Nippon Shokubai Kagaku Kogyo Co., Ltd.

Nippon Shokubai Co., Ltd.

Nippon Shokubai Kagaku Kabushiki Kaisha

Kazumasa Kimura

Tadao Shimomura

Kinya Nagasuna

Nobuyuki Harada

Takumi Hatsuda

Koji Miyake

Yoshio Irie

Kenji Kadonaga

Takashi Namba

Kunihiko Ishizaki

Yoshihiko Masuda

Tsuneo Tsubakimoto

Teruaki Fujiwara

Yoshihiro Motono

Hitoshi Yano

Yoshihiro Arita

Akito Yano

Koichi Yonemura

Kazuaki Abe

Ryuichi Ishikawa

Kaoru Iwasaki

Takashi Kai

Katsumi Terawaki

Masashi Nakaki

A method for the production of (D) an absorbent resin excelling in durability, which method comprises polymerizing (A) 30% by weight to saturated concentration of (A) an aqueous water-soluble ethylenically unsaturated monomer solution containing (B) 0.005 to 5 mol % of a cross-linking agent and (C) 0.001 to 1 mol % of a water-soluble chain transfer agent, both based on the amount of said monomer (A), and if necessary, the surface region of the resultant absorbent resin (D) is cross-linked with (E) a hydrophilic cross-linking agent capable of reacting with the functional group of the absorbent resin and an absorbent resin obtained by such method.

Method for production of absorbent resin excelling in durability

A process for producing water-absorbent resins having an average particle diameter of 100 to 600 .mu.m and a particle diameter distribution of 0.35 or less by polymerizing an aqueous solution of a water-soluble ethylenically unsaturated monomer, pulverizing and sieving the polymer so obtained, and crosslinking the surface of the polymer powder.

Water absorbent resin

An absorbent material produced by mixing 100 parts by weight of an absorbent polymer with 1 to 80 parts by weight of synthetic pulp in the presence of 1 to 40 parts by weight of water, an absorbent body produced by mixing 100 parts by weight of an absorbent polymer with 1 to 80 parts by weight of synthetic pulp in the presence of 1 to 40 parts by weight of water, dry mixing the resultant mixture with 10 to 1,000 parts by weight hydrophilic fibers based on 100 parts by weight of said absorbent polymer, pneumatically molding the resultant mixture in the form of web, and thermally compressing the resultant web to a density in the range of from 0.1 to 1.0 g/cm.sup.3, and a method for production thereof.

Absorbent material, absorbent body, and method for production thereof

A process for producing a modified polyaminoamide with markedly increased reactivity as an epoxy resin curing agent is disclosed. The process comprises introducing amino groups and mercapto groups into a polyaminoamide by using an aziridine compound and a thiirane compound. The modified polyaminoamide is capable of curing an epoxy resin at a low temperature and at a high rate to provide a cured epoxy resin excellent in anticorrosion and chemical resistance.

Process for producing modified polyaminoamide, modified polyaminoamide

An absorbent material produced by mixing 100 parts by weight of an absorbent polymer with 1 to 80 parts by weight of synthetic pulp in the presence of 1 to 40 parts by weight of water, an absorbent body produced by mixing 100 parts by weight of an absorbent polymer with 1 to 80 parts by weight of synthetic pulp in the presence of 1 to 40 parts by weight of water, dry mixing the resultant mixture with 10 to 1,000 parts by weight hydrophilic fibers based on 100 parts by weight of the absorbent polymer, pneumatically molding the resultant mixture in the form of web, and thermally compressing the resultant web to a density in the range of from 0.1 to 1.0 g/cm.sup.3, and a method for production thereof.

Absorbent material comprising absorbent polymeric particulate material

A method for the production of a particulate hydrogel polymer by the exposure of a hydrogel polymer possessing a cross-linked structure to shear force in a vessel thereby finely dividing said hydrogel polymer, which method comprises exerting shear force repeatedly on said hydrogel polymer while keeping said hydrogel polymer at a temperature in the range of from 40.degree. to 110.degree. C. under a mechanical pressure in the range of from 0.01 to 1.5 kg/cm.sup.2, and method for the production of an absorbent resin comprising drying the resultant particulate hydrogel polymer.

Method for production of particulate hydrogel polymer and absorbent resin

Water-absorbent resins having an average particle diameter of 100 to 600 .mu.m and a particle diameter distribution of 0.35 or less are prepared by polymerizing an aqueous solution of a water-soluble ethylenically unsaturated monomer, pulverizing and sieving the gel-like polymer so obtained, and crosslinking the surface of the polymer powder. In an alternative process, an aqueous solution of the monomer having a viscosity greater than 15 cps is dispersed in a hydrophobic organic solvent and polymerized to obtain a polymer powder, and the surface of the polymer powder is crosslinked.

Water-absorbent resin and production process

An absorbent body having an absorbent polymer and hydrophilic fibers as main components thereof, characterized by the fact that the density of said absorbent body is in the range of from 0.1 to 0.5 g/cm.sup.3 or a ratio of wet swelling is not less than 200%, a capacity of said absorbent body for absorption of physiological saline solution under pressure is in the range of from 11 to 25 g/g, and the ratio of exfoliation of said absorbent polymer is not more than 45%, and an absorbent article comprising a liquid-pervious surface material, a liquid-impervious lining material, and the absorbent body layer interposed therebetween.

Absorbent body and absorbent article

A method for treating the surface of an absorbent resin which comprises mixing (I) 100 parts by weight of an absorbent resin powder having a carboxyl group, (II) 0.01 to 30 parts by weight of a polyhydric alcohol, (III) 0 to 50 parts by weight of water and (IV) 0 to 60 parts by weight of a hydrophilic organic solvent, and heat-treating at a temperature in the range of 90.degree. to 250.degree. C. to treat the surface of said absorbent resin powder (I) until the reaction of said absorbent resin powder (I) with said polyhydric alcohol (II) is completed, wherein the time for completion of the reaction is the time that satisfies the following equation (a-1):

Method for treating the surface of an absorbent resin

A method of treating the surface of an absorbent resin, which comprises mixing (A) 100 parts by weight of an absorbent resin powder possessing a carboxyl group (B) 0.01 to 30 parts by weight of a cross-linking agent, (C) 0 to 50 parts by weight of water, and (D) 0 to 60 parts by weight of a hydrophilic organic solvent in a high-speed stirring type mixer provided with an inner surface formed substantially of a substrate (I) possessing a contact angle of not less than about 60.degree. with respect to water and a heat distortion point of not lower than about 70.degree. C. and completing reaction of said absorbent resin powder (A) with said cross-linking agent (B).

Method of treating the surface of an absorbent resin

In a body fluid-absorbing article composed of a liquid-permeable front-surface member, a liquid-impermeable rear-surface member, and a fibrous absorbent member nipped therebetween and adapted to be used with the front-surface member held in contact with the human body, by the improvement having disposed in half of the thickness of the absorbent member on the front-surface member side an absorbent composite (A) obtained by applying an ethylenically unsaturated monomer capable of forming an absorbent polymer by polymerization or an aqueous solution of the monomer to a fibrous web and thereafter polymerizing the monomer.

Body fluid-absorbing article

A method of preparation of an absorbent composite in which an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into an absorbent polymer by polymerization is applied to a substrate, and the monomer is polymerized while the substrate to which the aqueous solution is applied is, on both the sides, held in contact with polymerization-inert surfaces facing each other. A continuous manufacturing method includes the sequential steps of continuously passing a substrate through (1) a region applying to the substrate an aqueous solution containing a water-soluble radical polymerization initiator and a water-soluble ethylenically unsaturated monomer which can be converted into an absorbent polymer by polymerization, and (2) a region of polymerizing the monomer while maintaining the substrate, on both the sides, in contact with polymerization-inert surfaces facing each other.

Method for manufacturing a water absorbent composite by applying an

The present invention is a method for the production of a water absorbent resin, which comprises preparing a monomer component possessing an ability to form a cross-linked structure and convert itself into a hydrated gel polymer during the course of aqueous solution polymerization, possessing an acid group-containing monomer content of at least 50 mol %, and having 10 to 50 mol % of said acid group-containing monomer neutralized and subjecting said monomer component to aqueous solution polymerization within a reaction vessel having a plurality of rotary shafts each fitted with stirring blades.

Method for production of water absorbent resin

This invention relates to a water-absorbent resin of a new, novel type obtained from polymerization of water-soluble ethylenically unsaturated monomer and a process for producing this resin. The water-absorbent resin in this invention has average particle diameter in a specially defined range and a narrow range of particle distribution, being superior in water-absorption capacity, and also, being superior in handling properties in a point of that, when being mixed with liquid, formation of a fish-eye is absent. The water-absorbent resin shows an angle-lacking, non-sphere shape and, in a case of shape like this, is superior in handling properties in a point that being hard in falling off from an basis material. Although the production process is performed to get a water-absorbent resin by carrying out polymerization in a reverse-phase suspension polymerization method, since the aqueous monomer solution is chosen from a specially defined viscosity range and dispersed and suspended by using a specially defined dispersing agent, a water-absorbent resin is easily obtainable wherein, not only the average particle diameter is controlled by adjusting the viscosity of an aqueous monomer solution, but also the particle diameter distribution is narrow. The water-absorbent resin obtained shows that a water-soluble component is small, so that it is very good for sanitary reasons. In this method, it is possible to vary the particle shape by changing up and down the viscosity of an aqueous monomer solution in an above-described specially defined range. The water-absorbent resin in this invention, because of having the above-described properties, is preferably used for sanitary materials and the like.

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Ikoma, Japan

Kazumasa Kimura