M.a. Hannacolor

M.a. Hannacolor, a Division of M.a. Hanna Company

Polycne Corporation

Ke Feng

Ronald M Harris

Alan R Burgess

Jerry Alan Bodi

The invention provides a composition and method for obtaining both light and dark laser marks of varying shades and intensities on a single plastic article by selectively controlling laser parameters. The invention further provides compositions and methods for obtaining pre-selected one-color and multi-colored designs on plastic articles, by selectively controlling material formulations and laser parameter settings.

Controlled color laser marking of plastics

The invention provides molded, extruded or formed phosphorescent plastic articles having laser marked indicia and methods for preparing the articles. The indicia may be seen as a contrast against a phosphorescent background or, alternatively, the indicia may themselves be phosphorescent. An article of the invention has a composition comprising about 50% to about 99% by weight of a thermoplastic or thermosetting resin, about 1% to about 50% by weight of a phosphorescent phosphor pigment and about 0.001% to about 1% by weight of a laser energy absorbing additive. Resin compositions which themselves are laser energy absorbing do not require the additive; however, the addition of small quantities of the laser energy additive enhances the quality and contrast of the laser mark. The composition may further comprise small quantities of one or more of a whitening pigment, a lubricating agent, or an inert filler without interfering with the phosphorescence of the article and/or the quality and contrast of the laser mark.

Laser marking of phosphorescent plastic articles

A method for obtaining both light and dark laser marks on a colored plastic article by using a composition with (i) a thermoplastic resin that foams when heated, (ii) about 0.4% to 0.7% by weight of a mica based laser energy absorbing additive and (iii) a coloring agent with one or more colorants selected from the group of pigments, dyes, and mixtures of pigments and dyes. Using a laser at certain settings results in charring of the resin to produce dark laser marks. At other selected laser settings, the resin foams to produce a light mark on a colored background. By varying the laser energy settings, various degrees of both foaming and charring can be achieved on a single plastic article, having a single resin composition, resulting in a multicolored laser image produced by various shades of light and/or dark marks against the background color.

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Lilburn, GA, United States of America

Ke Feng