Asahi Kasei Kabushiki Kaisha

Keigo Sasaki

Harumi Watanabe

Katsuhiro Iwase

Miyuki Kazunori

Junichi Yoshida

Fumiki Murakami

Toshiharu Seyama

Provided is a method for manufacturing a methacrylic resin composition having excellent surface processability and displaying excellent preservability of formed surface processing. A method for manufacturing a methacrylic resin composition, wherein the methacrylic resin composition comprises two or more types of methacrylic resins that each have a structural unit (X) having the same type of cyclic structure-containing main chain, the methacrylic resin composition has a Vicat softening temperature of 120&#xb0; C. to 160&#xb0; C., methanol-soluble content is contained in an amount of 5 mass % or less relative to 100 mass %, in total, of the methanol-soluble content and methanol-insoluble content, comprising mixing a low molecular weight component and a high molecular weight component.

Method for manufacturing methacrylic resin composition

Methacrylic resin having high heat resistance, highly controlled birefringence, excellent color tone and transparency, and excellent moldability is provided. A methacrylic resin comprises a structural unit (B) having a cyclic structure-containing main chain, the structural unit (B) including at least one structural unit selected from the group consisting of an N-substituted maleimide-based structural unit (B-1) and a lactone ring structural unit (B-2), wherein a glass transition temperature is more than 120&#xb0; C. and 160&#xb0; C. or less, an amount of a methanol-soluble content is 5 mass % or less relative to 100 mass % of a total amount of the methanol-soluble content and a methanol-insoluble content in the methacrylic resin, and an yellowness index YI measured using a 10 cm optical path length cell for a 20 w/v % chloroform solution of the methanol-insoluble content is 0 to 7.

Methacrylic resin

A methacrylic resin composition having high heat resistance, excellent birefringence, and excellent heat stability and molding processability is provided. A methacrylic resin composition comprises: a methacrylic resin including a structural unit (X) having a cyclic structure-containing main chain, the structural unit (X) being at least one type selected from the group consisting of an N-substituted maleimide monomer-derived structural unit, a glutarimide-based structural unit, and a lactone ring structural unit; and an organic phosphorous compound, wherein a glass transition temperature is more than 120&#xb0; C. and 160&#xb0; C. or less, a content of a phosphorus element is 10 mass ppm to 1000 mass ppm, and a ratio P3/P5 of an integral value P3 of a spectral peak assigned to trivalent phosphorus to an integral value P5 of a spectral peak assigned to pentavalent phosphorus inP-NMR measurement is 0.2 to 5.0.

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Tokyo, Japan

Keigo Sasaki