Sumitomo Metal Industries, Inc.

Keiichi Sasaki

Yoshihiko Sunami

Kunihiko Nishioka

Tsukasa Chikata

Tohru Iwahashi

A coal-based heavy oil is refined so as to remove quinoline insolubles and provide a hydrocarbon product suitable for making carbon stocks by heating to remove the volatile components which have boiling points ranging from the initial boiling point of the heavy oil to up to at least 200.degree. C. and at most 270.degree. C., thereby leaving a residual coal-based heavy oil, the residual coal-based heavy oil is mixed with a ketone-type solvent having a boiling point less than 200.degree. C. to form an insoluble precipitate (including quinoline insolubles) and a supernatent, the supernatent is treated to recover the ketone-type solvent, and the remaining hydrocarbon mixture is easily processed by vacuum distillation to produce a hydrocarbon product suitable for making carbon stocks.

Process for refining coal-based heavy oils

A process of producing a solvent useful in coal liquefaction which includes separating the heavy liquid produced from the liquefaction of coal into a fraction boiling at 200.degree. to 210.degree. C., a fraction boiling at 211.degree. to 230.degree. C., and a fraction boiling at not less than 231.degree. subjecting the fraction boiling at 211.degree. to 230.degree. C. to a hydrogenation treatment to produce a hydrogenated fraction, mixing the hydrogenated fraction with the fraction boiling at 200.degree. to 210.degree. C. to form a resultant mixture, and mixing a portion of the resultant mixture with a portion of the fraction boiling at not less than 231.degree. C. Alternately, the solvent is produced from the heavy liquid by separating it into a fraction boiling at 200.degree. C. to 210.degree. C., a fraction boiling at 211.degree. C. to 230.degree. C., a fraction boiling at 231.degree. C. to 250.degree. C., a fraction boiling at 251.degree. C. to 350.degree. C. and a fraction boiling at not less than 351.degree. C., subjecting each of the middle three fractions to a hydrogenation treatment to form three hydrogenated fractions, mixing the three hydrogenated fractions with the fraction boiling at 200.degree. C. to 210.degree. C. to form a resultant mixture, and mixing the resultant mixture with a portion of the fraction boiling at not less than 351.degree. C.

Process for manufacture of solvent for coal liquefaction

A solvent useful in coal liquefaction is obtained by separating the heavy liquid resulting from coal liquefaction into a fraction boiling at temperatures of between 200.degree. to 210.degree. C., a fraction boiling at temperatures between 211.degree. to 250.degree. C., and a fraction boiling at not less than 250.degree. C., subjecting the fraction boiling at between 211.degree. C. to 250.degree. C. to two hydrogenation treatments, mixing the hydrogenated product with the fraction boiling at between 200.degree. to 210.degree. C. which optionally has been hydrogenated to form a resultant mixture and mixing a portion of the resultant mixture with the fraction boiling at not less than 250.degree. C. which has been optionally hydrogenated.

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Amagasaki, Japan

Keiichi Sasaki