Mitsui Toatsu Chemicals, Incorporated

Kazuo Wakimura

Masao Tanaka

Atsuhiko Hiai

Yoshiaki Toyoda

Takao Tanaka

Hiroshi Kato

Tetsuya Iwao

Nobumasa Arashiba

Nobuhisa Iwane

Hatuo Inoue

Kazuhuyu Sudoh

Tetsuo Yoshiyama

Tadaharu Hase

Athuhiko Hiai

Yuri Kawano

Nobuhiro Kitano

The present invention provides a process for the production of glyoxals which comprises effecting the oxidative dehydrogenation of a glycol at a temperature of 400.degree. to 700.degree. C. in the presence of a silver-based catalyst composed of silver and at least one element selected from the group consisting of gold, platinum, rhodium and palladium, and phosphorus or a phosphorus compound, as well as such catalysts. These process and catalysts make it possible to produce high-quality glyoxals in high yield and with industrial advantages while minimizing the contents of unreacted raw material and reaction intermediates such as glycolaldehyde and acetol.

Process for the production of glyoxals and catalysts therefor

Melamine cyanurate is prepared by heating melamine powder and cyanuric acid powder at 250.degree. to 500.degree. C. substantially in the absence of any liquid medium. The melamine cyanurate can be obtained in a granular form when the heating is conducted subsequent to granulation of a mixture of both the powders.

Granular melamine cyanurate and preparation process thereof

Sinterable crystalline aluminum nitride powder is produced by reacting alkyl aluminum with ammonia in a gas phase to produce an amorphous aluminum nitride presursor powder, and subjecting the precursor powder to a primary calcination in a reducing gas containing at least 20% (vol.) ammonia at 600.degree. C. to 1300.degree. C., and then subjecting the calcined aluminum nitride to a secondary calination in an inert gas or a reducing gas at 1400.degree.-1750.degree. C.

Process for producing sinterable crystalline aluminum nitride powder

Supply equipment for providing a stable supply of feed gas of an organic metal compound at a constant concentration comprises a cylindrical vessel with an organic metal compound housed, an inlet tube of carrier gas for vaporizing said organic metal compound, an outlet tube for letting out the carrier gas substantially saturated with the vaporized organic metal compound, a room provided in the lower part of the vessel which is connected to said carrier gas inlet tube, a packed bed of an organic metal compound formed above said room, and a partition with a plurarity of pores partitioning said room and said packed bed.

Equipment and method for supply of organic metal compound

A method for preparing high-purity aluminum nitride having high thermal conductivity and heat resistance for aluminum nitride substrates, which comprises the steps of reacting an organic aluminum compound with an aminotriazine in a solvent to obtain an aluminum nitride precursor, separating the precursor form the solvent, and heating the precursor at a temperature of 600.degree. C. or more in a reducing atmosphere and/or a non-oxidizing atmosphere. An aluminum nitride sinter is prepared by, if necessary, adding a sintering auxiliary to the above aluminum nitride powder, molding the powder into a desired shape, and then sintering the molded material at a temperature of 1,600.degree. to 2,000.degree. C. in a non-oxidizing atmosphere.

Method for preparing aluminum nitride and its sinter

A method for preparing high-purity aluminum nitride having high thermal conductivity and heat resistance for aluminum nitride substrates, which comprises the steps of reacting an organic aluminum compound with an aminotriazine in a solvent to obtain an aluminum nitride precursor, separating the precursor from the solvent, and heating the precursor at a temperature of 600.degree. C. or more in a reducing atmosphere and/or a non-oxidizing atmosphere. An aluminum nitride sinter is prepared by, if necessary, adding a sintering auxiliary to the above aluminum nitride powder, molding the powder into a desired shape, and then sintering the molded material at a temperature of 1,600.degree. to 2,000.degree. C. in a non-oxidizing atmosphere.

Process for producing silanes

There is disclosed a process for producing germanes by reducing germanium halide with a mixture of alkylaluminum hydride and trialkylaluminum, in which a treatment for reducing the content of trialkylaluminum in the mixture to 10 mol. % or less relative to the alkylaluminum hydride is carried out prior to the reduction reaction. As to the treatment for reducing the content of trialkylaluminum in the mixture, there are provided, for example, distillation, recrystallization, complex formation followed by separation, pyrolysis and decomposition by hydrogenation and addition of alkylaluminum halide to said mixture.

Growing community of inventors

Sennan, Japan

Kazuo Wakimura