Petrochina Company Limited

Kecun Ma

Yali Wang

Libo Wang

Tong Liu

Yan Jiang

Yulong Wang

Sihan Wang

Xianming Xu

Xiuhui Wang

Fuling Huang

Buwei Yu

Hongling Chu

Yuanyuan Cao

Enhao Sun

Hongliang Huo

Ning Zhang

Han Gao

Guizhi Wang

Xuemei Han

Weihong Guan

Yunguang Han

Fengrong Wang

Huaiqi Shao

Legang Feng

Ruhai Lin

The present invention provides a low viscosity poly-&#x3b1;-olefin lubricating oil and a synthesis method thereof. The method comprises: (1) the &#x3b1;-olefin raw material is subjected to dehydration treatment so that the water content in the raw material is &#x2264;10 ppm; (2) a reaction of the dehydration treated &#x3b1;-olefin raw material is carried out in the presence of a complex catalyst and gaseous BFto obtain a reaction product, wherein the pressure of the gaseous BFis 0.01 to 1 MPa; (3) the reaction product obtained in step (2) is sequentially subjected to flash distillation, gas stripping, centrifugation, and washing treatment to obtain an intermediate product; (4) the intermediate product obtained in step (3) is subjected to distillation under reduced pressure to separate the unreacted &#x3b1;-olefin raw material and &#x3b1;-olefin dimers, and the remaining heavy fractions are subjected to hydrogenation saturation treatment followed by fractionation and cutting-off.

Low viscosity poly-a-olefin lubricating oil and synthesis method thereof

The present disclosure provides a method and a catalyst for selective oligomerization of ethylene. The raw material for the catalyst consists of a dehydropyridine annulene-type ligand, a transition metal compound, and an organometallic compound in a molar ratio of 1:0.5-100:0.1-5000. The present disclosure also provides a method for selective oligomerization of ethylene accomplished by using the above-mentioned catalyst. The catalyst for selective oligomerization of ethylene has high catalytic activity, high selectivity for the target products 1-hexene and 1-octene, and low selectivity for 1-butene and 1-C.

Method and catalyst for selective oligomerization of ethylene

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Beijing, China

Kecun Ma