Sumitomo Chemical Company, Limited

Kazuyoshi Hirabayashi

Hirohito Kenmochi

Yoshio Mori

Yoshihisa Sueda

Suketsugu Koumura

Hisashige Terao

Masaaki Ohkawa

Yoshiro Takeda

Sadaharu Abeta

Tetsuo Okaniwa

Seizo Konishi

Yoshio Tanaka

Tadao Kinoshita

A dye, which is suitable for dyeing cellulosic fiber materials, of the formula, ##STR1## wherein R and R' are each hydrogen, a C.sub.1 -C.sub.4 alkyl, or C.sub.1 -C.sub.4 hydroxyalkyl, m is an integer of 1 to 6, n and n' are each an integer of 2 to 4, and when m is 2 or more, n may be the same or different integer between 2 and 4, X is hydrogen or a group of the formula ##STR2## (wherein Q is a dye residue, R.sub.1 is hydrogen or a C.sub.1 -C.sub.4 alkyl and R.sub.2 is halogen); Y is hydrogen or a group of the formula ##STR3## (wherein Q' is a dye residue, and when m is 2 or more, Q's may be the same or different, R.sub.1 ' is hydrogen or a C.sub.1 -C.sub.4 alkyl and R.sub.2 ' is halogen); Z is hydrogen or a group of the formula ##STR4## (wherein Q' is a dye residue, R.sub.1 ' is hydrogen or a C.sub.1 -C.sub.4 alkyl and R.sub.2 ' is halogen, Q, Q' and Q' may independently be the same or different and X, Y and Z are not hydrogen at the same time).

Triazinyl-antraquinone dyes

A dye, which is suitable for dyeing cellulosic fiber materials, of the formula, ##STR1## wherein R and R' are each hydrogen, a C.sub.1 -C.sub.4 alkyl, or C.sub.1 -C.sub.4 hydroxyalkyl, m is an integer of 1 to 6, n and n' are each an integer of 2 to 4, and when m is 2 or more, n may be the same or different integer between 2 and 4, X is hydrogen or a group of the formula ##STR2## (wherein Q is a dye residue, R.sub.1 is hydrogen or a C.sub.1 -C.sub.4 alkyl and R.sub.2 is halogen); Y is hydrogen or a group of the formula ##STR3## 1 (wherein Q' is a dye residue, and when m is 2 or more, Q's may be the same or different, R.sub.1 ' is hydrogen or a C.sub.1 -C.sub.4 alkyl and R.sub.2 ' is halogen); Z is hydrogen or a group of the formula ##STR4## 5 (wherein Q' is a dye residue, R.sub.1 ' is hydrogen or a C.sub.1 -C.sub.4 alkyl and R.sub.2 ' is halogen, Q, Q' and Q' may independently be the same or different and X, Y and Z are not hydrogen at the same time).

Metallized triazine reactive dyes

A dye, which is suitable for dyeing cellulosic fiber materials, of the formula, ##STR1## wherein R and R' are each hydrogen, a C.sub.1 - C.sub.4 alkyl, or C.sub.1 - C.sub.4 hydroxyalkyl, m is an integer of 1 to 6, n and n' are each an integer of 2 to 4, and when m is 2 or more, n may be the same or different integer between 2 and 4, X is hydrogen or a group of the formula ##STR2## (wherein Q is a dye residue, R.sub.1 is hydrogen or a C.sub.1 - C.sub.4 alkyl and R.sub.2 is halogen); Y is hydrogen or a group of the formula ##STR3## (wherein Q' is a dye residue, and when m is 2 or more, Q's may be the same or different, R.sub.1 ' is hydrogen or a C.sub.1 - C.sub.4 alkyl and R.sub.2 ' is halogen); Z is hydrogen or a group of the formula ##STR4## (wherein Q' is a dye residue, R.sub.1 ' is hydrogen or a C.sub.1 - C.sub.4 alkyl and R.sub.2 ' is halogen, Q, Q' and Q' may independently be the same or different and X, Y and Z are not hydrogen at the same time).

Triazine reactive dyes

A cationic dye compound of the formula ##STR1## wherein the group ##STR2## represents an unsubstituted or 4 and/or 5-substituted thiazole ring, or an unsubstituted or 6-substituted benzothiazole ring, B represents an indolyl group represented by the formula ##STR3## wherein R.sub.1 represents an alkyl having 1 to 4 carbon atoms, an aralkyl or an aryl, said aryl may have an alkyl having 1 to 2 carbon atoms, an alkoxy having 1 to 2 carbon atoms, a halogen, cyano or nitro, and R.sub.2 represents hydrogen, an alkyl having 1 to 4 carbon atoms, an alkoxyalkyl, an acyloxyalkyl, a haloalkyl, a cyanoalkyl or a carbamoylalkyl, or an anilino group represented by the formula ##STR4## wherein R.sub.3 represents hydrogen, an alkyl having 1 to 2 carbon atoms, an alkoxy having 1 to 2 carbon atoms, a halogen, cyano or nitro, R.sub.4 and R.sub.5 represent individually an alkyl having 1 to 4 carbon atoms, an alkoxyalkyl, an acyloxyalkyl, a cycloalkyl, an aralkyl or an aryl, said aryl may have an alkyl having 1 to 2 carbon atoms, an alkoxy having 1 to 2 carbon atoms, a halogen, cyano or nitro, and n is an integer of 1 or 2, R represents an alkyl having 1 to 4 carbon atoms and Z.sup.- is an anion, which is useful as a red or blue cationic dye for dyeing fibrous materials composed of an acid modified polyacrylonitrile, its copolymer, polyamide or polyester.

Thiazole and benzothiazole cationic dyes

A compound of the formula (I): ##SPC1## wherein

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Kazuyoshi Hirabayashi