dyes, and the pigments useful in this invention are the organic or inorganic pigments treated so as to have an isoelectric point in the dispersing medium. A magnetic fluid having black color or other desired hues can be obtained by properly selecting the dye and/or pigment. The magnetic fluid of this invention exhibits its excellent properties particularly when used as a recording material.

Growing community of inventors

Osaka, Japan

Keiichi Yubakami