Daicel Chemical Industries, Ltd.

Kazuyuki Matsuoka

Kenichi Yamamoto

Hiroshi Yagihara

Tomohide Ina

Li Rui Pan

Akinobu Matsuyama

Shogo Tomiyama

Yo Yamato

Jianzhou Wu

Noboru Kamei

Mitsuhiro Kouno

Takeshi Takahori

Xingxi Zhou

Masato Kawabe

Masayuki Okada

Kaoru Yamazaki

Provided is a basic metal nitrate suitable as an oxidizing agent for a gas generating agent, which is a basic metal nitrate having a good thermal stability and meeting at least one requirement of the following (a) to (d):

Basic metal nitrate, process for producing the same and gas generating agent composition

A granulated product of potassium sorbate (i) has an overall pore volume of 0.3 ml/g or less, (ii) has an Na content of 450 ppm or less, or (iii) has an overall pore volume of 0.4 ml/g or less, or a granule hardness of 15% or less, and an Na content of 1000 ppm or less. The granulated product is obtained, for example, (i) by granulating a potassium sorbate aqueous solution through fluidized bed granulation drying, (ii) by neutralizing sorbic acid with a potassium sorbate having a molar ratio of Na to K (Na/K) of 0.0024 or less to yield potassium sorbate, and granulating the potassium sorbate, or (iii) by neutralizing sorbic acid with a potassium sorbate having a molar ratio of Na to K (Na/K) of 0.006 or less to yield potassium sorbate, and moisture-conditioning 100 parts by weight of the potassium sorbate with 1 to 8.5 parts by weight of water and 1 to 8 parts by weight of a water-soluble organic solvent and subjecting the resulting mixture to extrusion granulation. The granulated product of potassium sorbate has a highly stable hue over time.

Potassium sorbate granulate and production processes thereof

Gas generant composition

3-hydroxymethylcycloalkanols and process for producing them

Alicyclic polyamines and process for the preparation thereof

The method comprises (1) a carboxylic acid salt providing step comprising permitting a strain of microorganism or a preparation derived from the microorganism to act upon a nitrile to thereby (a) provide at least the corresponding amide which is then hydrolyzed in the presence of a base to provide a salt of the corresponding carboxylic acid or (b) provide a salt of the corresponding carboxylic acid and (2) an electrodialysis step comprising subjecting the carboxylic acid salt provided in the step (1) to electrodialysis to provide the corresponding carboxylic acid and base. Carboxylic acids can be produced without formation of ammonium hydrogen sulfate and other byproducts. The microorganism includes microorganisms of the genera Pantoea and Gordona. The ammonia formed in the step (1) can be reused as a nitrogen source in a nitrile production line.

Method of producing carboxylic acids

A carbonylation catalytic system comprises (A) a combination of (A1) a Group VIII metal source of Periodic Table of the Elements (e.g., palladium, palladium chloride) supported on a carrier, (A2) a ligand such as triphenylphosphine and (A3) an acid such as an alkylsulfonic acid, or (B) a combination of (B1) the Group VIII metal source except for palladium (e.g., a platinum compound), (B2) a ligand such as triphenylphosphine and (B3) an electron donative compound having an electron donability .DELTA..nu.D of not less than 2 (for instance, an amine such as a heterocyclic tertiary amine). The catalytic system (B) may further comprise (B4) an acid such as methanesulfonic acid. In the presence of the catalytic system (A) or (B), an acetylenic or olefinic unsaturated compound is allowed to react with carbon monoxide and a nucleophilic compound having an active hydrogen such as water, an alcohol and a carboxylic acid in a liquid phase to give an unsaturated or saturated carboxylic acid or an ester thereof with high transformation rate and selectivity.

Catalytic systems and methods for carbonylation

A nitrile compound or an amide compound is hydrolyzed in the presence of an inorganic acid or other acidic catalyst or an alkali metal hydroxide or other basic catalyst, and the by-produced ammonium salt of the acidic catalyst or the produced salt of a carboxylic acid and a base is electrodialysed to form an acid and ammonia or aqueous ammonia, or to form a base and ammonia. The obtained acid or base may be recycled as a catalyst for the hydrolysis of the nitrile compound or amide compound, and the obtained ammonia is reutilized as a nitrogen source for the nitrile compound or amide compound. Such amide compound may be produced by hydration of a nitrite compound in the presence of a manganese oxide.

Process for producing a carboxylic acid

A carbonylation catalytic system comprises (A) a combination of (A1) a Group VIII metal source of Periodic Table of the Elements (e.g., palladium, palladium chloride) supported on a carrier, (A2) a ligand such as triphenylphosphine and (A3) an acid such as an alkyl-sulfonic acid, or (B) a combination of (B1) the Group VIII metal source except for palladium (e.g., a platinum compound), (B2) a ligand such as triphenylphosphine and (B3) an electron donative compound having an electron donability .DELTA..nu.D of not less than 2 (for instance, an amine such as a heterocyclic tertiary amine). The catalytic system (B) may further comprise (B4) an acid such as methanesulfonic acid. In the presence of the catalytic system (A) or (B), an acetylenic or olefinic unsaturated compound is allowed to react with carbon monoxide and a nucleophilic compound having an active hydrogen such as water, an alcohol and a carboxylic acid in a liquid phase to give an unsaturated or saturated carboxylic acid or an ester thereof with high transformation rate and selectivity.

Process for producing 2-hydroxy-4-methylthiobutanoic acid

Growing community of inventors

Kitakatsuragi-gun, Japan

Kazuyuki Matsuoka