The Fujikura Cable Works Limited

Kazuo Isawa

Masatsugu Maejima

Kohichi Saruwatari

Takayoshi Usuki

Hideo Nagasaka

Takao Suzuki

Koichi Saruwatari

Seizo Murayama

A process of treating an anodic oxide film wherein a base material of a valve metal is anodized to form the anodic oxide film thereon, which is then impregnated with a polymerizable organic metal compound and thereafter subjected to polymerization of the compound, whereby the micropores of the anodic oxide film are filled and sealed with the polymerized organometallic compound. According to this process, there is provided a base material having an anodic oxide film impregnated with polymerized organometallic compound which is excellent in heat resistance, heat radiance, and electrical insulation, and hence the base material is useful for the printed wiring board, electrically-insulative heat sink, heat-resistant insulated wire and the like.

Process of treating a nodic oxide film, printed wiring board and process

A method of the surface treatment of a porous material which comprises the step of electrolyzing the porous material in an electrolytic bath composed of an aqueous solution of at least one salt selected from the group consisting of alkali metal thiotungstate, alkali metal thioantimonate, alkali metal thiostannate, alkali metal thiocuprate, alkali metal thioarsenate, alkali metal thioaurate, alkali metal thioplatinate, alkali metal thioniobate, alkali metal thiovanadate, alkaline earth metal thiotungstate, alkaline earth metal thioantimonate, alkaline earth metal thiostannate, alkaline earth metal thiocuprate, alkaline earth metal thioarsenate, alkaline earth metal thioaurate, alkaline earth metal thioplatinate, alkaline earth metal thioniobate, alkaline earth metal thiovanadate, ammonium thiotungstate, ammonium thioantimonate, ammonium thiostannate, ammonium thiocuprate, ammonium thioarsenate, ammonium thioaurate, ammonium thioplatinate, ammonium thioniobate and ammonium thiovanadate, to thereby impregnate the porous material with the metallic sulfide. Optionally, the porous material may be immersed alternately in an aqueous solution prepared as described above for the electrolytic bath and an acid aqueous solution after the electrolysis to further impregnate the porous material with the metallic sulfide.

Method of surface treatment of porous material

A method for the surface treatment of anodic oxide film is disclosed which comprises the steps of electrolyzing the porous surface of anodic oxide film of aluminium or aluminium alloy in an aqueous solution of ammonium thiomolybdate, optionally immersing it in an aqueous solution of ammonium thiomolybdate or alkali metal thiomolybdate and in dilute mineral acid or organic acid alternately, and subjecting it to a heat treatment so as to impregnate the micropores of the anodic oxide film with molybdenum sulfide and to fix the molybdenum sulfide therein.

Method for surface treatment of anodic oxide film

A uniform, thick film is formed by applying a powdered metal, alloy, sulfide of metal or glass each particle of which is coated with plastics 1-15% by weight, preferably the particle surfaces having been treated with an aliphatic acid or a silane-type surface-treating agent and the plastics including an organic peroxide, to a substrate by electrostatic powder spraying, fluidized bed coating, electrophoretic deposition, or by electrostatic fluidization, and fixing the layer thus provided on the substrate with heating to such extent that the plastic ingredient is fused or volatilized, to finally produce the desired film. The materials having such films fixed thereon have a wide application for interior building and glass-lining and as material of bearings.

Process for forming a film composed of plastic-coated inorganic powder

Organic or inorganic particulate solid substances are coated with a polymeric material by dispersing the particulate solids, the surfaces of which have been treated so as to be compatible with the polymer coating, in a solution containing the polymer dissolved in a water-immiscible solvent, slowly introducing into the dispersion an aqueous solution of a hydrophilic protective colloid, thus producing an emulsifying liquid medium, and removing therefrom the solvent, to finally obtain polymer coated solid particles. The polymer-coated powder thus obtained is useful for application to various substrates by fluidized bed coating, electrostatic spraying, or electrophoretic deposition, followed by sintering to form films.

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Tokyo, Japan

Kazuo Isawa