Mazda Motor Corporation

Figaro Engineering Inc.

Kazunari Komatsu

Takashi Takemoto

Makoto Kyogoku

Akihide Takami

Hirofumi Nishimura

Masahiko Shigetsu

Hideharu Iwakuni

Yasuto Watanabe

Naoyuki Noguchi

Yuki Koda

Kiyoshi Kuronishi

Hiroshi Yamada

Hiroshi Murakami

Satoshi Ichikawa

Taeko Shimizu

Masayuki Koishi

Katsuyuki Tanaka

Keiko Matsui

Kazuo Okino

Kazuo Onaga

Mariko Hanada

The active temperature of an exhaust gas cleaning catalyst is shifted to a higher temperature side when Al.sub.2 O.sub.3 and/or CeO.sub.2 is used as a co-catalyst and/or when an oxidation number of Pt or Ir which is used as the noble active component is plus four.

Exhaust gas cleaning catalyst component, process of production of the

A catalyst (3) for purifying an automotive exhaust gas, in which inner and outer catalytic layers (5,6), each of which has a base material and a catalytic material held by the base material, are stratified on a honeycomb-type carrier (4). In the catalyst (3), the inner catalytic layer (5) contains a palladium component as the catalytic component. Further the inner catalytic layer (5) contains a nickel oxide component for preventing poisoning of the palladium component. On the other hand, though the outer catalytic layer (6) contains a rhodium component as the catalytic component, it does not contain a palladium component nor a nickel oxide component.

Catalyst for purifying exhaust gas

An engine exhaust gas purifying catalyst contains, as active substances, platinum and at least one of iridium, III-B metals and IV-B metals. In particular, the catalyst contains mainly platinum and iridium and, desirably, rhodium as an additive catalyst substance.

Exhaust gas purification system and catalyst therefor

A catalytic convertor for treating exhaust gas includes a first catalyst layer formed on a base material and a second catalyst layer formed on the first catalyst layer. The first catalyst layer is composed of metal-containing silicate provided with transition metal by ion exchange and at least one precious metal borne on the silicate, and the second catalyst layer is composed of metal-containing silicate provided with transition metal by ion exchange and at least one metal borne on the silicate which is selected from the group consisting of Zr, Co, Cu, Cr, Mn, Y, Fe, Ni, V, Ti, Zn, Ga, Ba, Mg, La, Ce, Pr, Nd, Sm and Tb and differs from the transition metal provided on the silicate by ion exchange.

Catalytic converter for treating exhaust gas

An engine exhaust purification system is provided with a catalyst in an exhaust line, and oxygen sensors disposed in the exhaust line upstream and downstream from the catalyst, respectively. Deterioration of the catalyst is judged based on a frequency ratio of reversal of an output from the downstream oxygen sensor with respect to a threshold value to an output from the upstream oxygen sensor with respect to a threshold value. The threshold value of the deteriorated oxygen sensor is changed so as to vary the frequency ratio of reversal.

Engine exhaust purification system

An exhaust purification apparatus for an engine uses a catalytic converter provided in an exhaust system of the engine. First and second exhaust sensors are provided on upstream and downstream sides, respectively, of the catalyst converter in the exhaust system. Detected values from the first and second exhaust sensors are used for feed back control of air fuel ratio and judging deterioration of the catalyst of the catalytic converter, respectively. A control constant of the air fuel ratio of the feed back control is changed so that the second exhaust sensor detects in accordance with a condition of the catalyst.

Exhaust purification apparatus for an engine

In an exhaust system for an internal combustion engine, including an upstream catalytic converter and a downstream catalytic converter, emission levels of exhaust gas are detected at positions upstream from the upstream catalytic converter, between the upstream and downstream catalytic converters, and downstream from the downstream catalytic converter, respectively. An air-fuel ratio is feedback controlled based on an emission level detected by the first emission sensor or feedback controlled based on an emission level detected by the second emission sensor when the engine operates in a specific vehicle operating condition. Deterioration of the downstream catalytic converter is detected based on an emission level detected by the third emission sensor while an air-fuel ratio is feedback controlled based on the emission level detected by the second emission sensor.

Exhaust system for internal combustion engine

An exhaust system for an automobile engine having two groups of cylinders has a catalytic device. Deterioration of the catalytic device is detected based on an oxygen level in exhaust gas passed through the catalytic device. A feedback control of an air-fuel ratio is conducted for the cylinder groups all together, based on either of the air-fuel ratios determined, based on emission levels of exhaust gas discharged, for one of two of the groups of cylinders, only when a specific vehicle driving condition is detected.

An exhaust gas sensor containing BaSnO.sub.3 or the like and a process for producing the sensor. The BaSnO.sub.3 is made free of segregation and adapted to have acid-base strength of at least 6.8 as determined with Hammett's indicator. Causes to reduce the acid-base strength of the BaSnO.sub.3 includes presence of Si and B, and causes to increase the acid-base strength include addition of Mg or Ca. The desired BaSnO.sub.3 can be prepared by precipitating BaSnO.sub.3 hydrous crystals while preventing introduction of Si and B thereinto especially with use of a container lined with a synthetic resin to prevent introduction of Si and B from the container, adding Mg or Ca to the precipitate, and thermally decomposing the precipitate.

Exhaust gas sensor and process for producing same

An exhaust gas sensor in which a metal oxide semiconductor containing at least one member of a group of elements consisting of Sn, Fe, Ni and Co and Pt electrodes having ZrO.sub.2, deposited in the grain boundary are used. Such metal oxide semiconductors include, for example, SnO.sub.2, BaSnO.sub.2, BaSnO.sub.3, SrSnO.sub.3, and CaSnO.sub.3. The exhaust gas sensors are manufactured by mixing such compounds as BaCO.sub.3, SrCO.sub.3 or CaCO.sub.3 with SnO.sub.2 in equimolar ratio to react them in air at 1200.degree. C. for four hours. The compounds thus obtained were pulverized and Pt electrodes with ZrO.sub.2 were imbedded therein, then were molded into sensor chips. The chips thus molded were baked by heating in air. After the chip has been sintered the exhaust gas sensor was assembled. It comprised an insulating substrate of alumina, etc. having a recess provided at one end thereof in which the aforementioned sensor chip was housed. The electrodes on the chip were housed in grooves provided in the substrate with their ends connected with base metal outside leads. Then an alumina sheet was pasted on the substrate, leaving a gap along the circumferential rim of the chip, thereby shielding and protecting the electrode from the atmosphere.

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Hiroshima, Japan

Kazunari Komatsu