Toyota Motor Engineering & Manufacturing North America, Inc.

University of Illinois

The University of Arizona

Kazuhisa Yano

Debasish Banerjee

Songtao Wu

Paul Vannest Braun

Gaohua Zhu

Matthew Goodman

Pierre A Deymier

Jiajun Chen

Nichlas Z Swinteck

Carbon opals, a form of colloidal crystal, are composed of ordered two-dimensional or three-dimensional arrays of Monodispersed Starburst Carbon Spheres (MSCS). Methods for producing such carbon opals include oxidizing as-synthesized MSCS, for example by heating in air, to increase surface charge. Such oxidation is believed to decrease settling rates of a colloidal suspension, enabling formation of an ordered colloidal crystal. Inverse opals, composed of any of a wide variety of materials, and based on a carbon opal template, have a reciprocal structure to a carbon opal. Inverse opals are formed by methods including: forming a carbon opal as described, impregnating a desired material into pores in the carbon opal to produce a hybrid structure, and removing the carbon portion from the hybrid structure.

Methods for forming carbon opal templates and their use in forming inverse opals

A self-assembled carbon structure such as a carbon opal is disclosed herein. The structure is composed of hydrophilic carbon spheres oriented in a periodic colloidal crystal structure, wherein the carbon spheres have a porous surface, wherein the carbons spheres have an average particle diameter less than 3000 nm. Also disclosed is an inverse opal structure that includes a plurality of voids in the structural material. The voids are regularly arranged in an ordered periodic structure, the voids having a spherical shape. The inverse opal structure has a specific surface area greater than 100 m/g and method for making the same together with materials that employ the same.

High surface area carbon opals and inverse opals obtained therefrom

Processes of forming an irreversibly loose packed structure of particulate material useful as a photonic or phononic crystal are provided. Matrix material is infilled between particles and extends above the particles to form a particulate free matrix layer. Removing the matrix layer causes deformation of or exposes the spacing between the particles. The spaces are infilled by additional matrix material that when cured produces a supported and irreversibly loose packed crystalline structure of particles producing differing bandgaps and transmissive properties relative to the original structure. The processes provided allow for economical tuning of the transmissive properties of photonic or phononic crystals.

Loose packed phoxonic crystals and methods of formation

A composition is provided that includes mesoporous starburst carbon domains. Each of the mesoporous starburst carbon domains is incorporated with particles of metal or metal oxide in an amount of from 40 to 85 total weight percent of the composition. The metal or metal oxide particles can include tin, cobalt, copper, molybdenum, nickel, iron, or ruthenium, or an oxide thereof. The resulting composition when combined with a binder forms a battery electrode. Such a battery electrode operating as an anode in a lithium ion battery has gravimetric capacity of more than 1000 milliampere hours per gram after 15 galvanostatic cycles.

Mesoporous starburst carbon incorporated with metal nanocrystals or metal oxide nanocrystals, and uses thereof

A phononic device is provided suitable for attenuating mechanical vibration, as well as acoustic vibration that propagate through a medium. Through the periodic inclusion of domains of a material in a matrix that vary in the ratio of the longitudinal speed of sound (CL) and the transverse speed of sound (CT) between the domains and the matrix of equal to or greater than 2.0 and 40, respectively; improved significant attenuation of vibration is achieved.

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Ann Arbor, MI, United States of America

Kazuhisa Yano